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The development of the shadow analysis team concept

Description: Part II, Section E, Paragraphs 52-55 of the {open_quotes}Verification Annex{close_quotes} (Annex 2) of the Chemical Weapons Convention (CWC) provides the general rights and obligations of both the Inspected State Party (ISP) and the Inspection Team (IT) as to the collection and analysis of samples. In summary, the inspection team has the right to request the collection of samples which will be collected by the ISP unless the decision is made by the ISP to allow the inspectors to collect them. Samples will, if possible, be analyzed at the inspection site, with the assistance of the ISP if requested by the IT. The ISP has the right to retain portions all collected samples. Samples may be sent off-site for independent analysis if deemed necessary. These rights are modified in the case of {open_quotes}Challenge Inspections{close_quotes} by the {open_quotes}Managed Access{close_quotes} Provisions of Part X, Section C, Paragraphs 4648 which specifies that sample collection is to be negotiated between the Inspection Team and the Inspected State Party. In order to assist the ISP in fulfilling its obligation to assist the IT in determining compliance, and in preserving its rights to protect sensitive information not relevant to the CWC, we propose to establish the Army Material Command Treaty Laboratory (AMCTL) Shadow Analysis Team.
Date: November 1, 1995
Creator: McGuire, R.R.
Partner: UNT Libraries Government Documents Department

Reevaluation of 1999 Health-Based Environmental Screening Levels (HBESLs) for Chemical Warfare Agents

Description: This report evaluates whether new information and updated scientific models require that changes be made to previously published health-based environmental soil screening levels (HBESLs) and associated environmental fate/breakdown information for chemical warfare agents (USACHPPM 1999). Specifically, the present evaluation describes and compares changes that have been made since 1999 to U.S. Environmental Protection Agency (EPA) risk assessment models, EPA exposure assumptions, as well as to specific chemical warfare agent parameters (e.g., toxicity values). Comparison was made between screening value estimates recalculated with current assumptions and earlier health-based environmental screening levels presented in 1999. The chemical warfare agents evaluated include the G-series and VX nerve agents and the vesicants sulfur mustard (agent HD) and Lewisite (agent L). In addition, key degradation products of these agents were also evaluated. Study findings indicate that the combined effect of updates and/or changes to EPA risk models, EPA default exposure parameters, and certain chemical warfare agent toxicity criteria does not result in significant alteration to the USACHPPM (1999) health-based environmental screening level estimates for the G-series and VX nerve agents or the vesicant agents HD and L. Given that EPA's final position on separate Tier 1 screening levels for indoor and outdoor worker screening assessments has not yet been released as of May 2007, the study authors find that the 1999 screening level estimates (see Table ES.1) are still appropriate and protective for screening residential as well as nonresidential sites. As such, risk management decisions made on the basis of USACHPPM (1999) recommendations do not require reconsideration. While the 1999 HBESL values are appropriate for continued use as general screening criteria, the updated '2007' estimates (presented below) that follow the new EPA protocols currently under development are also protective. When EPA finalizes and documents a position on the matter of indoor and outdoor worker screening ...
Date: May 1, 2007
Creator: Watson, Annetta Paule & Dolislager, Fredrick G
Partner: UNT Libraries Government Documents Department

Implementing the chemical weapons convention: The nuts and bolts of compliance

Description: This paper is a presentation prepared for the American Bar Association in which the author discusses the issue of rights to privacy in the United States in the face of implementing the Chemical Weapons Convention inspections. The author points out that there are no clear precedents in law which deal with all the issues which will result from international inspections for verification which are required by the treaty. In particular as inspections tread on the issue of personal rights or private property there is a fairly ill defined legal area which needs to be developed to allow such inspections in the face of constitutional guarantees.
Date: March 1, 1995
Creator: Tanzman, E.A.
Partner: UNT Libraries Government Documents Department

Destruction of VX by aqueous-phase oxidation using peroxydisulfate (direct chemical oxidation)

Description: Chemical warfare agents may be completely destroyed (converted to H{sub 2}O, CO{sub 2}, salts) by oxidation at 90--100 C using acidified ammonium peroxydisulfate, with recycle of NH{sub 4}SO{sub 4} byproduct. The process requires no toxic or expended catalysts and produces no secondary wastes other than the precipitated inorganic content of the agents. To determine oxidative capability of peroxydisulfate at low reductant contents, we measured rate data for oxidation of 20 diverse compounds with diverse functional groups; 4 of these have bonds similar to those found in VX, HD, and GB. On an equivalence basis, integral first-order rate constants for 100 C oxidation are 0.012{plus_minus}0.005 min{sup {minus}1} for di-isopropyl-methyl-phosphonate, methyl phosphonic acid, triethylamine, and 2,2{prime}-thiodiethanol at low initial concentrations of 50 ppM(as carbon) and pH 1.5. To provide scale-up equations for a bulk chemical agent destruction process, we measured time-dependent oxidation of bulk model chemicals at high concentrations (0.5 N) and developed and tested a quantitative model. A practical process for bulk VX destruction would begin with chemical detoxification by existing techniques (eg, hydrolysis or mild oxidation using oxone), followed by mineralization of the largely detoxified products by peroxydisulfate. Secondary wastes would be avoided by use of commercial electrolysis equipment to regenerate the oxidant. Reagent requirements, mass balance and scaleup parameters are given for VX destruction, using peroxydisulfate alone, or supplemented with hydrogen peroxide. For the use of 2.5 N peroxydisulfate as the oxidant, a 1 m{sup 3} digester will process about 200 kg (as C) per day. The process may be extended to total destruction of HD and hydrolysis products of G agents.
Date: October 11, 1995
Creator: Cooper, J.F.; Krueger, R. & Farmer, J.C.
Partner: UNT Libraries Government Documents Department

Pathways for the Oxidation of Sarin in Urban Atmospheres

Description: Terrorists have threatened and carried out chemicalhiological agent attacks on targets in major cities. The nerve agent sarin figured prominently in one well-publicized incident. Vapors disseminating from open containers in a Tokyo subway caused thousands of casualties. High-resolution tracer transport modeling of agent dispersion is at hand and will be enhanced by data on reactions with components of the urban atmosphere. As a sample of the level of complexity currently attainable, we elaborate the mechanisms by which sarin can decompose in polluted air. A release scenario is outlined involving the passage of a gas-phase agent through a city locale in the daytime. The atmospheric chemistry database on related organophosphorus pesticides is mined for rate and product information. The hydroxyl,radical and fine-mode particles are identified as major reactants. A review of urban air chernistry/rnicrophysics generates concentration tables for major oxidant and aerosol types in both clean and dirty environments. Organic structure-reactivity relationships yield an upper limit of 10-1' cm3 molecule-' S-* for hydrogen abstraction by hydroxyl. The associated midday loss time scale could be as little as one hour. Product distributions are difficult to define but may include nontoxic organic oxygenates, inorganic phosphorus acids, sarin-like aldehydes, and nitrates preserving cholinergic capabilities. Agent molecules will contact aerosol surfaces in on the order of minutes, with hydrolysis and side-chain oxidation as likely reaction channels.
Date: November 1, 1998
Creator: Streit, Gerald E.; Bossert, James E.; Gaffney, Jeffrey S.; Reisner, Jon; McNair, Laurie A.; Brown, Michael et al.
Partner: UNT Libraries Government Documents Department

Contamination source review for Building E3236, Edgewood Area, Aberdeen Proving Ground, Maryland

Description: The US Army Aberdeen Proving Ground (APG) commissioned Argonne National Laboratory (ANL) to conduct a contamination source review to identify and define areas of toxic or hazardous contaminants and to assess the physical condition and accessibility of APG buildings. The information obtained from the review may be used to assist the US Army in planning for the future use or disposition of the buildings. The contamination source review consisted of the following tasks: historical records search, physical inspection, photographic documentation, geophysical investigation, and review of available records regarding underground storage tanks associated with each building. This report provides the results of the contamination source review for Building E3236. Many of the APG facilities constructed between 1917 and the 1960s are no longer used because of obsolescence and their poor state of repair. Because many of these buildings were used for research, development, testing, and/or pilot- scale production of chemical warfare agents and other military substances, the potential exists for portions of the buildings to be contaminated with these substances, their degradation products, and other laboratory or industrial chemicals. These buildings and associated structures or appurtenances may contribute to environmental concerns at APG.
Date: September 1, 1995
Creator: Zellmer, S.D.; Smits, M.P.; Draugelis, A.K.; Glennon, M.A.; Rueda, J. & Zimmerman, R.E.
Partner: UNT Libraries Government Documents Department

Remedial investigation sampling and analysis plan for J-Field, Aberdeen Proving Ground, Maryland: Volume 2, Quality Assurance Project Plan

Description: J-Field encompasses about 460 acres at the southern end of the Gunpowder Neck Peninsula in the Edgewood Area of APG (Figure 2.1). Since World War II, the Edgewood Area of APG has been used to develop, manufacture, test, and destroy chemical agents and munitions. These materials were destroyed at J-Field by open burning and open detonation (OB/OD). For the purposes of this project, J-Field has been divided into eight geographic areas or facilities that are designated as areas of concern (AOCs): the Toxic Burning Pits (TBP), the White Phosphorus Burning Pits (WPP), the Riot Control Burning Pit (RCP), the Robins Point Demolition Ground (RPDG), the Robins Point Tower Site (RPTS), the South Beach Demolition Ground (SBDG), the South Beach Trench (SBT), and the Prototype Building (PB). The scope of this project is to conduct a remedial investigation/feasibility study (RI/FS) and ecological risk assessment to evaluate the impacts of past disposal activities at the J-Field site. Sampling for the RI will be carried out in three stages (I, II, and III) as detailed in the FSP. A phased approach will be used for the J-Field ecological risk assessment (ERA).
Date: March 1, 1995
Creator: Prasad, S.; Martino, L. & Patton, T.
Partner: UNT Libraries Government Documents Department

Investigations of emergency destruction methods for recovered, explosively configured, chemical warfare munitions: Interim emergency destruction methods - evaluation report

Description: At the request of the U.S. Army Non-Stockpile Chemical Material Office, the Sandia Explosives Containment System Design Team investigated mature destruction systems for destroying recovered chemical warfare munitions (CWM). The goal of the investigations was to identify and examine available techniques for the destruction of recovered CWM. The result of this study is a recommendation for an interim solution, a solution for use on any munitions found while an optimal, long-term solution is developed. Sandia is also performing the long-term solution study to develop a system that destroys CWM, contains the blast and fragments, and destroys the chemical agent without insult to the environment.
Date: July 1, 1995
Creator: Baer, M.R.; Cooper, P.W. & Kipp, M.E.
Partner: UNT Libraries Government Documents Department

Implementing the chemical weapons convention

Description: In 1993, as the CWC ratification process was beginning, concerns arose that the complexity of integrating the CWC with national law could cause each nation to implement the Convention without regard to what other nations were doing, thereby causing inconsistencies among States as to how the CWC would be carried out. As a result, the author's colleagues and the author prepared the Manual for National Implementation of the Chemical Weapons Convention and presented it to each national delegation at the December 1993 meeting of the Preparatory Commission in The Hague. During its preparation, the Committee of CWC Legal Experts, a group of distinguished international jurists, law professors, legally-trained diplomats, government officials, and Parliamentarians from every region of the world, including Central Europe, reviewed the Manual. In February 1998, they finished the second edition of the Manual in order to update it in light of developments since the CWC entered into force on 29 April 1997. The Manual tries to increase understanding of the Convention by identifying its obligations and suggesting methods of meeting them. Education about CWC obligations and available alternatives to comply with these requirements can facilitate national response that are consistent among States Parties. Thus, the Manual offers options that can strengthen international realization of the Convention's goals if States Parties act compatibly in implementing them. Equally important, it is intended to build confidence that the legal issues raised by the Convention are finite and addressable. They are now nearing competition of an internet version of this document so that interested persons can access it electronically and can view the full text of all of the national implementing legislation it cites. The internet address, or URL, for the internet version of the Manual is http: //www.cwc.ard.gov. This paper draws from the Manual. It comparatively addresses approximately thirty implementing ...
Date: December 7, 1999
Creator: Kellman, B. & Tanzman, E. A.
Partner: UNT Libraries Government Documents Department

Steps towards universality of the Chemical Weapons Convention: How can Africa contribute?

Description: Universality is a fundamental principal of the Chemical Weapons Convention (CWC). It suffuses the fabric of the Convention, found not only in the very first ringing clauses of Article I, but also in the many technical details of its Annexes and Schedules. Consequently, universality is a topic on which commentary is appropriate from all quarters. The author offers his personal views as a lawyer on this important matter in the hope that, this distinguished audience may gain a perspective not available from practitioners of other professions. The views expressed in this paper are those of the author alone, and do not represent the position of the government of the US or of any other institution.
Date: November 2, 1999
Creator: Tanzman, E.
Partner: UNT Libraries Government Documents Department

Expedient Respiratory and Physical Protection: Does a Wet Towel Work to Prevent Chemical Warfare Agent Vapor Infiltration?

Description: The purpose of this paper is to examine the effectiveness of expedient protection strategies to reduce exposure to vapors from chemical warfare agents. This includes an examination of the physical and the psychological effectiveness of measures such as using a wet towel to seal a door jam against the infiltration of chemicals while sheltering in place or to provide expedient respiratory protection. Respiratory protection for civilians has never been considered a viable option for population protection in the CSEPP. Problems of storage, ability to effectively don respirators, and questionable fit have been primary factors in rejecting this option. Expedient respiratory protection seems to offer little benefits for population protection for chemical agent vapors. Furthermore, using wet towels as a vapor barrier at the bottom of a door should be discouraged. The wetted towel provides no vapor filtration and its effectiveness in infiltration reduction is unknown. Taping the bottom of the door will still likely provide greater infiltration reduction and is recommended as the current method for use in sheltering.
Date: August 30, 2002
Creator: Sorensen, J. H.
Partner: UNT Libraries Government Documents Department

National measures under the chemical weapons convention to protect confidential business information and compensate for its loss

Description: This report contains a discussion presented at the Regional Seminar on the National Authority and the Chemical Weapons Convention. Measures to protect confidential business information and compensation for information which has not been sufficiently protected is discussed.
Date: July 1, 1995
Creator: Tanzman, E.A. & Kellman, B.
Partner: UNT Libraries Government Documents Department

Infrared microcalorimetric spectroscopy using uncooled thermal detectors

Description: The authors have investigated a novel infrared microcalorimetric spectroscopy technique that can be used to detect the presence of trace amounts of target molecules. The chemical detection is accomplished by obtaining the infrared photothermal spectra of molecules absorbed on the surface of an uncooled thermal detector. Traditional gravimetric based chemical detectors (surface acoustic waves, quartz crystal microbalances) require highly selective coatings to achieve chemical specificity. In contrast, infrared microcalorimetric based detection requires only moderately specific coatings since the specificity is a consequence of the photothermal spectrum. They have obtained infrared photothermal spectra for trace concentrations of chemical analytes including diisopropyl methylphosphonate (DIMP), 2-mercaptoethanol and trinitrotoluene (TNT) over the wavelength region2.5 to 14.5 {micro}m. They found that in the wavelength region 2.5 to 14.5 {micro}m DIMP exhibits two strong photothermal peaks. The photothermal spectra of 2-mercaptoethanol and TNT exhibit a number of peaks in the wavelength region 2.5 to 14.5 {micro}m and the photothermal peaks for 2-mercaptoethanol are in excellent agreement with infrared absorption peaks present in its IR spectrum. The photothermal response of chemical detectors based on microcalorimetric spectroscopy has been found to vary reproducibly and sensitively as a consequence of adsorption of small number of molecules on a detector surface followed by photon irradiation and can be used for improved chemical characterization.
Date: October 1, 1997
Creator: Datskos, P.G.; Rajic, S.; Datskou, I. & Egert, C.M.
Partner: UNT Libraries Government Documents Department

The Hydrolysis of Di-Isopropyl Methylphosphonate in Ground Water

Description: Di-isopropyl methylphosphonate (DIMP) is a byproduct from the manufacture of the nerve agent Sarin. The persistence of DIMP in the ground water is an important question in evaluating the potential environmental impacts of DIMP contamination. The half-life of DIMP in ground water at 10 deg C was estimated to be 500 years with a 95% confidence interval of 447 to 559 years from measurements of the hydrolysis rates at temperatures between 70 to 98 deg C.Extrapolation of the kinetics to 10 deg C used the Arrhenius equation, and calculation of the half-life assumed first-order kinetics. Inorganic phosphate was not detected.
Date: December 31, 1997
Creator: Sega, G.A., Tomkins, B.A., Griest, W.H., Bayne, C.K.
Partner: UNT Libraries Government Documents Department

Legal aspects of national implementation of the Chemical Weapons Convention national authority provisions. Workshop I: The National Authority

Description: This seminar is an excellent opportunity for all attendees to learn from each other about how the Chemical Weapons Convention (CWC) can become a foundation of arms control in Africa and around the world. The author discusses legal aspects of implementing the CWC`s national authority provisions. These implementing measures are universal, applying not only to the few States Parties that will declare and destroy chemical weapons, but also to the many States Parties that have never had a chemical weapons programme. This new need for national measures to implement multilateral arms control agreements has generated unease due to a perception that implementation may be burdensome and at odds with national law. In 1993, concerns arose that the complexity of integrating the treaty with national law would cause each nation to effectuate the Convention without regard to what other nations were doing, thereby engendering significant disparities in implementation steps among States Parties. As a result, the author prepared the Manual for National Implementation of the Chemical Weapons Convention late last year and presented it to each national delegation at the December 1993 meeting of the Preparatory Commission in The Hague. Here the author discusses progress among several States in actually developing implementing measures for the Convention`s national authority requirements. CWC legislation from Australia, Germany, Norway, South Africa, and Sweden were available at this writing in English through the PTS. Of course, it is important to note that this brief survey necessarily omitted examination of the existing {open_quotes}background{close_quotes} of other, related domestic laws that these signatories might also have adopted that affect CWC implementation. The author hopes that his brief review will give delegations a flavor of the choices that exist for national implementation of the CWC.
Date: May 9, 1995
Creator: Tanzman, E. A. & Kellman, B.
Partner: UNT Libraries Government Documents Department

Compilation of existing chemical agent guidelines table as of September 1997

Description: Public Law 99-145 requires the US Department of the Army to dispose of the lethal chemical agents and munitions stockpile stored at eight Army installations throughout the continental US and Johnston Atoll in the Pacific. Recognition by the US Army that a potential threat to the public from continued storage was greater than the threat from transportation and demilitarization of chemical agents gave rise to the Chemical Stockpile Emergency Preparedness Program (CSEPP). CSEPP is a community emergency preparedness program complementing the Department of Defense`s initiative to destroy domestic stockpiles of aged chemical warfare agent munitions. The Federal Emergency Management Agency (FEMA) and the US Army jointly coordinate and direct the CSEPP. The Compilation of Existing Chemical Agent Guidelines Table was developed under the direction of FEMA and the US Army Center for Health Promotion and Preventive Medicine (USACHPPM). The purpose of this Table is to identify established chemical warfare agent guidelines, standards, and interim standards as of September 1997, and place them in an explanatory context for ready use by the CSEPP community. This Table summarizes and organizes information from numerous agencies and review bodies responsible for recommending exposure guidelines [e.g., The Centers for Disease Control and Prevention (CDC), Committee on Toxicology (COT), Environmental Protection Agency (EPA), FEMA, Army and other federal agencies]. This Table provides references for the interested reader, but does not provide data and assumptions on which exposure guidelines were based, or comment on the rationale or appropriateness of the given values. To do so is beyond the scope of work for this task.
Date: August 1, 1998
Creator: Foust, C.B.
Partner: UNT Libraries Government Documents Department

A guide to the selection of personal protective equipment for use in responding to a release of chemical warfare agents

Description: Recognition by the US Army that a potential threat to the public from continued storage was potentially as great a threat as from transportation and the final demilitarization of chemical agents gave rise to the Chemical Stockpile Emergency Preparedness Program (CSEPP). CSEPP is a civilian community emergency preparedness program complementing the Department of Defense`s initiative to destroy domestic stockpiles of aged chemical warface munitions. An incident involving chemical warfare agents requires a unique hazardous materials (HAZMAT) response. As with any HAZMAT event, federal regulations prescribe that responders must be protected from exposure to the chemical agents. But unlike other HAZMAT events, special considerations govern the selection of personal protective equipment (PPE). PPE includes all clothing, respirators and detection equipment used to respond to a chemical release. PPE can differ depending on whether responders are military or civilian personnel. FEMA requested that ORNL create training materials for CSEPP participants. These training materials were to provide information on a variety of topics and answer questions that a typical CSEPP participant might ask, including the following: how did the Army select the CSEPP recommended ensemble (i.e., protective clothing, respiratory equipment, and detection equipment); how does the CSEPP participant know this ensemble is the right PPE for chemical warfare agents and will actually protect him; what are the concept of operations and work rules? Does one need to know what the CSEPP concept of operations and work rules include? This report describes the training document ORNL created.
Date: October 1, 1997
Creator: Foust, C.B.
Partner: UNT Libraries Government Documents Department

Mobile munitions assessment system design, testing, operational experience

Description: The remnants of America`s chemical weapons program exist at more than 200 sites in the United States. The U.S. Army`s Project Manager for Non-stockpile Chemical Material (PMNSCM) has the responsibility for the remediation of non-stockpile chemical warfare material (CWM). PMNSCM must respond to a variety of situations involving discovered, recovered or buried material. This response requires unique hardware capabilities to characterize, assess, and provide information to develop plans for disposing of the material. PMNSCM sponsored the development of a Mobile Munitions Assessment System (MMAS) at the Idaho National Engineering and Environmental Laboratory (INEEL) to meet the need to characterize and assess non-stockpile chemical warfare material. The MMAS equipment is capable of distinguishing CWM from conventional munitions, identifying the agent fill and level, and assessing the status of the firing train. The MMAS has a data processing, collection, and storage subsystem and a communications link to a Dugway Proving Ground (DPG) database. A typical data package includes X-rays, elemental spectra, weather data, physical descriptions, photographs, video, etc. The MMAS data will be used by the Army`s Munition Assessment and Review Board (MARB) to help determine the appropriate methods and safeguards necessary to store, transport, and dispose of non-stockpile CWM.
Date: August 1, 1997
Creator: Watts, K.D.; Snyder, A.M. & Rowe, L.C.
Partner: UNT Libraries Government Documents Department

An analysis of Chemical Stockpile Emergency Preparedness Program exercise results. Volume 2: Preliminary evaluation and analysis of CSEPP exercise database

Description: This study investigated the quality and usefulness of the information in the Chemical Stockpile Emergency Preparedness Program (CSEPP) exercise database. It incorporates the results of two separate analytical efforts. The first effort investigated the process of assigning standardized codes to issues identified in CSEPP exercise reports. A small group of issues was coded independently by each of several individuals, and the results of the individual codings were compared. Considerable differences were found among the individuals` codings. The second effort consisted of a statistical multivariate analysis, to investigate whether exercise issues are evenly distributed among exercise tabs, sites, and objectives. It was found that certain tabs, sites, and objectives were disproportionately associated with problem areas in exercises. In some cases, these problem areas have persisted over time, but in other cases they have undergone significant shifts over the time span of the investigation. The study concludes that the database can be a useful resource for analyzing problem areas and setting priorities for CSEPP program resources. However, some further analyses should be performed in order to more fully explore the data and increase confidence in the results.
Date: June 1, 1998
Creator: Wernette, D. & Lerner, K.
Partner: UNT Libraries Government Documents Department

RCRA delisting of agent-decontaminated waste and remediation waste at Dugway Proving Ground: A program update

Description: In July 1988, the state of Utah issued regulations that declared residues resulting from the demilitarization, treatment, and testing of military chemical agents to be hazardous wastes. These residues were designated as corrosive, reactive, toxic, and acute hazardous (Hazardous Waste No. F999). These residues are not listed by the U.S. Environmental Protection Agency (EPA) as hazardous waste under the Resource Conservation and Recovery Act (RCRA), which is the primary law governing management of hazardous waste in the United States. The RCRAI regulations (40 CFR 260-280), the Utah Administrative Code (R-315), and other state hazardous waste programs list specific wastes as hazardous but allow generators to petition the regulator to {open_quotes}delist{close_quotes} if it can be demonstrated that such wastes are not hazardous. In 1994, the U.S. Army Test and Evaluation Command FECOM initiated a project with the Argonne National Laboratory (Argonne) to demonstrate that certain categories of F999 residues are not hazardous waste and to achieve delisting. The initial focus is on delisting agent-decontaminated residues and soil with a history of contamination at the U.S. Army Dugway Proving Ground (DPG), Utah. An overview of the DPG delisting program was presented at the 1995 American Defense Preparedness Association Environmental Symposium. Since that time, much progress has been made. The purpose of this paper is to review the DPG delisting program and discuss overall progress. Emphasis is placed on progress with regard to analytical methods that will be used to demonstrate that the target residues do not contain hazardous amounts of chemical agent.
Date: March 1, 1996
Creator: Kimmell, T. A.; Anderson, A. W. & O`Neill, H. J.
Partner: UNT Libraries Government Documents Department

Contamination source review for Building E6891, Edgewood Area, Aberdeen Proving Ground, Maryland

Description: The US Army Aberdeen Proving Ground (APG) commissioned Argonne National Laboratory (ANL) to conduct a contamination source review to identify and define areas of toxic or hazardous contaminants and to assess the physical condition and accessibility of various APG buildings. This report provides the results of the contamination source review for Building E6891. The information obtained from this review may be used to assist the US Army in planning for the future use or disposition of the buildings. The contamination source review consisted of the following tasks: historical records search, physical inspection, photographic documentation, geophysical investigation, and collection of air samples. This building is part of the Lauderick Creek Concrete Slab Test Site, located in the Lauderick Creek Area in the Edgewood Area. Many of the APG facilities constructed between 1917 and the 1960s are no longer used because of obsolescence and their poor state of repair. Because many of these buildings were used for research, development, testing, and/or pilot-scale production of chemical warfare agents and other military substances the potential exists` for portions of the buildings to be contaminated with these substances, their degradation products, and other laboratory or industrial chemicals. These buildings and associated structures or appurtenances may contribute to environmental concerns at APG.
Date: September 1, 1995
Creator: Zellmer, S.D.; Draugelis, A.K.; Rueda, J. & Zimmerman, R.E.
Partner: UNT Libraries Government Documents Department

Development of land disposal restrictions for military chemical agent-associated waste

Description: In July 1988, the State of Utah, Department of Solid and Hazardous Waste (DSHW) listed certain military chemical agents as hazardous waste, as well as residues resulting from the demilitarization, treatment, and testing of these chemicals. These materials are listed as hazardous waste in Utah, but are not listed as hazardous wastes under the Federal Resource Conservation and Recovery Act (RCRA), the primary law governing management of hazardous waste in the United States. Pursuant to the 1984 Hazardous and Solid Waste Amendments (HSWA) to RCRA, the U.S. Environmental Protection Agency (EPA) has established Land Disposal Restriction (LDR) treatment standards for most categories of hazardous wastes. However, considering that EPA has not listed chemical agent-associated wastes as hazardous waste under RCRA, LDR treatment standards have not been established specifically for these wastes. In February 1995, the DSHW announced a regulatory initiative to develop LDRs for chemical agent-associated wastes and solicited data and information from the U.S. Army to support a rulemaking effort. The Army`s Chemical and Biological Defense Command (CBDCOM) was designated the lead agency for the Army to assist the DSHW in developing the rule. CBDCOM established the U.S. Army Land Disposal Restrictions Utah Group (LDRUG) and initiated a project with Argonne National Laboratory to support the LDRUG. The focus is on providing the state with accurate and up-to-date data and information to support the rulemaking and the establishment of LDRs. The purpose of this paper is to review the general direction of the proposed rule and to discuss overall progress. Potential impacts of the imposition of LDRs on the management of agent-associated wastes are also reviewed.
Date: April 1, 1997
Creator: Kimmell, T.A.; Anderson, A.W. & Rosenblatt, D.H.
Partner: UNT Libraries Government Documents Department

Solid Phase Microextraction and Miniature Time-of-Flight Mass Spectrometer

Description: A miniature mass spectrometer, based on the time-of-flight principle, has been developed for the detection of chemical warfare agent precursor molecules. The instrument, with minor modifications, could fulfill many of the needs for sensing organic molecules in various Defense Programs, including Enhanced Surveillance. The basic footprint of the instrument is about that of a lunch box. The instrument has a mass range to about 300, has parts-per-trillion detection limits, and can return spectra in less than a second. The instrument can also detect permanent gases and is especially sensitive to hydrogen. In volume, the device could be manufactured for under $5000.
Date: January 26, 1999
Creator: Hiller, j.m.
Partner: UNT Libraries Government Documents Department

Emergency destruction system for recovered chemical munitions

Description: At the request of the US Army Project Manager for Non-Stockpile Chemical Materiel, Sandia National Laboratories is developing a transportable system for destroying recovered, explosively configured, chemical warfare munitions. The system uses shaped charges to access the agent and burster followed by chemical neutralization to destroy them. The entire process takes place inside a sealed pressure vessel. In this paper, they review the design, operation, and testing of a prototype system capable of containing up to one pound of explosive.
Date: April 1, 1998
Creator: Shepodd, T.J.; Stofleth, J.H. & Haroldsen, B.L.
Partner: UNT Libraries Government Documents Department