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REVERSIBLE CONVERSION BETWEEN CHEMICAL AND ELECTRICAL ENERGIES CATALYZED BY Ru COMPLEXES AIMED TO CONSTRUCT SUSTAINABLE SOCIETY.

Description: The present study demonstrates that [Ru{sup II}(NH{sub 3})(q)(trpy)]{sup +} has an ability to oxidize alcohols catalytically under very mild conditions under electrolysis at +0.35 V in MeOH. The elucidation of the reaction mechanisms in the alcohol-oxidation is underway.
Date: November 30, 2007
Creator: TANAKA,K.; WADA, T.; FUJITA, E. & MUCKERMAN, J.
Partner: UNT Libraries Government Documents Department
open access

Design, Synthesis and Mechanistic Evaluation of Iron-Based Catalysis for Synthesis Gas Conversion to Fuels and Chemicals

Description: This project extends previously discovered Fe-based catalysts to hydrogen-poor synthesis gas streams derived from coal and biomass sources. These catalysts have shown unprecedented Fischer-Tropsch synthesis rates and selectivities for synthesis gas derived from methane. During the first reporting period, we certified a microreactor, installed required analytical equipment, and reproduced synthetic protocols and catalytic results previously reported. During the second reporting period, we prepar… more
Date: March 31, 2007
Creator: Ishikawa, Akio; Ojeda, Manuel; Yao, Nan & Iglesia, Enrique
Partner: UNT Libraries Government Documents Department
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