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Diosmacycloalkanes as models for the formation of hydrocarbons from surface methylenes

Description: We have obtained a neutron diffraction data set for Os{sub 2}(CO){sub 8}({mu}-C{sub 2}H{sub 4}). While the structure is still being solved, it is already clear that the hybridization at both of the ethylene carbons is sp{sup 3}. Our first interpretation of our liquid crystal NMR results had suggested a very acute H-C-H angle. We have also obtained {sup 13}C liquid crystal data for Os{sub 2}(CO){sub 8}({mu}-C{sub 2}H{sub 4}). Liquid crystal NMR ({sup 13}C as well as {sup 1}H) spectra have been o… more
Date: January 1, 1989
Creator: Norton, J.R.
Partner: UNT Libraries Government Documents Department
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Overburden Characterization and Post-Burn Study of the Hanna Iv, Underground Coal Gasification Site, Wyoming, and Comparison to Other Wyoming Ucg Sites

Description: Analysis of 21 post-burn cores taken from the Hanna IV UCG site allows 96 m (315 ft) of overburden to be subdivided into four local stratigraphic units. The 7.6 m (25 ft) thick Hanna No. 1 coal seam is overlain by a laterally discontinuous, 3.3 m (11 ft) thick shaley mudstone (Unit A') in part of the Hanna IV site. A more widespread, 30 m (90 ft) thick well-indurated sandstone (Unit A) overlies the A' unit. Unit A is the roof rock for both of the Hanna IV cavities. Overlying Unit A is a 33 m (1… more
Date: November 1, 1984
Creator: Marcouiller, B.A.; Burns, L.K. & Ethridge, F.G.
Partner: UNT Libraries Government Documents Department
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Grassland/Atmosphere Response to Changing Climate: Coupling Regional and Local Scales. Final Report

Description: The objectives of the study were: to evaluate the response of grassland ecosystems to atmospheric change at regional and site scales, and to develop multiscaled modeling systems to relate ecological and atmospheric models with different spatial and temporal resolutions. A menu-driven shell was developed to facilitate use of models at different temporal scales and to facilitate exchange information between models at different temporal scales. A detailed ecosystem model predicted that C{sub 3} te… more
Date: October 1, 1993
Creator: Coughenour, M. B.; Kittel, T. G. F.; Pielke, R. A. & Eastman, J.
Partner: UNT Libraries Government Documents Department
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Diosmacycloalkanes as models for the formation of hydrocarbons from surface methylenes. Progress report, April 1, 1988--March 31, 1989

Description: We have obtained a neutron diffraction data set for Os{sub 2}(CO){sub 8}({mu}-C{sub 2}H{sub 4}). While the structure is still being solved, it is already clear that the hybridization at both of the ethylene carbons is sp{sup 3}. Our first interpretation of our liquid crystal NMR results had suggested a very acute H-C-H angle. We have also obtained {sup 13}C liquid crystal data for Os{sub 2}(CO){sub 8}({mu}-C{sub 2}H{sub 4}). Liquid crystal NMR ({sup 13}C as well as {sup 1}H) spectra have been o… more
Date: January 1, 1989
Creator: Norton, J. R.
Partner: UNT Libraries Government Documents Department
open access

Capillary discharge extreme ultraviolet lasers. Progress report, December 15, 1991--December 14, 1992

Description: The project objective is to explore the generation of soft X-ray laser radiation in a plasma column created by a fast capillary discharge. The proposed capillary lasing scheme offers the potential for compact, simple and efficient soft X-ray laser sources. For this purpose a compact, fast pulse generator which produces 100 kA current pulses with a risetime of 11 ns was constructed. Initial experiments were conducted in evacuated capillaries, in which the plasma is produced by ablation of the ca… more
Date: August 1, 1992
Creator: Rocca, J. J.
Partner: UNT Libraries Government Documents Department
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Chemically modified electrodes and related solution studies. Final technical report, January 15, 1991--January 14, 1992

Description: This report is divided into 5 sections: Ru{sub 4}/Fe complexes of tetra(4{prime}-methyl-2,2{prime}-bipyridine)porphyrin--catalytic epoxidation of olefins; water oxidation catalysis by doubly linked {mu}-oxo ruthenium complexes; polymer films formed by oxidation of transition metal electrodes into solutions of bisbipyridinealkane ligands; polymer films containing [CpMo({mu}-S)]{sub 2}S{sub 2}CHR dinuclear clusters;and conducting polymer films for catalyst incorporation.
Date: April 1, 1993
Creator: Elliott, C. M.
Partner: UNT Libraries Government Documents Department
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Properties of molecular solids and fluids at high pressure and temperature. Final report, March 1, 1986--October 31, 1993

Description: The main thrust of this work was directed to the task of determining the thermodynamic behavior of condensed solids and fluids containing simple molecules. Properties calculated include specific heats, equations of state, compressibilities, sound velocities, virial coefficients, viscosities, and thermal expansion. In addition, details of the structural, orientational, and magnetic phase transitions were determined. Dynamical quantities calculated include the lattice, libron, and vibron mode fre… more
Date: June 1, 1994
Creator: Etters, R. D.
Partner: UNT Libraries Government Documents Department
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Chemically modified electrodes and related solution studies

Description: This report is divided into 5 sections: Ru[sub 4]/Fe complexes of tetra(4[prime]-methyl-2,2[prime]-bipyridine)porphyrin--catalytic epoxidation of olefins; water oxidation catalysis by doubly linked [mu]-oxo ruthenium complexes; polymer films formed by oxidation of transition metal electrodes into solutions of bisbipyridinealkane ligands; polymer films containing [CpMo([mu]-S)][sub 2]S[sub 2]CHR dinuclear clusters;and conducting polymer films for catalyst incorporation.
Date: April 1, 1993
Creator: Elliott, C.M.
Partner: UNT Libraries Government Documents Department
open access

Capillary discharge extreme ultraviolet lasers. [Colorado State Univ. , Ft. Collins]

Description: The project objective is to explore the generation of soft X-ray laser radiation in a plasma column created by a fast capillary discharge. The proposed capillary lasing scheme offers the potential for compact, simple and efficient soft X-ray laser sources. For this purpose a compact, fast pulse generator which produces 100 kA current pulses with a risetime of 11 ns was constructed. Initial experiments were conducted in evacuated capillaries, in which the plasma is produced by ablation of the ca… more
Date: August 1, 1992
Creator: Rocca, J. J.
Partner: UNT Libraries Government Documents Department
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Advanced NMR approaches in the characterization of coal. Final technical report, September 1, 1990--August 31, 1993

Description: This project addressed two main goals and one much smaller one. The main goals were (1) to improve the significance, reliability and information content in high-resolution NMR (nuclear magnetic resonance) characterization of coal samples and (2) to develop chemically informative NMR imaging techniques for coal. The minor goal was to explore advanced features of dynamic nuclear polarization (DNP) as a technique for coal characterization; this included the development of two DNP probes and the ex… more
Date: September 30, 1993
Creator: Maciel, G. E.
Partner: UNT Libraries Government Documents Department
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