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Reply to the Comment "Intercluster correlation in Seismicity" by Helmstetter and Sornette

Description: This paper is a reply to the comment by Helmstetter and Sornette titled "Intercluster correlation in Seismicity" which addresses an important point in a paper written by the authors that needs to be clarified.
Date: September 15, 2003
Creator: Mega, Mirko S.; Allegrini, Paolo; Grigolini, Paolo; Latora, Vito; Palatella, Luigi; Rapisarda, Andrea et al.
Partner: UNT College of Arts and Sciences

Dynamics of Electroencephalogram Entropy and Pitfalls of Scaling Detection

Description: This article discusses dynamics of electroencephalogram entropy and pitfalls of scaling detection. Herein the authors study the time evolution of diffusion entropy to elucidate the scaling of EGG time series.
Date: March 10, 2010
Creator: Ignaccolo, Massimiliano; Latka, Miroslaw; Jernajczyk, Wojciech; Grigolini, Paolo & West, Bruce J.
Partner: UNT College of Arts and Sciences

Trajectory versus probability density entropy

Description: In this article, the authors show that the widely accepted conviction that a connection can be established between the probability density entropy and the Kolmogorov-Sinai (KS) entropy is questionable.
Date: 2001
Creator: Bologna, Mauro; Grigolini, Paolo; Karagiorgis, Markos & Rosa, Angelo
Partner: UNT College of Arts and Sciences

Equation of State and Heat Content of Uranium

Description: Report issued by the APDA over studies conducted on the state of uranium at different temperature and pressure. Calculations are presented for the differing pressures of uranium. This report includes tables.
Date: February 20, 1957
Creator: Brout, Robert H.
Partner: UNT Libraries Government Documents Department

Compression and Diffusion: A Joint Approach to Detect Complexity

Description: Article discussing a joint approach to detect complexity by combining the Compression Algorithm Sensitive To Regularity (CASToRe) and Complex Analysis of Sequences via Scaling AND Randomness Assessment (CASSANDRA) procedures.
Date: February 2003
Creator: Allegrini, Paolo; Benci, V. (Vieri); Grigolini, Paolo; Hamilton, P.; Ignaccolo, Massimiliano; Menconi, Giulia et al.
Partner: UNT College of Arts and Sciences

Calculation of Five Thermodynamic Molecular Descriptors by Means of a General Computer Algorithm Based on the Group-Additivity Method: Standard Enthalpies of Vaporization, Sublimation and Solvation, and Entropy of Fusion of Ordinary Organic Molecules and Total Phase-Change Entropy of Liquid Crystals

Description: This article presents the calculation of the standard enthalpies of vaporization, sublimation and solvation of organic molecules using a common computer algorithm on the basis of a group-additivity method.
Date: June 25, 2017
Creator: Naef, Rudolf & Acree, William E. (William Eugene)
Partner: UNT College of Arts and Sciences

Spectrophotometric and Calorimetric Studies of Np(V) Complexation with Acetate at Variable Temperatures (T = 283 - 343 K)

Description: Spectrophotometric titrations were performed to identify the Np(V)/acetate complex and determine the equilibrium constants at variable temperatures (T = 283 - 343 K) and at the ionic strength of 1.05 mol {center_dot} kg{sup -1}. The enthalpy of complexation at corresponding temperatures was determined by microcalorimetric titrations. Results show that the complexation of Np(V) with acetate is weak but strengthened as the temperature is increased. The complexation is endothermic and is entropy-driven. The enhancement of the complexation at elevated temperatures is primarily due to the increasingly larger entropy gain when the solvent molecules are released from the highly-ordered solvation spheres of NpO{sub 2}{sup +} and acetate to the bulk solvent where the degree of disorder is higher at higher temperatures.
Date: December 21, 2009
Creator: Rao, Linfeng; Tian, Guoxin; Srinivasan, Thandankorai G.; Zanonato, PierLuigi & Di Bernardo, Plinio
Partner: UNT Libraries Government Documents Department

Thermodynamics of Cr2O3, FeCr2O4, ZnCr2O4 and CoCr2O4

Description: High temperature heat capacity measurements were obtained for Cr{sub 2}O{sub 3}, FeCr{sub 2}O{sub 4}, ZnCr{sub 2}O{sub 4} and CoCr{sub 2}O{sub 4} using a differential scanning calorimeter. These data were combined with previously-available, overlapping heat capacity data at temperatures up to 400 K and fitted to 5-parameter Maier-Kelley C{sub p}(T) equations. Expressions for molar entropy were then derived by suitable integration of the Maier-Kelley equations in combination with recent S{sup o}(298) evaluations. Finally, a database of high temperature equilibrium measurements on the formation of these oxides was constructed and critically evaluated. Gibbs energies of Cr{sub 2}O{sub 3}, FeCr{sub 2}O{sub 4} and CoCr{sub 2}O{sub 4} were referenced by averaging the most reliable results at reference temperatures of 1100, 1400 and 1373 K, respectively, while Gibbs energies for ZnCr{sub 2}O{sub 4} were referenced to the results of Jacob [Thermochim. Acta 15 (1976) 79-87] at 1100 K. Thermodynamic extrapolations from the high temperature reference points to 298.15 K by application of the heat capacity correlations gave {Delta}{sub f}G{sup o}(298) = -1049.96, -1339.40, -1428.35 and -1326.75 kJ mol{sup -1} for Cr{sub 2}O{sub 3}, FeCr{sub 2}O{sub 4}, ZnCr{sub 2}O{sub 4} and CoCr{sub 2}O{sub 4}, respectively.
Date: January 9, 2007
Creator: Ziemniak SE, Anovitz LM, Castelli RA, Porter WD
Partner: UNT Libraries Government Documents Department

Bound states and the Bekenstein bound

Description: We explore the validity of the generalized Bekenstein bound, S<= pi M a. We define the entropy S as the logarithm of the number of states which have energy eigenvalue below M and are localized to a flat space region of width alpha. If boundary conditions that localize field modes are imposed by fiat, then the bound encounters well-known difficulties with negative Casimir energy and large species number, as well as novel problems arising only in the generalized form. In realistic systems, however, finite-size effects contribute additional energy. We study two different models for estimating such contributions. Our analysis suggests that the bound is both valid and nontrivial if interactions are properly included, so that the entropy S counts the bound states of interacting fields.
Date: October 16, 2003
Creator: Bousso, Raphael
Partner: UNT Libraries Government Documents Department

Aza Cope Rearrangement of Propargyl Enammonium Cations Catalyzed By a Self-Assembled `Nanozyme

Description: The tetrahedral [Ga{sub 4}L{sub 6}]{sup 12-} assembly (L = N,N-bis(2,3-dihydroxybenzoyl)-1,5-diaminonaphthalene) encapsulates a variety of cations, including propargyl enammonium cations capable of undergoing the aza Cope rearrangement. For propargyl enammonium substrates that are encapsulated in the [Ga{sub 4}L{sub 6}]{sup 12-} assembly, rate accelerations of up to 184 are observed when compared to the background reaction. After rearrangement, the product iminium ion is released into solution and hydrolyzed allowing for catalytic turnover. The activation parameters for the catalyzed and uncatalyzed reaction were determined, revealing that a lowered entropy of activation is responsible for the observed rate enhancements. The catalyzed reaction exhibits saturation kinetics; the rate data obey the Michaelis-Menten model of enzyme kinetics, and competitive inhibition using a non-reactive guest has been demonstrated.
Date: February 27, 2008
Creator: Hastings, Courntey J.; Fiedler, Dorothea; Bergman, Robert G. & Raymond, Kenneth N.
Partner: UNT Libraries Government Documents Department

Mega et al. Reply

Description: This article is a reply to a comment by A. Helmstetter and D. Sornette about the article 'Power-Law Time Distribution of Large Earthquakes' from 2003.
Date: March 26, 2004
Creator: Mega, Mirko S.; Allegrini, Paolo; Grigolini, Paolo; Latora, Vito; Palatella, Luigi; Rapisarda, Andrea et al.
Partner: UNT College of Arts and Sciences