Multiresonant Spectroscopy and the High-Resolution Threshold Photoionization of Combustion Free Radicals
Description:
This report describes the results of a program of research on the thermochemistry, spectroscopy and intramolecular relaxation dynamics of the combustion intermediate, HCO. We prepare this radical from acetaldehyde as a photo-precursor in a differentially pumped laser-ionization source quadrupole mass spectrometer. Using a multiresonant spectroscopic technique established in our laboratory, we select individual rotational states and overcome Franck-Condon barriers associated with neutral-to-cati…
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Date:
September 7, 2005
Creator:
Grant, Edward R.
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Partner:
UNT Libraries Government Documents Department