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Chemical Technology Division Unit Operations Section Monthly Progress Report, September 1961

Description: Nine samples of ThO/sub 2/ -UO/sub 2/ prepared as part of the solgel process development studies showed no consistent effects from small variations in several process parameters. The reaction of methane and copper oxide was studied. Engineering studies of the continuous dissolution of simulated U-Zr-Sn fuels in 6.5 M NH4F, 0.6-1.0 M NH/sub 4/NO/sub 3/, 0.1 M H/sub 2/O/sub 2/ were continued in modified 6-in.-dia. equipment. A total of 1642 kg of U from NaK bonded SRE Core I fuel rods wad dejacke… more
Date: April 1, 1962
Creator: Whatley, M. E.; Haas, P. A.; Horton, R. W.; Ryon, A. D.; Suddath, J. C. & Watson, C. D.
Partner: UNT Libraries Government Documents Department
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Energy-related doctoral scientists and engineers in the United States, 1977

Description: Information is compiled about the number and characteristics of doctoral-level engineers and scientists in primarily energy-related activities. These data are for the year 1977 and are part of the data base for a program of continuing studies on the employment and utilization of all scientists and engineers involved in energy-related activities. Data on mathematics, physics, chemistry, environmental engineering, engineering, life sciences, psychology, and social sciences doctoral degree special… more
Date: April 1, 1980
Partner: UNT Libraries Government Documents Department
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Assessment of the theory and hypotheses of the acidification of watersheds

Description: This report documents and critically assesses the evolution and status of the scientific understanding of the effects of acidic deposition on surface waters. The main conclusion is that the dominant theory of surface-water acidification fails to adequately incorporate many important factors and processes that influence surface water acidity. Some of these factors and processes are not well researched or recognized as being important by most scientists in the aquatic effects research area. 258 r… more
Date: April 1, 1989
Creator: Krug, E.C.
Partner: UNT Libraries Government Documents Department
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The solar flare of 18 August 1979: Incoherent scatter radar data and photochemical model comparisons

Description: Measurements of electron density at seven D-region altidues were made with the Arecibo radar during a Class-X solar flare on 18 August 1979. Measurements of solar x-ray fluxes during the same period were available from the GOES-2 satellite (0.5 to 4 /angstrom/ and 1 to 8 /angstrom/) and from ISEE-3 (in four bands between 26 and 400 keV). From the x-ray flux data we computed ionization rates in the D-region and the associated chemical changes, using a coupled atmospheric chemistry and diffusion … more
Date: April 1, 1988
Creator: Zinn, J.; Sutherland, C. D.; Fenimore, E. E. & Ganguly, S.
Partner: UNT Libraries Government Documents Department
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Crystallographic D-Space Computer Program

Description: D-Space is a computer program which generates indices (hld), tests for space-group extinctions, and calculates d,'' 1/d/sup 2/, sin theta , sin/sup 2/ theta , sin theta / lambda , sin/sub 2/ theta / lambda /sup 2/, theta , and 2 theta for any crystal system and space group, requiring only the unit cell constants as data input. Optional calculations are the single-crystal angle settings, phi and chi, and various Lorentz and Lorentz-polarization corrections. (auth)
Date: April 1962
Creator: Mueller, M. H.; Meyer, E. F. H. & Simonsen, S. H.
Partner: UNT Libraries Government Documents Department
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Influence of nitrogen on the sensitization, corrosion, mechanical, and microstructural properties of austenitic stainless steels. First annual progress report

Description: During this first year of the project, the research effort has concentrated on the electrochemical aspects of the effect of nitrogen on austenitic steels. The status of all the individual project tasks are outlined briefly, and then more detailed results of the electrochemical studies conducted so far are reported. Highlights of this quarter are: (1) nitrogen additions of up to 0.16 wt % retard sensitization of 18Cr-8Ni austenitic stainless steels. However, nitrogen additions to levels above ap… more
Date: April 1, 1982
Creator: Clark, W.A.T. & Macdonald, D.D.
Partner: UNT Libraries Government Documents Department
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Monitoring the materials and chemistry of a geothermal plant

Description: The components of geothermal brines that cause corrosion and scaling problems are reviewed, especially brine pH, CO/sub 2/, H/sub 2/S, oxygen (from air), silicia, calcium, sulfides, and suspended particulates. Instrumental methods for on-line measurement are discussed to show how to keep costs low by operating a geothermal plant from a position of knowledge of what is occurring to the plant materials. The US Department of Energy research and development program in brine chemistry and on-line in… more
Date: April 1, 1988
Creator: Shannon, D.W.
Partner: UNT Libraries Government Documents Department
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Simulation of ethylbenzene dehydrogenation in microporous catalytic membrane reactors

Description: Current state-of-the-art inorganic oxide membranes offer the potential of being modified to yield catalytic properties. The resulting modules may be configured to simultaneously induce catalytic reactions with product concentration and separation in a single processing step. Processes utilizing such catalytically active membrane reactors have the potential for dramatically increasing yield of reactions which are currently limited by either thermodynamic equilibria, product inhibition, or kineti… more
Date: April 1, 1989
Partner: UNT Libraries Government Documents Department
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Precipitation kinetics of a continuous precipitator, with application to the precipitation of ammonium polyuranate

Description: A mathematical model describing the kinetics of continuous precipitation was developed which accounts for crystal nucleation, crystal growth, primary coagulation, and secondary coagulation. Population density distributions, average particle sizes, dominant particle sizes, and suspension density fractions of the crystallites, primary agglomerates, and secondary agglomerates leaving the continuous precipitator can be determined. This kinetic model was applied to the continuous precipitation of am… more
Date: April 1, 1978
Creator: Hoyt, R.C.
Partner: UNT Libraries Government Documents Department
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RADIOISOTOPES AND RADIATION APPLICATIONS. Quarterly Progress Report No. 12

Description: Continued research is reported in the areas of intrinsic radioactive tracers for industrial process control and the effects of structural factors on radioinduced graft polymerization. The use of Be-- Po neutron sources for production of short-lived isotopes is being investigated. Data are included on the effects of target volume, high-Z scattering media, target-isotope concentration, and macroscopic cross-section on speciflc and total activation produced with a 10-curie source. Research on graf… more
Date: April 18, 1962
Creator: Sunderman, D.N. ed.
Partner: UNT Libraries Government Documents Department
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First-year evaluation of a nondestructive assay system for the examination of ORNL TRU waste

Description: The Oak Ridge National Laboratory has been selected as the demonstration site for a new transuranic neutron assay system (NAS) developed at the Los Alamos National Laboratory. In addition, in order to meet specific ORNL program objectives, an upgraded segmented gamma-ray drum scanner has been integrated into the nondestructive assay (NDA) system to serve as a radioisotope identifier and as a quantitative assay backup to the NAS. A verification study, wherein selected waste drums will be emptied… more
Date: April 1, 1984
Creator: Schultz, F. J.; Haff, K. W.; Coffey, D. E.; Norris, L. B.; Caldwell, J. T.; Close, D. A. et al.
Partner: UNT Libraries Government Documents Department
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Analytical Chemistry Division. Annual progress report for period ending December 31, 1981

Description: The functions of the Analytical Chemistry Division fall into three general categories: (1) analytical research, development, and implementation; (2) programmatic research, development and utilization; (3) technical support. The Division is organized into five major sections each of which may carry out any type of work falling into the thre categories mentioned above. Chapters 1 through 5 of this report highlight progress within the five sections which are: analytical methodology; mass and emiss… more
Date: April 1, 1982
Creator: Lyon, W. S.
Partner: UNT Libraries Government Documents Department
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CHEMICAL PROCESSING OF COATED PARTICLE FUELS

Description: BS>Laboratory studies on the processing of graphite-base fuel elements containing pyrolytic carbon- or Al/sub 2/O/sub 3/-coated particles are reviewed. Potential processes for recovering U and Th from irradiated elements include grinding followed by acid leaching, and, burning and subsequent dissolution of the oxide ash. Disintegration in 90% HNO/sub 3/ was briefly evaluated as a method for determining the integrity of coated particles dispersed in graphite matrices. (auth)
Date: April 1, 1962
Creator: Ferris, L.M.
Partner: UNT Libraries Government Documents Department
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Biotechnology for a renewable resources chemicals and fuels industry, biochemical engineering R and D

Description: To establish an effective biotechnology of biomass processing for the production of fuels and chemicals, an integration of research in biochemical engineering, microbial genetics, and biochemistry is required. Reduction of the costs of producing chemicals and fuels from renewable resources will hinge on extensive research in biochemical engineering.
Date: April 1, 1980
Creator: Villet, R.H.
Partner: UNT Libraries Government Documents Department
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Nuclear medicine program progress report for quarter ending December 31, 1991

Description: This report presents information on (1) a new improved synthesis of carrier-free rhenium-188-labeled Re(V) dimercaptosuccinic acid (DMSA) complex as a potential therapeutic agent for treatment of thyroid medullary carcinoma; and (2) the synthesis and evaluation of a series of iodine-125-labeled analogues of altanserine for imaging of serotonin receptors.
Date: April 1, 1992
Creator: Knapp, F. F., Jr.; Ambrose, K. R.; Callahan, A. P.; McPherson, D. W.; Mirzadeh, S.; Srivastava, P. C. et al.
Partner: UNT Libraries Government Documents Department
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Fate of corrosion products released from stainless steel in marine sediments and seawater. Part 3. Calcareous ooze

Description: The physicochemical forms and partitioning of corrosion products released from stainless steel upon exposure to selected environmental conditions is the subject of this investigation. This report describes the influence of calcareous sediment on the rate of release and fate of corrosion products produced when neutron-activated stainless steel specimens were exposed to a Globigerina ooze taken from the Northeast Pacific Ocean. The calcareous ooze used in this study consists largely of planktonic… more
Date: April 1, 1982
Creator: Schmidt, R. L.
Partner: UNT Libraries Government Documents Department
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Americium purification by a combined anion exchange and bidentate organophosphorus solvent extraction process. [Patent application]

Description: Americium is separated from mixtures containing plutonium, other actinides, and other non-lanthamide impurities, by a combined process of anion exchange resin sorption to remove plutonium, and a bidentate organophosphorus solvent extraction of americium of the anion exchange resin effluent. Dihexyl-N,N-diethylcarbamylmethylenephosphonate is a preferred solvent. The initial mixture may be subjected to a cation exchange operation to remove monovalent impurities. The process is especially effectiv… more
Date: April 10, 1981
Creator: Navratil, J.D. & Martella, L.L.
Partner: UNT Libraries Government Documents Department
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Fundamental studies of catalytic processing of synthetic liquids

Description: This project revolves around understanding the fundamental processes involved in the catalytic removal of harmful oxygenated organics present in coal liquids. We will model the complex type of sulfided Mo catalyst proposed for these reactions with a simple single crystal surfaces that display a controlled range and number of reaction sites and can be extensively characterized by surface science techniques.
Date: April 10, 1990
Creator: Watson, P. R.
Partner: UNT Libraries Government Documents Department
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Simultaneous analysis of uranium and nitrate

Description: A direct spectrophotometric method has been developed for the determination of 20 to 200 g/l of uranium in the presence of 3 to 5 M nitric acid. A dual-wavelength analysis is used to eliminate the enhancing effect of nitrate ion on the uranium visible spectra. The precision and accuracy of the simultaneous analysis of uranium and nitrate were compared using combinations of the four uranium wavelength maxima, occurring at 426, 416, 403 and 359 nm. Calculations based on 426 and 416 nm data yielde… more
Date: April 1, 1978
Creator: Bostick, D.T.
Partner: UNT Libraries Government Documents Department
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Electrochemistry applied to biomass. Progress report, October 1980-September 1981

Description: The electrochemical conversion of biomass-derived compounds, obtained through thermochemical pretreatments, into valuable organic chemicals, petrochemical substitutes, and energy-intensive chemicals is investigated. A hardwood-derived lignin obtained from ethanol extraction of the explosively depressurized aspen has been investigated. We have partially characterized this lignin material, and have also submitted it to electrolyses under controlled potential. The electrolytic conditions employed … more
Date: April 1, 1982
Creator: Chum, H. L.
Partner: UNT Libraries Government Documents Department
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