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Rapid thermal outgassing of component samples

Description: This paper/presentation describes the rapid thermal outgassing tests that were ran to provide an inventory of all gasses present in the weld channel during the weld. The component samples tested were of all materials that are exposed to the channel during the temperature excursion due to the welding operation. The temperature ramps were determined from previous weld tests. The test equipment, test procedures, and the data collection system is described. They present the data and their interpretation of it.
Date: March 26, 1999
Creator: Beat, T G & Moffitt, K
Partner: UNT Libraries Government Documents Department

Summary of Degas II performance at the US Strategic Petroleum Reserve Big Hill site.

Description: Crude oil stored at the US Strategic Petroleum Reserve (SPR) requires mitigation procedures to maintain oil vapor pressure within program delivery standards. Crude oil degasification is one effective method for lowering crude oil vapor pressure, and was implemented at the Big Hill SPR site from 2004-2006. Performance monitoring during and after degasification revealed a range of outcomes for caverns that had similar inventory and geometry. This report analyzed data from SPR degasification and developed a simple degas mixing (SDM) model to assist in the analysis. Cavern-scale oil mixing during degassing and existing oil heterogeneity in the caverns were identified as likely causes for the range of behaviors seen. Apparent cavern mixing patterns ranged from near complete mixing to near plug flow, with more mixing leading to less efficient degassing due to degassed oil re-entering the plant before 100% of the cavern oil volume was processed. The report suggests that the new cavern bubble point and vapor pressure regain rate after degassing be based on direct in-cavern measurements after degassing as opposed to using the plant outlet stream properties as a starting point, which understates starting bubble point and overstates vapor pressure regain. Several means to estimate the cavern bubble point after degas in the absence of direct measurement are presented and discussed.
Date: October 1, 2007
Creator: Rudeen, David K. (GRAM, Inc., Albuquerque, NM) & Lord, David L.
Partner: UNT Libraries Government Documents Department

Measurement and Prediction of H2O Outgassing Kinetics from Silica-Filled Polydimethylsiloxane TR55 and S5370

Description: The isoconversional technique was employed for the measurement and prediction of H2O outgassing kinetics from silica-filled polydimethylsiloxane TR55 and S5370 in a vacuum or dry environment. Isoconversional analysis indicates that the energy barrier for H2O release from TR55 and S5370 is an increasing function of the fractional H2O release. This can be interpreted as the release of H2O from physisorbed water and then chemisorbed water with decreasing OH density from the surfaces of the embedded silica particles. Model independent predictions of H2O outgassing based on the measured kinetics follow the trend of actual isothermal outgassing at elevated temperatures, and suggest gradual outgassing in dry storage over many decades at low temperatures for both TR55 and S5370.
Date: August 28, 2006
Creator: Dinh, L N; Burnham, A K; Schildbach, M A; Smith, R A; Maxwell, R S; Balazs, B et al.
Partner: UNT Libraries Government Documents Department

Recent Developments in Graphite

Description: Developments in the production of various graphite products and data on the properties, outgassing, and radiation resistance of various graphites are reviewed. (C.J.G.)
Date: July 17, 1959
Creator: Kosiba, W. L.
Partner: UNT Libraries Government Documents Department

Desorption Kinetics of H2O from Cab-O-Sil-M-7D and Hi-Sil-233 Silica Particles

Description: Temperature programmed desorption (TPD) was performed at temperatures up to 850K on Cab-O-Sil-M-7D and Hi-Sil-233 silica particles. Physisorbed water molecules on both types of silica had activation energies in the range of 9-14.5 kcal/mol. However, the activation energies of desorption for chemisorbed water varied from {approx} 19 kcal/mol to > 59 kcal/mol for Cab-O-Sil-M-7D, and {approx} 23-37 kcal/mol for Hi-Sil-233. Our results suggest that physisorbed water can be effectively pumped away at room temperature (or preferably at 320 K) in a matter of hours. Chemisorbed water with high activation energies of desorption (>30 kcal/mol) will not escape the silica surfaces in 100 years even at 320 K, while a significant amount of the chemisorbed water with medium activation energies (19-26 kcal/mol) will leave the silica surfaces in that time span. Most of the chemisorbed water with activation energies < 30 kcal/mol can be pumped away in a matter of days in a good vacuum environment at 500 K. We had previously measured about 0.1-0.4 wt. % of water in M9787 polysiloxane formulations containing {approx} 21% Cab-O-Sil-M-7D and {approx} 4% Hi-Sil-233. Comparing present results with these formulations, we conclude that absorbed H{sub 2}O and Si-OH bonds on the silica surfaces are the major contributors to water outgassing from M97 series silicones.
Date: January 26, 2000
Creator: Dinh, L.; Balooch, M. & LeMay, J.D.
Partner: UNT Libraries Government Documents Department

Impact of the Wall Conditioning Program on Plasma Performance in NSTX

Description: High performance operating regimes have been achieved on NSTX (National Spherical Torus Experiment) through impurity control and wall-conditioning techniques. These techniques include HeGDC-aided boronization using deuterated trimethylboron, inter-discharge HeGDC, 350 C PFC bake-out followed by D2 and HeGDC, and experiments to test fueling discharges with either a He-trimethylboron mixture or pure trimethylboron. The impact of this impurity and density control program on recent advances in NSTX plasma performance is discussed.
Date: July 12, 2002
Creator: Kuge, H. W.; Soukhanovskii, V.; Bell, M.; Blanchard, W.; Gates, D.; LeBlanc, B. et al.
Partner: UNT Libraries Government Documents Department

Young organic matter as a source of carbon dioxide outgassing from Amazonian rivers

Description: Rivers are generally supersaturated with respect to carbon dioxide, resulting in large gas evasion fluxes that can be a significant component of regional net carbon budgets. Amazonian rivers were recently shown to outgas more than ten times the amount of carbon exported to the ocean in the form of total organic carbon or dissolved inorganic carbon. High carbon dioxide concentrations in rivers originate largely from in situ respiration of organic carbon, but little agreement exists about the sources or turnover times of this carbon. Here we present results of an extensive survey of the carbon isotope composition ({sup 13}C and {sup 14}C) of dissolved inorganic carbon and three size-fractions of organic carbon across the Amazonian river system. We find that respiration of contemporary organic matter (less than 5 years old) originating on land and near rivers is the dominant source of excess carbon dioxide that drives outgassing in mid-size to large rivers, although we find that bulk organic carbon fractions transported by these rivers range from tens to thousands of years in age. We therefore suggest that a small, rapidly cycling pool of organic carbon is responsible for the large carbon fluxes from land to water to atmosphere in the humid tropics.
Date: June 23, 2005
Creator: Mayorga, E; Aufdenkampe, A K; Masiello, C A; Krusche, A V; Hedges, J I; Quay, P D et al.
Partner: UNT Libraries Government Documents Department


Description: The distribution of H/sub 2/ among feed materials and products in the thermite reaction producing dingot U was studied. The H/sub 2/ content of Mg, molten U, and molten and solid MgF/sub 2/ density oxide to 98 to 99% for the high specific surface, ow bulk density oxides. The observed values for properties of the U/sub 3/O/sub 8/ samples correlated better with conversion of U/ sub 3/O/sub to UF/sub 4/ than did the observed values for properties of the corresponding UO/sub 2/ intermediates. (auth)
Date: September 20, 1957
Creator: Trzeciak, M.J. & Mallett, M.W.
Partner: UNT Libraries Government Documents Department

Measurement and Prediction of Water Outgassing from TR55 Silicone by the Isoconversional Technique

Description: The objectives of this report are to measure the H{sub 2}O outgassing kinetics of TR55 silicon after a few hours of vacuum pumping; and to make H{sub 2}O outgassing kinetic predictions for TR55 at low temperatures in a vacuum/dry environment.
Date: May 1, 2006
Creator: Dinh, L N; Schildbach, M A; Burnham, A K; Maxwell, R S & Balazs, B
Partner: UNT Libraries Government Documents Department

Preliminary results from the lunar prospector alpha particle spectrometer

Description: The Lunar Prospector Alpha Particle Spectrometer (LP APS) builds on Apollo heritage and maps the distribution of outgassing sites on the Moon. The APS searches for lunar surface gas release events and maps their distribution by detecting alpha particles produced by the decay of gaseous radon-222 (5.5 MeV, 3.8 day half-life) and solid polonium-210 (5.3 MeV, 138 day half-life, but remains on the surface with a 21 year half-life as lead-210), which are radioactive daughters from the decay of uranium-238. Radon is in such small quantities that it is not released directly from the lunar interior, rather it is entrained in a stream of gases and serves as a tracer for such gases. Once released, the radon spreads out by 'bouncing' across the surface on ballistic trajectories in a random-walk process. The 3.8 day half-life of radon-222 allows the gas to spread out by several 100 km before it decays and allows the APS to detect gas release events up to a few days after they occur. The long residence time (10s of years) of the lead-210 precursor to the polonium-210 allows the mapping of gas vents which have been active over the last approximately 50 years. Because radon and polonium are daughter products of the decay of uranium, the background level of alpha particle activity is a function of the lunar crustal uranium distribution. Using radioactive radon and polonium as tracers, the Apollo 15 and 16 Command Module orbital alpha particle experiments obtained evidence for the release of gases at several sites beneath the orbit tracks, especially over the Aristarchus Plateau and Mare Fecunditatis [1]. Aristarchus crater had previously been identified by ground-based observers as the site of transient optical events [2]. The Apollo 17 surface mass spectrometer showed that argon-40 is released from the lunar interior every few ...
Date: January 1, 2001
Creator: Lawson, S. L. (Stefanie L.)
Partner: UNT Libraries Government Documents Department

A Radically New Method for Hydrogen Storage in Hollow Glass Microspheres

Description: The primary goal of this project is to demonstrate that hydrogen gas can be rapidly extracted from hollow glass microspheres (HGMS) using a photo-induced heating effect. The results of the project demonstrate that diffusion of hydrogen is readily induced by exposure to light from an IR lamp in transition metal-doped HGMS filled to as much as 5,000 psi with hydrogen gas, which contain approximately 2.2 wt% hydrogen. Doped HGMS in conjunction with optically induced outgassing provide a solution to the traditional limitation of HGMS – i.e., the slow release of hydrogen from HGMS that are heated using a furnace. This information will also be invaluable in designing process changes for future production of HGMS able to hold higher pressures of hydrogen.
Date: July 13, 2009
Creator: Shelby, James E.; Hall, Matthew M.; Snyder, Michael J. & Wachtel, Peter B.
Partner: UNT Libraries Government Documents Department


Description: Ecologically sound operations of projected Ocean Thermal Energy Conversion (OTEC) plants can be insured by careful attention to the marine environment during the design phase. this requires quality information from regions of potential OTEC interest, coordinated with required assessment studies to insure legal compliance. Currently, preliminary or actual surveys and laboratory studies are being conducted in the waters of Puerto Rico, the Gulf of Mexico, Hawaii, and Guam for potential moored or seacoast OTEC plants and in the equatorial South Atlantic for proposed plant-ship operations to provide such benchmark and baseline data. These data plus existing archival information can be used to model effects of OTEC operations based on projected design schemes. Four major areas of concerns (1) redistribution of oceanic properties, (2) chemical pollution, (3) structural effects, and (4) socio-legal-economic; and 11 key issues associated with OTEC deployment and operation have been identified. In general mitigating strategies can be used to alleviate many deleterious environmental effects of operational problems as biostimulation, outgassing, etc. Various assessment research studies on toxicity, biocide releases, etc., are under way or are planned to investigate areas where no clear mitigating strategy is available. Data from the monitoring and assessment programs is being integrated into a series of environmental compliance documents including a comprehensive programmatic environmental impact assessment.
Date: June 1, 1979
Creator: Wilde, P.
Partner: UNT Libraries Government Documents Department

Degassing of Aluminum Alloys Using Ultrasonic Vibration

Description: The research was intended to lead to a better fundamental understanding of the effect of ultrasonic energy on the degassing of liquid metals and to develop practical approaches for the ultrasonic degassing of alloys. The goals of the project described here were to evaluate core principles, establish a quantitative basis for the ultrasonic degassing of aluminum alloy melts, and demonstrate the application of ultrsaonic processing during ingot casting and foundry shape casting.
Date: June 1, 2006
Creator: Meek, T. T.; Han, Q. & Xu, H.
Partner: UNT Libraries Government Documents Department

First high gradient test results of a dressed 325 MHz superconducting single spoke resonator at Fermilab

Description: A new superconducting RF cavity test facility has been commissioned at Fermilab in conjunction with first tests of a 325 MHz, {beta} = 0.22 superconducting single-spoke cavity dressed with a helium jacket and prototype tuner. The facility is described and results of full gradient, CW cavity tests with a high Q{sub ext} drive coupler are reported. Sensitivities to Q disease and externally applied magnetic fields were investigated. Results are compared to bare cavity results obtained prior to hydrogen degassing and welding into the helium jacket.
Date: September 1, 2010
Creator: Webber, R.C.; Khabiboulline, T.; Madrak, R.; Nicol, T.; Ristori, L.; Soyars, W. et al.
Partner: UNT Libraries Government Documents Department

Technical information for the relocation and treatment of Argonne National Laboratory drums

Description: The technical information in this document is to evaluate waste drums stored in Solid Waste Project Management facilities that contain organic and potentially flammable gases. The document provides an evaluation of the planned venting of potentially flammable gases and the potential risks associated with the task.
Date: August 7, 1997
Creator: Clinton, R.
Partner: UNT Libraries Government Documents Department

Operational test report, 500 CFM portable exhauster

Description: A 500 cubic foot per minute (CFM) portable exhauster system was fabricated for use on 241-A-101 [a Hydrogen Watch List tank] during saltwell pumping activities. An operational test was performed on this unit during 9/20/96 through 1O/14/96 in the 241-A Tank Farm. This operational test was done in accordance with OTP-060-001 Rev 0 (See Appendix A of this report). The test was performed with exceptions.
Date: May 15, 1997
Creator: Nelson, O.D.
Partner: UNT Libraries Government Documents Department

Ozone chemiluminescent detection of olefins: Potential applications for real-time measurements of natural hydrocarbon emissions

Description: A chemiluminescence analyzer has been constructed that takes advantage of the temperature dependence of the ozone-hydrocarbon reaction. When operated at a temperature of 170 C, the analyzer functions as a total nonmethane hydrocarbon analyzer with sensitivities 10--1,000 times better than a conventional FID. However, with operation at varying temperatures, the chemiluminescent signal reflects the differences in rates of reaction of the hydrocarbons with ozone. Preliminary studies at room temperature indicated that the relative rates of reaction of isoprene, {alpha}-pinene, {beta}-pinene, and limonene with ozone correlated with the observed chemiluminescence signal. When hydrocarbons are grouped in classes of similar structure, their rates of reaction with electrophilic atmospheric oxidants (e.g., OH, O{sub 3}, NO{sub 3}) can be correlated with each other. By varying the temperature of the reaction chamber, the chemiluminescence analyzer can be tuned to more reactive classes of hydrocarbons. Therefore, the chemiluminescence analyzer has the ability to determine atmospheric hydrocarbon concentrations as a function of class and will also provide a measure of the atmospheric reactivity of the hydrocarbons.
Date: October 1, 1997
Creator: Marley, N.A.; Gaffney, J.S. & Cunningham, M.M.
Partner: UNT Libraries Government Documents Department

Application & testing of high temperature materials for solenoid coils

Description: Sandia National Laboratories has designed and proven-in two new Solenoid coils for a highly-reliable electromechanical switch. Mil-Spec Magnetics Inc., Walnut CA manufactured the coils. The new design utilizes two new materials: Liquid Crystal Polymer (Vectra C130) for the bobbin and Thermal Barrier Silicone (VI-SIL V-658) for the encapsulant. The use of these two new materials solved most of the manufacturing problems inherent in the old Sandia design. The coils are easier to precision wind and more robust for handling, testing, and storage. The coils have some unique weapon related safety requirements. The most severe of these requirements is the 400{degrees}C, 1600 V test. The coils must not, and did not, produce any outgassing products to affect the voltage breakdown between contacts in the switch at these temperatures and voltages. Actual coils in switches were tested under these conditions. This paper covers the prove-in of this new coil design.
Date: August 1, 1997
Creator: Sanchez, R.O.; Archer, W.E. & Zich, J.L.
Partner: UNT Libraries Government Documents Department

Natural gas productive capacity for the lower 48 states 1984 through 1996, February 1996

Description: This is the fourth wellhead productive capacity report. The three previous ones were published in 1991, 1993, and 1994. This report should be of particular interest to those in Congress, Federal and State agencies, industry, and the academic community, who are concerned with the future availability of natural gas. The EIA Dallas Field Office has prepared five earlier reports regarding natural gas productive capacity. These reports, Gas Deliverability and Flow Capacity of Surveillance Fields, reported deliverability and capacity data for selected gas fields in major gas producing areas. The data in the reports were based on gas-well back-pressure tests and estimates of gas-in-place for each field or reservoir. These reports use proven well testing theory, most of which has been employed by industry since 1936 when the Bureau of Mines first published Monograph 7. Demand for natural gas in the United States is met by a combination of natural gas production, underground gas storage, imported gas, and supplemental gaseous fuels. Natural gas production requirements in the lower 48 States have been increasing during the last few years while drilling has remained at low levels. This has raised some concern about the adequacy of future gas supplies, especially in periods of peak heating or cooling demand. The purpose of this report is to address these concerns by presenting a 3-year projection of the total productive capacity of natural gas at the wellhead for the lower 48 States. Alaska is excluded because Alaskan gas does not enter the lower-48 States pipeline system. The Energy Information Administration (EIA) generates this 3-year projection based on historical gas-well drilling and production data from State, Federal, and private sources. In addition to conventional gas-well gas, coalbed gas and oil-well gas are also included.
Date: February 9, 1996
Partner: UNT Libraries Government Documents Department

Challenges in the Packaging of MEMS

Description: Microelectromechanical Systems (MEMS) packaging is much different from conventional integrated circuit (IC) packaging. Many MEMS devices must interface to the environment in order to perform their intended function, and the package must be able to facilitate access with the environment while protecting the device. The package must also not interfere with or impede the operation of the MEMS device. The die attachment material should be low stress, and low outgassing, while also minimizing stress relaxation overtime which can lead to scale factor shifts in sensor devices. The fabrication processes used in creating the devices must be compatible with each other, and not result in damage to the devices. Many devices are application specific requiring custom packages that are not commercially available. Devices may also need media compatible packages that can protect the devices from harsh environments in which the MEMS device may operate. Techniques are being developed to handle, process, and package the devices such that high yields of functional packaged parts will result. Currently, many of the processing steps are potentially harmful to MEMS devices and negatively affect yield. It is the objective of this paper to review and discuss packaging challenges that exist for MEMS systems and to expose these issues to new audiences from the integrated circuit packaging community.
Date: September 24, 1999
Partner: UNT Libraries Government Documents Department