Neutron scattering from solutions: the hydration of lanthanide and actinide ions
Description:
The neutron scattering difference method is described and applied to investigations of the aqua rare-earth ions, Nd/sup 3 +/ and Dy/sup 3 +/. Metal-water distances and hydration numbers have been unambiguously determined for these ions' inner coordination spheres. The values of the hydration number, n, of 8.5 +- 0.2 for Nd/sup 3 +/ and 7.4 +- 0.5 for Dy/sup 3 +/, directly support the claim of Spedding et al. that n decreases by one unit across the lanthanide series. The possible application of …
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Date:
January 1, 1985
Creator:
Hahn, R.L.; Narten, A.H. & Annis, B.K.
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UNT Libraries Government Documents Department