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Crystal Densities of Uranium Chlorides

Description: Abstract: "Using xylene as the densimetric solvent, the crystal densities have been determined by the pyknometric method for the following chlorides, UCl3, UCl4, UCl6(UCl4), UCl6 and U02Cl2."
Date: December 13, 1946
Creator: Sterett, C. C. & Calkins, V. P.
Partner: UNT Libraries Government Documents Department

Qualitative Observations of the Characteristics of TCl₅

Description: Summary: The controlled decomposition of the TCl₅ was carried out in an electric furnace at furnace temperatures varying from 114° to 550°C. The results indicate that chlorine evolution is noticeable when the TCl₅ temperature is about 75°C. The rate of reaction increases rapidly at a TCl₅ temperature of 175°C. Thus the possibility of TCl₅ existing at a very high temperature becomes uncertain. The TCl₄ prepared at the low temperatures (up to 300°) was obtained as a micro crystalline powder while those products allowed to heat at 400°-500° had a characteristic crystalline appearance.
Date: 1945
Creator: Gavlin, Gilbert; Hubbard, J. V. & Clewett, O. H.
Partner: UNT Libraries Government Documents Department

ELECTROCHEMISTRY OF MOLTEN SALTS. Period Covered: June 1, 1954 to June 1, 1956

Description: A new back-emf method for measuring the thermodynamic emf of molten salt cells of the type M/MCl/sub 2/ in molten salt solvent/Cl/sub 2/ is presented. Decomposition potentials are measured in the course of the thermodynamic emf determination. The systems PbCl/sub 2/-ZrCl/sub 2/, LiCl-KCl eutectic, LiCl-KCl- NdCl/sub 3/, MgCl/sub 2/ in LiClKCl and NaCl, SnCl/sub 2/, KCl, and PbCl/sub 2/, and ZnCl/sub 2/ in LiClKCl eutectic were studied. The thermodynamic emf's obtained by the back-emf method are in good agreement with values calculated from independent thermochemical data. Thus Raoult's law is thought to apply in these simple systems to within a factor of two in the activity coefficient. (auth)
Date: June 1, 1956
Creator: Roland, E.H. & Pound, G.M.
Partner: UNT Libraries Government Documents Department

Darex Process: Processing of Stainless Steel-Containing Reactor Fuels with Dilute Aqua Regia

Description: From abstract: "The Darex process developed for the recovery of uranium from stainless steel-containing reactor fuels consists of three steps: (1) dissolution of the fuel material in dilute aqua regia, (2) removal of chloride from the solution to prevent corrosion of downstream stainless steel process equipment, and (3) adjustment of the nitrate solution to solvent extraction feed conditions."
Date: June 7, 1962
Creator: Kitts, F. G.
Partner: UNT Libraries Government Documents Department

Spectrophotometric Evidence for the Existence of UCl₅ as the Double Compound UCl₆ and UCl₄

Description: Abstract: "Spectrophotometric evidence for the existence of UCl₅ as a double compound UCl₆ and UCl₄ has been obtained by studying the absorption spectra of these chlorides in CCl₄ and SOCl2 solutions in the visible and ultraviolet regions of the spectrum."
Date: December 9, 1946
Creator: Sterett, C. C. & Calkins, V. P.
Partner: UNT Libraries Government Documents Department

The Heat of Solution of Neptunium Metal and the Heats of Formation of some Neptunium Chlorides ; A Microcalorimeter for Heat of Solution Measurements

Description: Due to a need of precise thermodynamical and thermochemical data on these elements and their compounds for the understanding and correlation of the chemical behavior of these substances, this report measures the heat of the solution of neptunium metal and the heats of formation of the neptunium chlorides using a microcalorimeter to measure the heat.
Date: August 1950
Creator: Westrum, Edgar F., (Jr.) & Eyring, LeRoy
Partner: UNT Libraries Government Documents Department

Electrostatic Modeling of Vacuum Insulator Triple Junctions

Description: A comprehensive matrix of 60 tests was designed to explore the effect of calcium chloride vs. sodium chloride and the ratio R of nitrate concentration over chloride concentration on the repassivation potential of Alloy 22. Tests were conducted using the cyclic potentiodynamic polarization (CPP) technique at 75 C and at 90 C. Results show that at a ratio R of 0.18 and higher nitrate was able to inhibit the crevice corrosion in Alloy 22 induced by chloride. Current results fail to show in a consistent way a different effect on the repassivation potential of Alloy 22 for calcium chloride solutions than for sodium chloride solutions.
Date: August 13, 2007
Creator: Tully, L. K.; White, A. D.; Goerz, D. A.; Javedani, J. B. & Houck, T. L.
Partner: UNT Libraries Government Documents Department

Dehydration of plutonium trichloride hydrate

Description: A process of preparing anhydrous actinide metal trichlorides of plutonium or neptunium by reacting an aqueous solution of an actinide metal trichloride selected from the group consisting of plutonium trichloride or neptunium trichloride with a reducing agent capable of converting the actinide metal from an oxidation state of +4 to +3 in a resultant solution, evaporating essentially all the solvent from the resultant solution to yield an actinide trichloride hydrate material, dehydrating the actinide trichloride hydrate material by heating the material in admixture with excess thionyl chloride, and recovering anhydrous actinide trichloride is provided.
Date: December 31, 1991
Creator: Foropoulos, J. Jr.; Avens, L.R. & Trujillo, E.A.
Partner: UNT Libraries Government Documents Department

Repassivation Potential of Alloy 22 in Sodium and Calcium Chloride Brines

Description: A comprehensive matrix of 60 tests was designed to explore the effect of calcium chloride vs. sodium chloride and the ratio R of nitrate concentration over chloride concentration on the repassivation potential of Alloy 22. Tests were conducted using the cyclic potentiodynamic polarization (CPP) technique at 75 C and at 90 C. Results show that at a ratio R of 0.18 and higher nitrate was able to inhibit the crevice corrosion in Alloy 22 induced by chloride. Current results fail to show in a consistent way a different effect on the repassivation potential of Alloy 22 for calcium chloride solutions than for sodium chloride solutions.
Date: August 11, 2007
Creator: Rebak, R B; Ilevbare, G O & Carranza, R M
Partner: UNT Libraries Government Documents Department

Phase equilibria in the system H{sub 2}O-NaCl-KCl-MgCl{sub 2} relevant to salt cake processing

Description: One waste product in recycling of Al is salt cake, a mixture of Al, salts, and residue oxides. Several methods have been proposed to recycle salt cake, one involving high-temperature leaching of salts from the salt cake. The salt composition can be approximated as a mixture predominantly of NaCl and KCl salts, with lesser amounts of Mg chloride. In order to better assess the feasibility of recycling salt cake, an experimental study was conducted of phase equilibria in the system H{sub 2}O-NaCl-KCl-MgCl{sub 2} at pressure (P), temperature (T), and composition conditions appropriate for high- temperature salt cake recycling. These experiments were designed to evaluate the effect of small amounts (2-10 wt%) of MgCl{sub 2} on solubilities of halite (NaCl) and sylvite (KCl) in saturated solutions (30-50 wt% NaCl+KCl; NaCl:KCl = 1:1 and 3:1) at elevated P and T.
Date: February 1, 1997
Creator: Bodnar, R.J.; Vityk, M.O.; Hryn, J.N. & Mavrogenes, J.
Partner: UNT Libraries Government Documents Department

Matrix Isolation Studies of High-Temperature Species Group II Chlorides

Description: A matrix isolation technique for the investigation of infrared absorption spectra of molecules of hightemperature species trapped in a pseudo- gas phase'' is described. The spectra of the dichlorides of zinc, cadmium, and mercury in argon, krypton, and xenon matrices are reported. Presence in the gas phase of dimers of zinc chloride and mercuric chloride is noted. An absorption band, previously reported as due to the degenerate bending motion of zinc chloride, is attributed to zinc dimer. (auth)
Date: September 13, 1962
Creator: McNamee, R. W., Jr.
Partner: UNT Libraries Government Documents Department

TRANSFERENCE NUMBERS AND ION ASSOCIATION IN PURE FUSED ALKALINE EARTH CHLORIDES

Description: The transference number of the chloride ion was determined in pure fused MgCl/sub 2/, CaCl/sub 2/, SrCl/sub 2/, and BaCl/sub 2/ utili zing radioactive chloride ions in a porous quartz membrane cell. On the basis of a two-step dissociation for these salts, MCl/sub 2/ in equilibrium MCl/sup +/ + Cl/sup -/ in equilibrium Ml/sup +/ + 2Cl/sup -/, the ext ent of the second dissociation was qualitatively predicted from a consideration of the relative mobilities of the ions. (auth)
Date: March 27, 1962
Creator: Wolf, E.D. & Duke, F.R.
Partner: UNT Libraries Government Documents Department

INVESTIGATION FOR THE PRODUCTION OF THORIUM METAL. Technical Progress Report--Fifth Quarter

Description: Processes for preparing a suitable ThCl/sub 4/ electrolyte free of H/sub 2/O and C/sub 2/ were investigated including chlorination with C -Cl/sub 2/, sulfur chlorides, NaCl, and preparation from anhydrous solvents. The method selected consisted of reacting ThOCO/sub 3/ with HCl, adding NH/sub 4/Cl, and heating in inert atmosphere to drive off NH/sub 4/Cl. (T.R.H.)
Date: December 17, 1953
Creator: Merlub-Sobel, M.
Partner: UNT Libraries Government Documents Department

Ketene Reactions: I. The Addition of Acid Chlorides to Dimethylketene ; II. The Cycloaddition of Ketenes to Carbonyl Compounds

Description: Part I describes the addition of several acid chlorides to dimethylketene. The resulting 3-ketoacid chlorides were isolated and characterized. Part II describes the cycloaddition of several aldoketenes to chloral. The ketenes were generated in situ by dehydrohalogenation and dehalogenation of appropriately substituted acyl halides.
Date: December 1970
Creator: Smith, Larry
Partner: UNT Libraries

The Vapor Phase Hydrolysis of the Trichlorides of Lanthanum, Praseodymium, Samarium, and Americium

Description: The following report studies the reactions of vapor phase hydrolysis of the trichlorides of lanthanum, praseodymium, samarium, and americium with gas mixtures of HCl and H2O passing over the solid materials mounted on a cantilever-type quartz fiber microbalance. This report calculates the values of the heats and entropies of the reactions, as well as the heat formation of LaCl3, 1254.9 kcal mol-(-1) that was obtained by determining the heat of the solution of La metal in 1.5M HCl.
Date: 1943
Creator: Broido, Abraham
Partner: UNT Libraries Government Documents Department

The Reaction of Hexachloropropylene With Metallic Oxides

Description: Abstract: Twenty-two metallic oxides were refluxed with hexachloropropylene. The anhydrous chlorides or other products formed are described for each oxide. The reactions were particularly vigorous with higher valent oxides of the fifth and sixth group elements.
Date: January 14, 1946
Creator: Pitt, B. M.; Wagner, E. L. & Miller, A. J.
Partner: UNT Libraries Government Documents Department

Fiber Optical Micro-detectors for Oxygen Sensing in Power Plants

Description: A reflection mode fiber optic oxygen sensor that can operate at high temperatures for power plant applications is being developed. The sensor is based on the {sup 3}O{sub 2} quenching of the red emission from hexanuclear molybdenum chloride clusters. Our approach towards immobilizing the potassium salt of the molybdenum cluster, K{sub 2}Mo{sub 6}Cl{sub 14}, at the far end of an optical fiber is to embed the cluster in a thermally cured sol-gel matrix particle. Due to the improved mechanical properties of this approach high temperature sensor measurements were performed up to 100 C. These are promising results for a high temperature fiber optical oxygen sensor based on molybdenum chloride clusters.
Date: September 30, 2006
Creator: Baker, Gregory L.; Ghosh, Ruby N.; Osborn, D. J. & Zhang, Po
Partner: UNT Libraries Government Documents Department