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Electrochemical cell for in-situ x-ray characterization

Description: An electrochemical cell suitable for in-situ XRD analysis is presented. Qualitative information such as phase formation and phase stability can be easily monitored using the in-situ cell design. Quantitative information such as lattice parameters and kinetic behavior is also straightforward. Analysis of the LiMn&sub2;O&sub4; spinel using this cell design shows that the lattice undergoes two major structural shrinkages at approx. 4.0 V and approx. 4.07 V during charging. These shrinkages correlate well with the two electrochemical waves observed and indicate the likelihood of two separate redox processes which charging and discharging.
Date: August 4, 1998
Creator: Doughty, D.H.; Ingersoll, D. & Rodriguez, M.A.
Partner: UNT Libraries Government Documents Department

USE OF COUPLED MULTI-ELECTRODE ARRAYS TO ADVANCE THE UNDERSTANDING OF SELECTED CORROSION PHENOMENA

Description: The use of multi-coupled electrode arrays in various corrosion applications is discussed with the main goal of advancing the understanding of various corrosion phenomena. Both close packed and far spaced electrode configurations are discussed. Far spaced electrode arrays are optimized for high throughput experiments capable of elucidating the effects of various variables on corrosion properties. For instance the effects of a statistical distribution of flaws on corrosion properties can be examined. Close packed arrays enable unprecedented spatial and temporal information on the behavior of local anodes and cathodes. Interactions between corrosion sites can trigger or inhibit corrosion phenomena and affect corrosion damage evolution.
Date: February 23, 2006
Creator: Budiansky, N.D.; Bocher, F.; Cong, H.; Hurley, M.F. & Scully, J.R.
Partner: UNT Libraries Government Documents Department

Low cost MCFC anodes

Description: This paper outlines a project, funded under a DOE SBIR grant, which tested a potentially lower cost method of manufacturing MCFC stack anodes and evaluated the feasibility of using the technology in the existing M-C Power Corp. manufacturing facility. The procedure involves adding activator salts to the anode tape casting slurry with the Ni and Cr or Al powders. Two different processes occur during heat treatment in a reducing environment: sintering of the base Ni structure, and alloying or cementation of the Cr or Al powders. To determine whether it was cost-effective to implement the cementation alloying manufacturing process, the M-C Power manufacturing cost model was used to determine the impact of different material costs and processing parameters on total anode cost. Cost analysis included equipment expenditures and facility modifications required by the cementation alloying process.
Date: December 31, 1996
Creator: Erickson, D.S.
Partner: UNT Libraries Government Documents Department

IGT Stack No. 6 (SDG{ampersand}E-1) Test Plan and Component Specification Document: Topical report, March 1996

Description: The purpose of Stack-6 (SDG{ampersand}E-1) is to scale up and demonstrate the long term performance and endurance characteristics of the IMHEX stack design and the Generation No. 2 cell components (improved pore matching electrodes) in a 20 cell subscale stack test.
Date: December 31, 1997
Partner: UNT Libraries Government Documents Department

Effect on Performance of Composition of Li-Ion Carbon Anodes Derived from PMAN/DVB Copolymers

Description: The effects on electrochemical performance of the nitrogen content of disordered carbons derived from polymethacryonitrile (PMAN)-divinylbenzene (DVB) copolymers were examined in galvanostatic cycling tests between 2 V and 0.01 V vs. Li/Li+ in lM LiPF<sub>6</sub>/ethylene carbonate (EC)-dimethyl carbonate (DMC). The first-cycle reversible capacities and coulombic efficiencies increased with increase in the level of nitrogen for samples prepared at 700&deg;C. However, the degree of fade also increased. Similar tests were performed on materials that were additionally heated at 1,000&deg; and 1,300&deg;C for five hours. Loss of nitrogen, oxygen, and hydrogen occurred under these conditions, with none remaining at the highest temperature in all cases but one. The pyrolysis temperature dominated the electrochemical performance for these samples, with lower reversible and irreversible capacities for the first intercalation cycle as the pyrolysis temperature was increased. Fade was reduced and coulombic efficiencies also improved with increase in temperate. The large irreversible capacities and high fade of these materials makes them unsuitable for use in Li-ion cells.
Date: May 14, 1999
Creator: Even, William R. & Guidotti, Ronald A.
Partner: UNT Libraries Government Documents Department

Edge reclamation in position-sensitive photomultiplier tubes

Description: We have investigated the performance of a position-sensitive, gamma-ray detector based on a CsI(Na) scintillator coupled to a Hamamatsu R3292 Position-Sensitive Photomultiplier Tube (PSPMT). The R3292 has an active area 10.0 cm in diameter (quoted). Utilization of the full active area of the photocathode is a goal that has been previously unrealized due to edge effects. Initial measurements with a 0.75 cm thick CsI(Na) crystal indicate that the performance (position resolution linearity) starts to degrade as one reaches a radius of only 3.5 cm, reducing the active area by 60%. Measuring the anode wires we have found that this fall off is not solely due to crystal edge effects, but rather is inherent to the tube crystal system. In this paper we describe the results of our measurements and how good performance can be maintained across a full 10cm of the tube face through the use of a few additional electronics channels.
Date: June 16, 1999
Creator: Nakae, L & Ziock, K
Partner: UNT Libraries Government Documents Department

Inert anodes and advanced smelting of aluminum

Description: This report provides a broad assessment of open literature and patents that exist in the area of inert anodes and their related cathode systems and cell designs, technologies that are relevant for the advanced smelting of aluminum. The report also discusses the opportunities, barriers, and issued associated with these technologies from a technical, environmental, and economic viewpoint. It discusses the outlook for the direct retrofit of advanced reduction technologies to existing aluminum smelters, and compares retrofits to ''brown field'' usage and ''green field'' adoption of the technologies. A number of observations and recommendations are offered for consideration concerning further research and development efforts that may be directed toward these advanced technologies. The opportunities are discussed in the context of incremental progress that is being made in conventional Hall-Heroult cell systems.
Date: July 1, 1999
Creator: Technologies, ASME Technical Working Group on Inert Anode
Partner: UNT Libraries Government Documents Department

Effect of Sulfur and Hydrocarbon Fuels on Titanate/Ceria SOFC Anodes

Description: The purpose of the project is to develop low-cost, high-performance anodes that offer low polarization resistance as well as improved tolerance for nonidealities in anode environment such as redox cycles, sulfur and other poisons, and hydrocarbons.
Date: January 27, 2005
Creator: Marina, O.A.; Pedersen, L.R. & Stevenson, J.W.
Partner: UNT Libraries Government Documents Department

Charge and fluence lifetime measurements of a dc high voltage GaAs photogun at high average current

Description: GaAs-based dc high voltage photoguns used at accelerators with extensive user programs must exhibit long photocathode operating lifetime. Achieving this goal represents a significant challenge for proposed high average current facilities that must operate at tens of milliamperes or more. This paper describes techniques to maintain good vacuum while delivering beam, and techniques that minimize the ill effects of ion bombardment, the dominant mechanism that reduces photocathode yield of a GaAs-based dc high voltage photogun. Experimental results presented here demonstrate enhanced lifetime at high beam currents by: (a) operating with the drive laser beam positioned away from the electrostatic center of the photocathode, (b) limiting the photocathode active area to eliminate photoemission from regions of the photocathode that do not support efficient beam delivery, (c) using a large drive laser beam to distribute ion damage over a larger area, and (d) by applying a relatively low bias voltage to the anode to repel ions created within the downstream beam line. A combination of these techniques provided the best total charge extracted lifetimes in excess of 1000 C at dc beam currents up to 9.5 mA, using green light illumination of bulk GaAs inside a 100 kV photogun.
Date: April 1, 2011
Creator: J. Grames, R. Suleiman, P.A. Adderley, J. Clark, J. Hansknecht, D. Machie, M. Poelker, M.L. Stutzman
Partner: UNT Libraries Government Documents Department

Pulsed X-ray Characterization of Stripline Micro-Channel Plate Gated Imager

Description: We report on characterization of x-ray imaging arrays developed by National Security Technologies, LLC. These devices are based on a microchannel plate (MCP) with a conventional glass microchannel structure, but the top and bottom conductive coatings, rather than covering the entire area, are configured into several (4 to 8) parallel strips. Since the bias voltage is a pulse launched from one end, these operate as striplines; relative delays between these pulses give different active exposure times. Unlike the case of a static bias voltage, non-uniformities in impedance along a stripline will produce spatial fluctuations in the bias voltage. These are expected to be slight, but the very sensitive dependence of gain on voltage - approximately like Vl/4d, where l and d are the length and diameter of the channel - means there may be very significant spatial non-uniformities in gain. Flat-field calibrations are therefore required so that such effects can be unfolded from the raw images if quantitative data is required. Such flat-field and other characterization measurements, e.g. responsivity and linearity, have therefore been done with a flash X-ray radiographic system. The maximum endpoint energy is 500 keV. The duration is {approx}40 ns, and so is essentially flat (temporally) during the MCP stripline transit time, which is a maximum of 600 ps. Spatial variations are significant, but the data are corrected using independent flat-field measurements. A monochromator selects a particular X-ray transition line (typically K{alpha}) of the anode material, so that characterizations can be done for various well-defined input photon energies.
Date: March 30, 2011
Creator: F. J. Goldin, D. V. Morgan, K. J. Moy
Partner: UNT Libraries Government Documents Department

MEASUREMENT AND SIMULATION OF SOURCE-GENERATED HALOS IN THE UNIVERSITY OF MARYLAND ELECTRON RING (UMER)

Description: One of the areas of fundamental beam physics that have served as the rationale for recent research on UMER is the study of the generation and evolution of beam halos. Recent experiments and simulations have identified imperfections in the source geometry, particularly in the region near the emitter edge, as a significant potential source of halo particles. The edge-generated halo particles, both in the experiments and the simulations are found to pass through the center of the beam a short distance downstream of the anode plane. Understanding the detailed evolution of these particle orbits is therefore important to designing any aperture to remove the beam halo.
Date: June 18, 2007
Creator: Haber, I.; Haber, I.; Bernal, S.; Kishek, R.A.; O'Shea, P.G.; Papadopoulos, C. et al.
Partner: UNT Libraries Government Documents Department

ELECTRON AVALANCHE MODEL OF DIELECTRIC-VACUUM SURFACE BREAKDOWN

Description: The model assumes that an 'initiating event' results in positive ions on the surface near the anode and reverses the direction of the normal component of electric field so that electrons in vacuum are attracted to the dielectric locally. A sequence of surface electron avalanches progresses in steps from the anode to the cathode. For 200 kV across 1 cm, the spacing of avalanches is predicted to be about 13 microns. The time for avalanches to step from the anode to the cathode is predicted to be about a ns.
Date: February 21, 2007
Creator: Lauer, E J
Partner: UNT Libraries Government Documents Department

Electrostatic Modeling of Vacuum Insulator Triple Junctions

Description: Triple junctions are often initiation points for insulator flashover in pulsed power devices. The two-dimensional finite-element TriComp [1] modeling software suite was utilized for its electrostatic field modeling package to investigate electric field behavior in the anode and cathode triple junctions of a high voltage vacuum-insulator interface. TriComp enables simple extraction of values from a macroscopic solution for use as boundary conditions in a subset solution. Electric fields computed with this zoom capability correlate with theoretical analysis of the anode and cathode triple junctions within submicron distances for nominal electrode spacing of 1.0 cm. This paper will discuss the iterative zoom process with TriComp finite-element software and the corresponding theoretical verification of the results.
Date: October 25, 2006
Creator: Tully, L K; Goerz, D A; Houck, T L & Javedani, J B
Partner: UNT Libraries Government Documents Department

Electronic Circuits Lectures

Description: The two-electrode vacuum tube, or diode, consists of an electron-emitting cathode surrounded by a positive anode (plate). A plot of plate current (i{sub b}) vs plate voltage (e{sub b}) is shown. At low anode voltages, the anode current is limited by the repelling effect that the negative electrons already in the space have on the electrons just being emitted (space-charge effect). When a full space charge is present, the plate current depends upon the plate voltage according to Childs law: i{sub b} {approx} e{sub b}{sup 3/2}. Increasing the plate voltage eventually results in an electron flow equal to total cathode emission, after which further increases in anode voltage will produce practically no additional current (voltage saturation). However, for high field stresses, additional electrons are pulled out of the cathode (field emission), increasing the current even further.
Date: December 1, 1947
Creator: Mozley, Robert
Partner: UNT Libraries Government Documents Department

Cathodic protection of carbon steel in simulated geothermal environments

Description: The applicability of cathodic protection to mitigate corrosion of carbon steel in two different environments containing H{sub 2}S has been investigated using impressed current and sacrificial anode techniques. Results of impressed current tests conducted under potential control shows that the weight loss can be reduced significantly by shifting the potential of the metal 60 to 80 mV cathodic to the open circuit potential. The relationship between the applied current and the potential shift shows that the current requirement does not necessarily increase with the voltage shift, thus implying that the cost of cathodic protection may not increase in proportion to the protection achieved. The feasibility of using zinc as a sacrificial anode in the environment of interest has also been studied.
Date: October 8, 1982
Creator: Bandy, R. & van Rooyen, D.
Partner: UNT Libraries Government Documents Department

Next Generation Hole Injection/Transport Nano-Composites for High Efficiency OLED Development

Description: The objective of this program is to use a novel nano-composite material system for the OLED anode coating/hole transport layer. The novel anode coating is intended to significantly increase not only hole injection/transport efficiency, but the device energy efficiency as well. Another goal of the Core Technologies Program is the optimization and scale-up of air-stable and cross-linkable novel HTL nano-composite materials synthesis and the development of low-cost, large-scale mist deposition processes for polymer OLED fabrication. This proposed technology holds the promise to substantially improve OLED energy efficiency and lifetime.
Date: July 31, 2009
Creator: Wang, King
Partner: UNT Libraries Government Documents Department

A solid state Marx generator for TEL2

Description: The solid-state Marx generator modulates the anode of the electron gun to produce the electron beam pulses in the second Tevatron Electron Lens (TEL2). It is capable of driving the 60 pF terminal with 600 ns pulses of up to 6 kV with a p.r.r. of 50 kHz. The rise and fall times are 150 ns. Stangenes Industries developed the unit and is working on a second version which will go to higher voltage and have the ability to vary its output in 396 ns intervals over a 5 {micro}s pulse.
Date: June 1, 2007
Creator: Kamerdzhiev, V.; Pfeffer, H.; Saewert, G.; Shiltsev, V. & /Fermilab
Partner: UNT Libraries Government Documents Department

FREE STANDING NANOSTRUCTURED ANODES FOR LI-ION RECHARGEABLE BATTERIES

Description: The free standing nanorodes of aluminum and cobalt oxides were grown on electrode and tested as the anodes directly in the half-cell. The average diameter and length of the nanorods are 80 nm and 200 nm respectively. The aligned nanorods demonstrated high initial capacity from 1200-1400 mAh/g at rate of 0.5C. The gradually decrease of initial capacity was observed. The preliminary characterization shows that the changes of the crystalline structure and morphology during cycling may be responsible for the capacity decay.
Date: July 20, 2009
Creator: Au, M.
Partner: UNT Libraries Government Documents Department

Performance of Lithium Ion Cell Anode Graphites Under Various Cycling Conditions

Description: Graphites MCMB-2810 and OMAC-15 (made by Osaka Gas Inc.), and SNG12 (Hydro Quebec, Inc.) were evaluated (in coin cells with lithium counter electrodes) as anode materials for lithium-ion cells intended for use in hybrid electric vehicles. Though the reversible capacity obtained for SNG was slightly higher than that of OMAC or MCMB, its 1st cycle efficiency was lower. Voltage vs capacity plots of cycling data show that the discharge and charge limits shift to higher capacity values due to continuation of anode side reactions. Varying the cycle charge and discharge limits was found to have no significant effect on fractional capacity shift per cycle.
Date: June 15, 2009
Creator: Ridgway, Paul; Zheng, Honghe; Liu, Gao; Song, Xiangun; Guerfi, Abdelbast; Charest, Patrick et al.
Partner: UNT Libraries Government Documents Department

Microwave Plasma Chemical Vapor Deposition of Nano-Structured Sn/C Composite Thin-Film Anodes for Li-ion Batteries

Description: In this paper we report results of a novel synthesis method of thin-film composite Sn/C anodes for lithium batteries. Thin layers of graphitic carbon decorated with uniformly distributed Sn nanoparticles were synthesized from a solid organic precursor Sn(IV) tert-butoxide by a one step microwave plasma chemical vapor deposition (MPCVD). The thin-film Sn/C electrodes were electrochemically tested in lithium half cells and produced a reversible capacity of 440 and 297 mAhg{sup -1} at C/25 and 5C discharge rates, respectively. A long term cycling of the Sn/C nanocomposite anodes showed 40% capacity loss after 500 cycles at 1C rate.
Date: February 1, 2008
Creator: Stevenson, Cynthia; Marcinek, M.; Hardwick, L.J.; Richardson, T.J.; Song, X. & Kostecki, R.
Partner: UNT Libraries Government Documents Department

MAPMT H7546B anode current response study for ILC SiD muon system prototype

Description: The proposed Silicon Detector (SiD) concept for the ILC has barrel and end cap muon systems. An SiD scintillator based muon system prototype has 256 strips and was constructed from extruded strips, WLS fibers, clear fibers, and multianode photo multiplier tubes (MAPMT) Hamamatsu H7546B. Six MAPMTs were used. As a first step to understand strip output, the response of every anode to a given brightness of light and applied voltage must be measured. For the test, a custom made light source was used. Each MAPMT output was measured independently. The anode currents were measured at constant (green) input light brightness and the same photocathode to anode voltage (800V). The anode currents have a wide spread; for all tubes the maximum value is 5.23 times larger than the minimum value. The MAPMT cross talk was measured for one of the central inputs. The maximum cross talk value is about 4.9%. The average cross talk for the nearest four neighboring channels is 3.9%, for the farthest four is 1%. To assure the reproducibility and repeatability of the measurements, the double reference method was used.
Date: October 1, 2007
Creator: Dyshkant, A.; Blazey, G.; Francis, K.; Hedin, D.; Zutshi, V.; U., /Northern Illinois et al.
Partner: UNT Libraries Government Documents Department