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ELECTROCHEMICAL STUDIES OF CARBON STEEL CORROSION IN HANFORD DOUBLE SHELL TANK (DST) WASTE

Description: This paper reports on the electrochemical scans for the supernatant of Hanford double-shell tank (DST) 241-SY-102 and the electrochemical scans for the bottom saltcake layer for Hanford DST 241-AZ-102. It further reports on the development of electrochemical test cells adapted to both sample volume and hot cell constraints.
Date: October 13, 2006
Creator: DUNCAN, J.B. & WINDISCH, C.F.
Partner: UNT Libraries Government Documents Department

SALT FOG TEST OF SAM2X5 COATED STAINLESS STEEL CYLINDER

Description: A salt fog test of an iron-based amorphous metal, SAM2X5, coated Type 316L stainless steel (SS316L) cylinder was made. The cylinder was 30-inch diameter by 88-inch long, and 3/8-inch thick. One end was welded shut with a SS316L end cap before coating. The body of the cylinder and the end cap were both coated. The cylinder was coated with SAM2X5 by the HVOF thermal spray process. The coating thickness was 0.015-inch to 0.019-inch thick. The cylinder was tested in a horizontal position. Also included in the test for reference purposes were five coupons (2-inch x 2-inch x 1/8-inch) of uncoated Type 1018 carbon steel (1018CS). The test used an abbreviated form of GM 9540P. Each cycle was 6 hours in duration and the cylinder and reference samples were exposed to a total of eight cycles. The cylinder was in relatively good condition after the test. Along the body of the cylinder only two pinpoint spot sized signs of rust were seen. The 1018CS reference specimens were extensively rusted.
Date: April 23, 2007
Creator: Aprigliano, L F; Rebak, R B; Choi, J; Lian, T & Day, S D
Partner: UNT Libraries Government Documents Department

Cumalative Distribution Functions for the Relative Humidity Thresholds for the Onset of Carbon Steel Corrosion

Description: The purpose of this calculation is to process the cumulative distribution functions (CDFs) characterizing the relative humidity (RH) thresholds for the onset of carbon steel corrosion provided by expert elicitation and minimize the set of values to 200 points for use in WAPDEG.
Date: May 13, 1998
Creator: Mon, K.G.
Partner: UNT Libraries Government Documents Department

CUMULATIVE DISTRIBUTION FUNCTIONS FOR THE TEMPERATURE THRESHOLD FOR THE ONSET OF CARBON STEEL CORROSION

Description: The purpose of this calculation is to process the cumulative distribution functions (CDFs) characterizing the temperature threshold for the onset of corrosion provided by expert elicitation and minimize the set of values to 200 points for use in WAPDEG.
Date: May 15, 1998
Creator: Mon, K.G.
Partner: UNT Libraries Government Documents Department

EXTENSION OF OPERATING LIFE OF KAPL-30 THIMBLE

Description: Due to extended low-temperature operation of the KAPL30 carbon steel thimble in the Materials Testing Reactor, a radiation damage evaluation was undertaken. Radiation damage in carbon steel may not be annealed under lowtemperature operating conditions. The data used in the evaluation are presented, and an extension of thimble life to 16 reactor cycles is recommended, subject to review if further low-temperature operation occurs. (D.E.B.)
Date: July 22, 1957
Creator: Lewis, D.M.
Partner: UNT Libraries Government Documents Department

MAG-GATE System for Molten metal Flow Control

Description: The need for improved active flow control has been recognized as part of the Steel Industry Technology Roadmap. Under TRP 9808 for the American Iron and Steel Institute and the Department of Energy, Concept Engineering Group Inc. has developed MAG-GATE{trademark}, an electromagnetic system for active molten metal flow control. Two hot steel tests were successfully conducted in 2003 at the Whemco Foundry Division, Midland, PA. Approximately 110,000 pounds of 0.2% carbon steel were poured through the device subject to electromagnetic flow control. Excellent agreement between predicted and actual flow control was found. A survey of the molten metal flow control practices at 100 continuous casters in North America was also conducted in 2003. This report summarizes the results of the development program to date. Preliminary designs are described for the next step of a beta test at an operating billet/bloom or slab caster.
Date: May 15, 2004
Creator: Nathenson, Richard D.
Partner: UNT Libraries Government Documents Department

Evaluation of cast carbon steel and aluminum for rack insert in MCO Mark 1A fuel basket

Description: This document evaluates the effects ofusing a cast carbon steel or aluminum instead of 3O4L stainless steel in the construction ofthe fuel rack insert for the Spent Nuclear Fuel MCO Mark IA fuel baskets. The corrosion, structural, and cost effects are examined.
Date: March 21, 1997
Creator: Graves, C. E.
Partner: UNT Libraries Government Documents Department

Development of a carburizing and quenching simulation tool: A material model for low carbon steels undergoing phase transformations

Description: An internal state variable formulation for phase transforming alloy steels is presented. We have illustrated how local transformation plasticity can be accommodated by an appropriate choice for the corresponding internal stress field acting between the phases. The state variable framework compares well with a numerical micromechanical calculation providing a discrete dependence of microscopic plasticity on volume fraction and the stress dependence attributable to a softer parent phase. The multiphase model is used to simulate the stress state of a quenched bar and show qualitative trends in the response when the transformation phenomenon is incorporated on the length scale of a global boundary value problem.
Date: June 24, 1996
Creator: Bammann, D.; Prantil, V. & Kumar, A.
Partner: UNT Libraries Government Documents Department

Effect of Nitrite/Nitrate concentrations on Corrosivity of Washed Precipitate

Description: Cyclic polarization scans were performed using A-537 carbon steel in simulated washed precipitate solutions of various nitrite and nitrate concentrations. The results of this study indicate that nitrate is an aggressive anion in washed precipitate. Furthermore, a quantitative linear log-log relationship between the minimum effective nitrite concentration and the nitrate concentration was established for washed precipitate with other ions at their average compositions.
Date: March 28, 2001
Creator: Congdon, J.W.
Partner: UNT Libraries Government Documents Department

Why Do Kraft Recovery Boiler Composite Floor Tubes Crack?

Description: Cracks were first reported in 1992 in co-extruded 304L stainless steel/SA210 Gd Al carbon steel floor tubes of North American black liquor recovery boilers. Since then, a considerable amount of information has been collected on the tube environment, crack characteristics, the stress state of the tubes, and the crack initiation and propagation mechanisms. These studies have identified both operating procedures that apparently can greatly lessen the likelihood of crack formation in the stainless steel layer and alternate materials that appear to be much more resistant to cracking than is 304L stainless.
Date: October 22, 2001
Creator: Keiser, J.R.
Partner: UNT Libraries Government Documents Department

Solid-state joining of ultrahigh carbon steels

Description: A joining study of these steels was initiated to determine the feasibility of using ultrahigh carbon steels in structural applications. The high carbon content (1.5 wt%) in these steels and the desire to maintain the superplastic microstructure limit the use of conventional arc-welding processes. We chose two solid-state joining processes: diffusion bonding and inertia friction welding. Preliminary results show that sound bonds can be obtained with tensile properties nearly equal to those of the base metal. Of three UHC steels bonded by both inertia-friction welding and diffusion- bonding processes, the one with the lowest aluminum content had the best overall properties. Diffusion bonding with a nickel interlayer showed the most promising results for the UHC steel containing 1.6 wt% aluminum. The properties of inertia-friction-welded steels can be improved by a post-weld heat treatment.
Date: April 22, 1993
Creator: Sunwoo, A.J.
Partner: UNT Libraries Government Documents Department

Investigations of Low Temperature Time Dependent Cracking

Description: The objective of this project was to investigate metallurgical and mechanical phenomena associated with time dependent cracking of cold bent carbon steel piping at temperatures between 327 C and 360 C. Boiler piping failures have demonstrated that understanding the fundamental metallurgical and mechanical parameters controlling these failures is insufficient to eliminate it from the field. The results of the project consisted of the development of a testing methodology to reproduce low temperature time dependent cracking in laboratory specimens. This methodology was used to evaluate the cracking resistance of candidate heats in order to identify the factors that enhance cracking sensitivity. The resultant data was integrated into current available life prediction tools.
Date: September 30, 2002
Creator: Van der Sluys, W A; Robitz, E S; Young, B A & Bloom, J
Partner: UNT Libraries Government Documents Department

The fate of organics from hot semiworks in CR vault

Description: The 244-CR vault contains four tanks: two 40,000-gallon carbon steel tanks and two 15,000-gallon stainless steel tanks. On occasion, the waste from 201-C Semiworks was routed through the tanks in 244-CR. This had the potential for mixing the organics from 201-C Semiworks and a residual heel in 244-CR which may be acidic. The purpose of this study is to determine if there is a possibility that a reactive waste could be present in 244-CR vault.
Date: August 23, 1999
Creator: Reynolds, D. A.
Partner: UNT Libraries Government Documents Department

Surface and Electrochemical Behavior of HSLA in Supercritical CO2-H2O Environment

Description: General corrosion was observed on high strength low alloy carbon steel after electrochemical impedance spectroscopy experiments (EIS) performed in H{sub 2}O saturated with CO{sub 2} at 50 C and 15.2 MPa. However, general and localized were observed on the same material surfaces after the EIS experiments performed in supercritical CO{sub 2} containing approximately 6100 ppmv H{sub 2}O at 50 C and 15.2 MPa. The general corrosion areas were uniformly covered by the FeCO{sub 3}-like phase identified by X-ray diffraction (XRD). In the area of localized corrosion, XRD also revealed FeCO{sub 3}-rich islands embedded in {alpha}-iron. The energy dispersive X-ray (EDX) analysis revealed high concentrations of iron, carbon, and oxygen in the area affected by general corrosion and in the islands formed in the area of localized corrosion. The real and imaginary impedances were lower in H{sub 2}O saturated with CO{sub 2} than those in the supercritical CO{sub 2} containing the aqueous phase indicating faster corrosion kinetics in the former.
Date: January 11, 2012
Creator: Ziomek-Moroz, M.; Holcomb, G. R.; Tylczak, J.; Beck, J.; Fedkin, M. & Lvov, S.
Partner: UNT Libraries Government Documents Department

L AREA WASTEWATER STORAGE DRUM EVALUATION

Description: This report documents the determination of the cause of pressurization that led to bulging deformation of a 55 gallon wastewater drum stored in L-Area. Drum samples were sent to SRNL for evaluation. The interior surface of these samples revealed blistering and holes in the epoxy phenolic drum liner and corrosion of the carbon steel drum. It is suspected that osmotic pressure drove permeation of the water through the epoxy phenolic coating which was weakened from exposure to low pH water. The coating failed at locations throughout the drum interior. Subsequent corrosion of the carbon steel released hydrogen which pressurized the drum causing deformation of the drum lid. Additional samples from other wastewater drums on the same pallet were also evaluated and limited corrosion was visible on the interior surfaces. It is suspected that, with time, the corrosion would have advanced to cause pressurization of these sealed drums.
Date: November 30, 2007
Creator: Vormelker, P; Cynthia Foreman, C; Zane Nelson, Z; David Hathcock, D & Dennis Vinson, D
Partner: UNT Libraries Government Documents Department

HEAT OF DILUTION CALCULATION FOR 19 MOLAR SODIUM HYDROXIDE WITH WATER FOR USE IN 241-S-112

Description: High concentration caustic solutions are known to cause stress corrosion cracking in carbon steel at elevated temperature. This calculation establishes the conditions where heat of dilution will not cause the solution temperature--concentration to exceed the boundary for stress corrosion cracking as established by NACE International.
Date: February 20, 2007
Creator: Barton, W. B.
Partner: UNT Libraries Government Documents Department

Environmental Degradation of Materials for Nuclear Waste Repositories Engineered Barriers

Description: Several countries are considering geological repositories for the storage of nuclear waste. Most of the environments for these repositories will be reducing in nature, except for the repository in the US, which is going to be oxidizing. For the reducing repositories, alloys such as carbon steel, copper, stainless steels and titanium are being evaluated. For the repository in the US, some of the most corrosion resistant commercially available alloys are being investigated. This paper presents a summary of the behavior of the different materials under consideration for the repositories and the current understanding of the degradation modes of the proposed alloys in ground water environments from the point of view of general corrosion, localized corrosion and environmentally assisted cracking.
Date: December 24, 2006
Creator: Rebak, R B
Partner: UNT Libraries Government Documents Department

Cathodic protection of carbon steel in simulated geothermal environments

Description: The applicability of cathodic protection to mitigate corrosion of carbon steel in two different environments containing H{sub 2}S has been investigated using impressed current and sacrificial anode techniques. Results of impressed current tests conducted under potential control shows that the weight loss can be reduced significantly by shifting the potential of the metal 60 to 80 mV cathodic to the open circuit potential. The relationship between the applied current and the potential shift shows that the current requirement does not necessarily increase with the voltage shift, thus implying that the cost of cathodic protection may not increase in proportion to the protection achieved. The feasibility of using zinc as a sacrificial anode in the environment of interest has also been studied.
Date: October 8, 1982
Creator: Bandy, R. & van Rooyen, D.
Partner: UNT Libraries Government Documents Department

RIP Input Tables from WAPDEG for LA Design Selection: Enhabced Design Alternatie IV

Description: The purpose of this calculation is to document (1) the Waste Package Degradation (WAPDEG) version 3.09 (CRWMS M&O 1998b. ''Software Routine Report for WAPDEG'' (Version 3.09)) simulations used to analyze degradation and failure of 2-cm thick titanium grade 7 corrosion resistant material (CRM) drip shields (that are placed over single-layer waste packages composed of a 30-cm thick A-5 16 carbon steel corrosion allowance material (CAM)) as well as degradation and failure of the waste packages themselves, and (2) post-processing of these results into tables of drip shield/waste package degradation time histories suitable for use as input into the Integrated Probabilistic Simulator for Environmental Systems (RIP) version 5.19.01 (Golder Associates 1998) computer code. This calculation supports Performance Assessment analysis of the License Application Design Selection (LADS) Enhanced Design Alternative IV.
Date: June 29, 1999
Creator: Mon, K.G.
Partner: UNT Libraries Government Documents Department

Total System Performance Assessment: Enhanced Design Alternative IV

Description: The purpose of this calculation is to document total system performance assessment modeling of Enhanced Design Alternative (EDA) Feature IV. Total System Performance Assessment (TSPA) calculations for EDA IV are based on the TSPA-VA Base Case which has been modified with a quartz sand invert, quartz sand backfill, line loading and 21 PWR waste packages that have 2-cm thick titanium grade 7 corrosion resistant material (CRM) drip shields that are placed over a 30 cm thick carbon steel (A5 16) waste package with an integral filler material (CRWMS M&O 1999a & 1999b). This document details the changes and assumptions made to the VA reference Performance Assessment Model (CRWMS M&O 1998a) to incorporate the design changes detailed for EDA IV. The performance measure for this evaluation is the expected value dose-rate history at 20 km from the repository boundary.
Date: June 23, 1999
Creator: Mattie, P.D.
Partner: UNT Libraries Government Documents Department

EFFECT OF CHLORIDE AND SULFATE CONCENTRATION ON PROBABLITY BASED CORROSION CONTROL FOR LIQUID WASTE TANKS- PART IV

Description: A series of cyclic potentiodynamic polarization tests was performed on samples of A537 carbon steel in support of a probability-based approach to evaluate the effect of chloride and sulfate on corrosion susceptibility. Testing solutions were chosen to build off previous experimental results from FY07, FY08, FY09 and FY10 to systemically evaluate the influence of the secondary aggressive species, chloride, and sulfate. The FY11 results suggest that evaluating the combined effect of all aggressive species, nitrate, chloride, and sulfate, provides a consistent response for determining corrosion susceptibility. The results of this work emphasize the importance for not only nitrate concentration limits, but also chloride and sulfate concentration limits as well.
Date: August 23, 2012
Creator: Hoffman, E.
Partner: UNT Libraries Government Documents Department

RECOMMENDATIONS FOR SAMPLING OF TANK 18 IN F TANK FARM

Description: Representative sampling is required for characterization of the residual floor material in Tank 18 prior to operational closure. Tank 18 is an 85-foot diameter, 34-foot high carbon steel tank with nominal operating volume of 1,300,000 gallons. It is a Type IV tank, and has been in service storing radioactive materials since 1959. Recent mechanical cleaning of the tank removed all mounds of material. Anticipating a low level of solids in the residual material, Huff and Thaxton [2009] developed a plan to sample the material during the final clean-up process while it would still be resident in sufficient quantities to support analytical determinations in four quadrants of the tank. Execution of the plan produced fewer solids than expected to support analytical determinations in all four quadrants. Huff and Thaxton [2009] then restructured the plan to characterize the residual floor material separately in the North and the South regions: two 'hemispheres.' This document provides sampling recommendations to complete the characterization of the residual material on the tank bottom following the guidance in Huff and Thaxton [2009] to split the tank floor into a North and a South hemisphere. The number of samples is determined from a modification of the formula previously published in Edwards [2001] and the sample characterization data for previous sampling of Tank 18 described by Oji [2009]. The uncertainty is quantified by an upper 95% confidence limit (UCL95%) on each analyte's mean concentration in Tank 18. The procedure computes the uncertainty in analyte concentration as a function of the number of samples, and the final number of samples is determined when the reduction in the uncertainty from an additional sample no longer has a practical impact on results. The characterization of the full suite of analytes in the North hemisphere is currently supported by a single Mantis rover sample ...
Date: December 14, 2009
Creator: Shine, G.
Partner: UNT Libraries Government Documents Department

CRACK TIP OPENING DISPLACEMENT AND ANGLE FOR A GROWING CRACK IN CARBON STEEL

Description: The crack tip opening displacements and angles (CTOD/CTOA) are calculated with finite element method based on the test data of a set of constraint-dependent J-R curves for A285 carbon steel. The values of the CTOD/CTOA are initially high at initiation, but rapidly decrease to a nearly constant value. When the common practice is adopted by using only the constant part of CTOD/CTOA as the fracture criterion, the crack growth behavior is shown to be severely underestimated. However, with a bilinear form of CTOD/CTOA fracture criterion which approximates the initial non-constant portion, the experimental load vs. crack extension curves can be closely predicted. Furthermore, it is demonstrated that the CTOD/CTOA is crack tip constraint dependent. The values of CTOD/CTOA for specimens with various ratios of crack length to specimen width (a/W) are reflected by the J-R curves and their slopes.
Date: January 18, 2005
Creator: LAM, POH-SANG
Partner: UNT Libraries Government Documents Department