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Wetting of metals and glasses on Mo

Description: The wetting of low melting point metals and Si-Ca-Al-Ti-O glasses on molybdenum has been investigated. The selected metals (Au, Cu, Ag) form a simple eutectic with Mo. Metal spreading occurs under nonreactive conditions without interdiffusion or ridge formation. The metals exhibit low (non-zero) contact angles on Mo but this requires temperatures higher than 1100 C in reducing atmospheres in order to eliminate a layer of adsorbed impurities on the molybdenum surface. By controlling the oxygen activity in the furnace, glass spreading can take place under reactive or nonreactive conditions. We have found that in the glass/Mo system the contact angle does not decrease under reactive conditions. In all cases, adsorption from the liquid seems to accelerate the diffusivity on the free molybdenum surface.
Date: January 8, 2008
Creator: Saiz, Eduardo; Tomsia, Antoni P.; Saiz, Eduardo; Lopez-Esteban, Sonia; Benhassine, Mehdi; de Coninck, Joel et al.
Partner: UNT Libraries Government Documents Department

Microstructural evolution of eutectic Au-Sn solder joints

Description: Current trends toward miniaturization and the use of lead(Pb)-free solder in electronic packaging present new problems in the reliability of solder joints. This study was performed in order to understand the microstructure and microstructural evolution of small volumes of nominally eutectic Au-Sn solder joints (80Au-20Sn by weight), which gives insight into properties and reliability.
Date: May 31, 2002
Creator: Song, Ho Geon
Partner: UNT Libraries Government Documents Department

Role of Nucleation and Growth in Two-Phase Microstructure Formation

Description: During the directional solidification of peritectic alloys, a rich variety of two-phase microstructures develop, and the selection process of a specific microstructure is complicated due to the following two considerations. (1) In contrast to many single phase and eutectic microstructures that grow under steady state conditions, two-phase microstructures in a peritectic system often evolve under non-steady-state conditions that can lead to oscillatory microstructures, and (2) the microstructure is often governed by both the nucleation and the competitive growth of the two phases in which repeated nucleation can occur due to the change in the local conditions during growth. In this research, experimental studies in the Sn-Cd system were designed to isolate the effects of nucleation and competitive growth on the dynamics of complex microstructure formation. Experiments were carried out in capillary samples to obtain diffusive growth conditions so that the results can be analyzed quantitatively. At high thermal gradient and low velocity, oscillatory microstructures were observed in which repeated nucleation of the two phases was observed at the wall-solid-liquid junction. Quantitative measurements of nucleation undercooling were obtained for both the primary and the peritectic phase nucleation, and three different ampoule materials were used to examine the effect of different contact angles at the wall on nucleation undercooling. Nucleation undercooling for each phase was found to be very small, and the experimental undercooling values were orders of magnitude smaller than that predicted by the classical theory of nucleation. A new nucleation mechanism is proposed in which the clusters of atoms at the wall ahead of the interface can become a critical nucleus when the cluster encounters the triple junction. Once the nucleation of a new phase occurs, the microstructure is found to be controlled by the relative growth of the two phases that give rise to different oscillatory microstructures that depend ...
Date: May 1, 2008
Creator: Shin, Jong Ho
Partner: UNT Libraries Government Documents Department

PURE DIFFUSIONAL MASS TRANSFER IN ZONE MELTING

Description: The differential equation and boundary conditions for pure diffusional mass transfer in zone melting were derived. Numerical solutions were obtained and approximated algebraically for eutectic-forming systems. An analytical solution for constant distribution coefficient was obtained. Graphs are given which permit rapid approximation of concentration profiles resulting from one zone pass. Example problems are provided which illustrate the use of the calculation techniques developed. (auth)
Date: August 1, 1962
Creator: Wilcox, W.R. & Wilke, C.R.
Partner: UNT Libraries Government Documents Department

THE KINETICS OF THE 02/C02 REACTION IN MOLTEN CARBONATE: REACTION ORDERS FOR 02 AND CO2 ON NiO

Description: A molten carbonate electrolytic cell of the Broers and Ketalaar type was used to study the reaction CO{sub 2} + 1/2 O{sub 2} + 2e{sup -} {r_equilibrium} CO{sub 2} {double_bond} in an Li/K carbonate eutectic melt with porous NiO electrodes. A noble gas Au wire reference electrode was used to measure anodic and cathodic polarizationduring electrolysis. Steady-state polarization curves were obtained at 800-1000 K with a matrix of fifteen CO{sub 2}/O{sub 2} mixtures: 0.5, 1, 10, 20, 50% CO{sub 2}/1,19, 50% O{sub 2}. Kinetic analysis in the linear overpotential region indicated ({partial_derivative} log i{sub 0}/{partial_derivative} log P) is near zero for CO{sub 2} and 0.5 for O{sub 2}. The kinetic Tafel slope wasmeasured from current-potential curves for current densities well below the diffusion limiting current and was found to be ca. RT/2F for cathodic polarizationand ca. 3RT/2F for anodic polarization. The reaction orders are + 1/4 in CO{sub 2} and + 5/8 in O{sub 2} in the cathodic direction, and -3/4 in CO{sub 2} and + 1/8 in O{sub 2} in the anodic direction.
Date: May 1, 1980
Creator: Winnick, Jack & Ross, Philip N., Jr.
Partner: UNT Libraries Government Documents Department

Mechanistic Selection and Growth of Twinned Bicrystalline Primary Si in Near Eutectic Al-Si Alloys

Description: Morphological evolution and selection of angular primary silicon is investigated in near-eutectic Al-Si alloys. Angular silicon arrays are grown directionally in a Bridgman furnace at velocities in the regime of 10{sup -3} m/sec and with a temperature gradient of 7.5 x 10{sup 3} K/m. Under these conditions, the primary Si phase grows as an array of twinned bicrystalline dendrites, where the twinning gives rise to a characteristic 8-pointed star-shaped primary morphology. While this primary Si remains largely faceted at the growth front, a complex structure of coherent symmetric twin boundaries enables various adjustment mechanisms which operate to optimize the characteristic spacings within the primary array. In the work presented here, this primary silicon growth morphology is examined in detail. In particular, this thesis describes the investigation of: (1) morphological selection of the twinned bicrystalline primary starshape morphology; (2) primary array behavior, including the lateral propagation of the starshape grains and the associated evolution of a strong <100> texture; (3) the detailed structure of the 8-pointed star-shaped primary morphology, including the twin boundary configuration within the central core; (4) the mechanisms of lateral propagation and spacing adjustment during array evolution; and (5) the thermosolutal conditions (i.e. operating state) at the primary growth front, including composition and phase fraction in the vicinity of the primary tip.
Date: December 12, 2006
Creator: Jung, Choonho
Partner: UNT Libraries Government Documents Department

Stability of eutectic interface during directional solidification

Description: Directional solidification of eutectic alloys shows different types of eutectic morphologies. These include lamellar, rod, oscillating and tilting modes. The growth of these morphologies occurs with a macroscopically planar interface. However, under certain conditions, the planar eutectic front becomes unstable and gives rise to a cellular or a dendritic structure. This instability leads to the cellular/dendritic structure of either a primary phase or a two-phase structure. The objective of this work is to develop a fundamental understanding of the instability of eutectic structure into cellular/dendritic structures of a single phase and of two-phases. Experimental studies have been carried out to examine the transition from a planar to two-phase cellular and dendritic structures in a ceramic system of Alumina-Zirconia (Al{sub 2}O{sub 3}-ZrO{sub 2}) and in a transparent organic system of carbon tetrabromide and hexachloroethane (CBr{sub 4}-C{sub 2}Cl{sub 6}). Several aspects of eutectic interface stability have been examined.
Date: April 23, 1996
Creator: Han, S.H.
Partner: UNT Libraries Government Documents Department

Liquid Permeability Measurements in Solidifying Aluminum-Copper Alloys

Description: Measurements of liquid permeability in the mushy zones of AI-15.42% Cu and Al-8.68% Cu alloy samples have been performed isothermally just above the eutectic temperature, using eutectic liquid as the fluid. A modified method has been developed to determine the specific permeability, K{sub s}, as a function of time during the test from the data collected on these alloys. Factors affecting permeability measurements are discussed. Permeabilities are observed to vary throughout the experiment. This is attributed to microstructural coarsening and channeling that occurs in the sample during the experiment. The permeability is related to the microstructure of the sample using the Kozeny-Carman equation. The correlation between the measured K{sub s}, liquid fraction, g{sub L} and the specific solid surface area, S{sub v}, improves markedly when compared to previous studies in which microstructural coarsening was ignored.
Date: February 28, 1999
Creator: Duncan, A.J.; Han, Q. & Viswanathan, S.
Partner: UNT Libraries Government Documents Department

Eutectic bonding of a Ti sputter coated, carbon aerogel wafer to a Ni foil

Description: The formation of high energy density, storage devices is achievable using composite material systems. Alternate layering of carbon aerogel wafers and Ni foils with rnicroporous separators is a prospective composite for capacitor applications. An inherent problem exists to form a physical bond between Ni and the porous carbon wafer. The bonding process must be limited to temperatures less than 1000{degrees}C, at which point the aerogel begins to degrade. The advantage of a low temperature eutectic in the Ni-Ti alloy system solves this problem. Ti, a carbide former, is readily adherent as a sputter deposited thin film onto the carbon wafer. A vacuum bonding process is then used to join the Ni foil and Ti coating through eutectic phase formation. The parameters required for successfld bonding are described along with a structural characterization of the Ni foil-carbon aerogel wafer interface.
Date: June 1, 1994
Creator: Jankowski, A.F.; Hayes, J.P. & Kanna, R.L.
Partner: UNT Libraries Government Documents Department

Processing, Microstructure, and Properties of Multiphase Mo Silicide Alloys

Description: Multiphase Mo silicide alloys containing T2 (Mo{sub 5}SiB{sub 2}), Mo{sub 3}Si and Mo phases where prepared by both melting and casting (M and C) and powder metallurgical (PM) processes. Glassy phases are observed in PM materials but not in M and C materials. Microstructural studies indicate that the primary phase is Mo-rich solid solution in alloys containing {le}(9.4Si+13.8B, at. %) and T2 in alloys with {ge}(9.8Si+14.6B). An eutectic composition is estimated to be close to Mo-9.6Si-14.2B. The mechanical properties of multiphase silicide alloys were determined by hardness, tensile and bending tests at room temperature. The multiphase alloy MSB-18 (Mo-9.4Si-13.8B) possesses a flexure strength distinctly higher than that of MoSi{sub 2} and other Mo{sub 5}Si{sub 3} silicide alloys containing no Mo particles. Also, MSB-18 is tougher than MoSi{sub 2} by a factor of 4.
Date: November 30, 1998
Creator: Heatherly, L.; Liu, C.T. & Schneibel, J.H.
Partner: UNT Libraries Government Documents Department

CATALYTIC GASIFICATION OF COAL USING EUTECTIC SALT MIXTURES

Description: This progress report on the Department of Energy project DE-FG-97FT97263 entitled, ''Catalytic Gasification of Coal Using Eutectic Salt Mixtures,'' covers the period April-September 1998. The specific aims of the project for this period were to identify appropriate eutectic salt mixture catalysts for the gasification of Illinois No.6 coal, evaluate various impregnation or catalyst addition methods to improve catalyst dispersion, and evaluate gasification performance in a bench-scale fixed bed reactor. The project is being conducted jointly by Clark Atlanta University (CAU), the University of Tennessee Space Institute (UTSI) and the Georgia Institute of Technology (Georgia Tech) with CAU as the prime contractor. Several single salt catalysts and binary and ternary eutectic catalysts were investigated at Clark Atlanta University. Physical mixing and incipient wetness methods were investigated as catalyst addition techniques. Gasification was carried out using TGA at CAU and UTSI and with a fixed-bed reactor at UTSI. The results showed better gasification activity in the presence of the catalysts tested. The eutectic salt studies showed clear agreement between the melting points of the prepared eutectics and reported literature values. The order of catalytic activity observed was ternary > binary > single salt. With the soluble single salt catalysts, the incipient wetness method was found to give better results than physical mixing technique. Also, catalyst preparation conditions such as catalyst loading, drying time and temperature were found to influence the gasification rate. Based on the Clark Atlanta University studies on Task 1, the project team selected the 43.5%Li{sub 2}CO{sub 3}-31.5%Na{sub 2}CO{sub 3}-25%K{sub 2}CO{sub 3} ternary eutectic and the 29%Na{sub 2}CO{sub 3}-71%K{sub 2}CO{sub 3} and 2.3%KNO{sub 3}-97.7%K{sub 2}CO{sub 3} binary eutectic for the fixed bed studies at UTSI. The eutectic salts were found to be highly insoluble in aqueous medium. As a result the technique of adding the eutectic to the raw coal ...
Date: October 1, 1998
Partner: UNT Libraries Government Documents Department

CATALYTIC GASIFICATION OF COAL USING EUTECTIC SALT MIXTURES

Description: This progress report on the Department of Energy project DE-FG-97FT97263 entitled, ''Catalytic Gasification of Coal Using Eutectic Salt Mixtures'', covers the period April-September 1998. The specific aims of the project for this period were to identify appropriate eutectic salt mixture catalysts for the gasification of Illinois No.6 coal, evaluate various impregnation or catalyst addition methods to improve catalyst dispersion, and evaluate gasification performance in a bench-scale fixed bed reactor. The project is being conducted jointly by Clark Atlanta University (CAU), the University of Tennessee Space Institute (UTSI) and the Georgia Institute of Technology (Georgia Tech) with CAU as the prime contractor. Several single salt catalysts and binary and ternary eutectic catalysts were investigated at Clark Atlanta University. Physical mixing and incipient wetness methods were investigated as catalyst addition techniques. Gasification was carried out using TGA at CAU and UTSI and with a fixed-bed reactor at UTSI. The results showed better gasification activity in the presence of the catalysts tested. The eutectic salt studies showed clear agreement between the melting points of the prepared eutectics and reported literature values. The order of catalytic activity observed was ternary > binary > single salt. With the soluble single salt catalysts, the incipient wetness method was found to give better results than physical mixing technique. Also, catalyst preparation conditions such as catalyst loading, drying time and temperature were found to influence the gasification rate. Based on the Clark Atlanta University studies on Task 1, the project team selected the 43.5%Li{sub 2}CO{sub 3}-31.5%Na{sub 2}CO{sub 3}-25%K{sub 2}CO{sub 3} ternary eutectic and the 29%Na{sub 2}CO{sub 3}-71%K{sub 2}CO{sub 3} and 2.3% KNO{sub 3}-97.7%K{sub 2}CO{sub 3} binary eutectic for the fixed bed studies at UTSI. The eutectic salts were found to be highly insoluble in aqueous medium. As a result the technique of adding the eutectic to the raw ...
Date: April 1, 2000
Partner: UNT Libraries Government Documents Department

Thermal contact resistance across a copper-silicon interface.

Description: An experimental setup to measure the thermal contact conductance across a silicon-copper (Si-Cu) interface is described, and the results obtained are presented. The resulting thermal contact resistance data are used in estimating the thermo-mechanical and optical performance of optical substrates cooled by interfaced copper cooling blocks. Several factors influence the heat transfer across solid interfaces. These include the material properties, interface pressure, flatness and roughness of the contacting surfaces, temperature, and interstitial material, if any. Results presented show the variation of thermal contact conductance as a function of applied interface pressure for a Cu-Si interface. Various interstitial materials investigated include iridium foil, silver foil and a liquid eutectic (Ga-In-Sn). As expected, thermal contact resistance decreases as interface pressure increases, except in the case of the eutectic, in which it was nearly constant. The softer the interstitial material, the lower the thermal contact resistance, Liquid metal provides the lowest thermal contact resistance across the Cu-Si interface, followed by the iridium foil, and then the silver foil.
Date: October 27, 1997
Creator: Khounsary, A.; Chojnowski, D.; Assoufid, L. & Worek, W.M.
Partner: UNT Libraries Government Documents Department

CATALYTIC GASIFICATION OF COAL USING EUTECTIC SALT MIXTURES

Description: The project, ''Catalytic Gasification of Coal Using Eutectic Salt Mixtures'', is being conducted jointly by Clark Atlanta University (CAU), the University of Tennessee Space Institute (UTSI) and the Georgia Institute of Technology (GT). The aims of the project are to: identify appropriate eutectic salt mixture catalysts for the gasification of Illinois No.6 coal; evaluate various impregnation or catalyst addition methods to improve catalyst dispersion; evaluate effects of major process variables (e.g., temperature, system pressure, etc.) on coal gasification; evaluate the recovery, regeneration and recycle of the spent catalysts in a bench-scale fixed bed reactor; and conduct thorough analysis and modeling of the gasification process to provide a better understanding of the fundamental mechanisms and kinetics of the process. The eutectic catalysts increased gasification rate significantly. The methods of catalyst preparation and addition had significant effect on the catalytic activity and coal gasification. The incipient wetness method gave more uniform catalyst distribution than that of physical mixing for the soluble catalysts resulting in higher gasification rates for the incipient wetness samples. The catalytic activity increased by varying degrees with catalyst loading. The above results are especially important since the eutectic catalysts (with low melting points) yield significant gasification rates even at low temperatures. Among the ternary eutectic catalysts studied, the system 39% Li{sub 2}CO{sub 3}-38.5% Na{sub 2}CO{sub 3}-22.5% Rb{sub 2}CO{sub 3} showed the best activity and will be used for further bench scale fixed-bed gasification reactor in the next period. Based on the Clark Atlanta University studies in the previous reporting period, the project team selected the 43.5% Li{sub 2}CO{sub 3}-31.5% Na{sub 2}CO{sub 3}-25% K{sub 2}CO{sub 3} ternary eutectic and the 29% Na{sub 2}CO{sub 3}-71% K{sub 2}CO{sub 3} binary eutectic for the fixed-bed studies at UTSI during this reporting period. Temperature was found to have a significant effect on the rate ...
Date: April 1, 1999
Partner: UNT Libraries Government Documents Department

Development of a high-power and high-energy thermal battery

Description: The Li(Si)/FeS{sub 2} and Li(Si)/CoS{sub 2} couples were evaluated with a low-melting LiBr-KBr-LiF eutectic and all-Li LiCl-LiBr-LiF electrolyte for a battery application that required both high energy and high power for short duration. Screening studies were carried out with 1.25 inch-dia. triple cells and with 10-cell batteries. The Li(Si)/LiCl-LiBr-LiF/CoS{sub 2} couple performed the best under the power load and the Li(Si)/LiCl-LiBr-LiF/FeS{sub 2} was better under the energy load. The former system was selected as the best overall performer for the wide range of temperatures for both loads, because of the higher thermal stability of CoS{sub 2}.
Date: April 18, 2000
Creator: GUIDOTTI,RONALD A.; SCHARRER,GREGORY L. & REINHARDT,FREDERICK W.
Partner: UNT Libraries Government Documents Department

A fully coupled 2D model of equiaxed eutectic solidification

Description: We propose a model of equiaxed eutectic solidification that couples the macroscopic level of heat diffusion with the microscopic level of nucleation and growth of the eutectic grains. The heat equation with the source term corresponding to the latent heat release due to solidification is calculated numerically by means of an implicit finite difference method. In the time stepping scheme, the evolution of solid fraction is deduced from a stochastic model of nucleation and growth which uses the local temperature (interpolated from the FDM mesh) to determine the local grain density and the local growth rate. The solid-liquid interface of each grain is tracked by using a subdivision of each grain perimeter in a large number of sectors. The state of each sector (i.e. whether it is still in contact with the liquid or already captured by an other grain) and the increase of radius of each grain during one time step allows one to compute the increase of solid fraction. As for deterministic models, the results of the model are the evolution of temperature and of solid fraction at any point of the sample. Moreover the model provides a complete picture of the microstructure, thus not limiting the microstructural information to the average grain density but allowing one to compute any stereological value of interest. We apply the model to the solidification of gray cast iron.
Date: December 31, 1995
Creator: Charbon, Ch. & LeSar, R.
Partner: UNT Libraries Government Documents Department

MEGAPIE analytical support task : characterization of lead-bismuth eutectic and sodium-cooled tungsten target materials for accelerator driven systems.

Description: Lead-Bismuth Eutectic and Tungsten are under consideration as target materials with high-energy protons for generating neutrons to drive actinide and fission product transmuters. A detailed characterization has been performed to study the performance of these target materials as a function of the main variables and the design selections. The characterization includes the neutron yield, the spatial energy deposition, the neutron spectrum, the beam window performance, and the target buffer impact on the target performance. The characterization has also considered high-energy deuteron particles to study the impact on the target neutronic performance. The obtained results quantify the performance of the Lead-Bismuth Eutectic and Tungsten target materials as a function of the target variables and design selections.
Date: October 18, 2002
Creator: Gohar, Y.
Partner: UNT Libraries Government Documents Department