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The Inference of Adsorption from Differential Double Layer Capacitance Measurements

Description: From Abstract : "Dependence of boundary tension and capacitance at the mercury-aqueous 0.1 N HClO4 interface on polarization and organic solute concentration were determined for the colutes n-amyl alcohol and phenol. ... An earlier treatment proposed by this Laboratory based on a (non-thermodynamic) assumption of linear variation of surface charge density with coverage appears adequately justified for inference of fractional surface coverages near the electrocapillary maximum, but must be consi… more
Date: April 26, 1963
Creator: Hansen, Robert S.; Kelsh, Dennis J. & Grantham, D. H.
Partner: UNT Libraries Government Documents Department
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Bismuth

Description: This report provides a broad and in depth discussion of bismuth, discussing the properties of bismuth--including physical, electrochemical, and chemical properties. It then discusses the processes by which bismuth is detected and how bismuth can be separated and isolated, with discussions of dissolution, precipitation, and extraction.
Date: 1960
Creator: Fritz, James S.
Partner: UNT Libraries Government Documents Department
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Chapter 48: Analytical Chemistry of Cobalt

Description: This report provides a detailed discussion of the analytical chemistry of cobalt, including an introduction, the properties of cobalt, the sampling of cobalt-bearing materials, the separation and isolation of cobalt, the detection and identification of cobalt, the determination of cobalt, and the specific methods for determining cobalt.
Date: 1961
Creator: Dale, John M. & Banks, Charles V.
Partner: UNT Libraries Government Documents Department
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Separation of Iron by Liquid-Liquid Column Extraction

Description: From abstract: "Iron(III) can be separated from many elements by extraction from 6 to ͟8M hydrochloric acid. The extraction is carried out by passing the aqueous hydrochloric acid solution through a column packed with 2-octanone adsorbed onto a poly-fluorocarbon resin. Fluoride, phosphate, sulfate or citrate cause no interference. Traces if iron(III) can be separated quantitatively from large amounts of copper(II) or zinc(II); traces of titanium(IV) can be separated from large amounts of iron(II… more
Date: March 21, 1962
Creator: Fritz, James S. (James Sherwood), 1924- & Hedrick, C. E.
Partner: UNT Libraries Government Documents Department
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Radical and Molecular Reaction Mechanisms for (γ, n) Activated c11 Reactions in Liquid Cyclohexane

Description: From abstract: "A study has been made of the yields of gaseous products labeled with C11 from the C12(γ, n) reaction in liquid cyclohexane. The effects of variations in the radiation dose and in the concentration of dissolved iodine during irradiation on the yields of these products were studied in order to elucidate the reaction mechanisms. A reaction model was developed as a method of assessing the relative importance of radical and molecular processes. The data suggest (1) that the formation… more
Date: March 21, 1962
Creator: Rack, Edward P. & Voigt, Adolf F.
Partner: UNT Libraries Government Documents Department
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͟v͟ic-Dioximes as Analytical Reagents

Description: This technical report discusses the synthesis of vic-dioximes, the analysis of vic-dioximes, the structure of vic-dioximes, the structure of metal(II)-vic-dioxime complexes, and analytical applications of this research. The report includes tables and figures that accompany the report's contents and findings.
Date: March 19, 1962
Creator: Banks, Charles V.
Partner: UNT Libraries Government Documents Department
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Analysis of Carbon Monoxide-Nitrogen Mixtures by High Resolution Mass Spectrometry

Description: From abstract: "A single focusing mass spectrometer has been converted into a double focusing instrument. Relatively high resolution is obtained by decreasing the slit widths and minimizing the ion-optic aberrations. A relatively low ion accelerating voltage (2000 volts) is utilized compared to those normally used for high resolution work. The entire construction was performed at these laboratories. Essentially all of the original equipment was reused in the double focusing system. Although the… more
Date: February 1962
Creator: Conzemius, Robert Joseph & Svec, Harry J. (Harry John), 1918-
Partner: UNT Libraries Government Documents Department
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