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The development of precipitated iron catalysts with improved stability

Description: The objective of this program is to identify the chemical principles governing the deactivation of precipitated iron catalysts during Fischer-Tropsch synthesis and to use these chemical principles in the design of catalysts suitable for slurry reactors. The performance targets are 88% CO+H{sub 2} conversion with less than 1% deactivation/day for 1 month and a methane and ethane selectivity of no more than 7% (based on hydrocarbons and oxygenates only) at a space velocity of at least 2 normal li… more
Date: May 6, 1992
Creator: Abrevaya, H.
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
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Solar-thermal energy conversion and storage: cyclohexane dehydrogenation. Progress report, 30 September 1977-30 June 1978

Description: The objective of this project is to provide research support for the benzene/cyclohexane heat pipe development program at Sandia. The kinetics of the cyclohexane decomposition (energy collection) reaction over a commercially available naphtha reforming catalyst (RD-150, Englehard Industries) in the temperature range 400 to 800/sup 0/F and pressures of 1 to 40 atmospheres were measured. Significant amounts of side products such as toluene and butane were identified at temperatures above 550/sup … more
Date: July 1, 1978
Creator: Ritter, A.B.; DeLancey, G.B.; Schneider, J. & Silla, H.
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
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Importance of the specific heat anomaly in the design of binary Rankine cycle power plants

Description: The transposed critical temperature (TPCT) is shown to be an extremely important thermodynamic property in the selection of working fluids and turbine states for geothermal power plants operating on a closed organic (binary) Rankine cycle. When the optimum working fluid composition and process states are determined for specified source and sink conditions, turbine inlet states consistently lie adjacent to the working fluids' TPCT line for all resource temperatures, constraints, and cost and eff… more
Date: May 1, 1980
Creator: Pope, W.L.; Doyle, P.A.; Fulton, R.L. & Silvester, L.F.
Item Type: Refine your search to only Article
Partner: UNT Libraries Government Documents Department
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Establishment of viscometer capability for geopressured fluids. Project 61024 final report, November 19, 1978-December 31, 1979

Description: The feasibility of modifying the IGT capillary viscometer for the measurement of methane-saturated brines at 10,000 psi and 200/sup 0/C was evaluated. The viscometer was cleaned, modified, reassembled and pressure treated. The density cells were calibrated to a precision of approximately 7%. The viscosity of pure value was measured and the best value obtained was 6% below values reported in the literature. The operation of the viscometer was time-consuming and required meticulous cleaning betwe… more
Date: October 1, 1980
Creator: Rockar, E. & Randolph, P.
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
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Energy from biological processes

Description: This assessment responds to a request by the Senate Committee on Commerce, Science, and Transportation for an evaluation of the energy potential of various sources of plant and animal matter (biomass). This report complements an earlier OTA report on the Application of Solar Technology to Today's Energy Needs in evaluating the major solar energy resources available to the United States. The findings also will serve as part of the material to be used in an upcoming OTA assessment of synthetic fu… more
Date: July 1, 1980
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
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Methane oxidation over dual redox catalysts

Description: Review and analysis of the literature data on electron transfer itself and electron transfer oxidation of alkyl radicals was done in order to understand the mechanism by which methyl radical can be oxidized to CH{sub 3}{sup +} and further substituted by OH{sup {minus}} to form methanol. This allowed to compare and classify the various possible reaction patterns, understand the mechanism and circumstances of operation of each of them and select those which can be involved in oxidation of methyl … more
Date: March 1, 1989
Creator: Klier, Kamil; Herman, Richard G. & Sojka, Zvigniew
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
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Energy Program annual report

Description: The national economy is particularly dependent on efficient electrical generation and transportation. Electrical demand continues to grow and will increasingly rely on coal and nuclear fuels. The nuclear power industry still has not found a solution to the problem of disposing of the waste produced by nuclear reactors. Although coal is in ample supply and the infrastructure is in place for its utilization, environmental problems and improved conversion processes remain technical challenges. In … more
Date: February 1, 1988
Creator: Borg, I.Y. (ed.)
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
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Energy and protein production from pulp mill wastes. Progress report, June 15, 1977--September 15, 1977

Description: Experiments conducted during this past quarter demonstrated the decided difference both in amount and composition of the gas produced from the fermentation of ozonated versus unozonated yeast-plant SSL. Gas from ozonated SSL averaged over 80% methane content while unozonated effluent was mostly carbon dioxide. Gas production rates and retention time studies indicated that the fermentation was substrate-limited. Preliminary tests using supplemental carbon sources have verified this. The success … more
Date: September 15, 1977
Creator: Jurgensen, M. F. & Patton, J. T.
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
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Thermo-chemical energy conversion and storage. Final report

Description: Research support for the cyclohexane/benzene heat pipe development program at Sandia Laboratories is reported. The apparent kinetics of the gas-phase catalytic dehydrogenation of cyclohexane to benzene in an internally recirculated (gradientless) reactor over the temperature range from 500 to 800/sup 0/F at 1 atm at various space velocities was studied. A kinetic model was developed based on a reversible mass-action rate expression and a catalyst effectiveness factor which is able to correlate … more
Date: September 1, 1978
Creator: Ritter, A.B.; DeLancey, G.B.; Schneider, J. & Silla, H.
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
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Development of BEACON technology. Quarterly report, April-June 1982

Description: The BEACON process involves the catalytic deposition of a highly reactive form of carbon from a gas stream which contains carbon monoxide. The carbon-depleted gas is combusted with air to produce power, and the carbon is reacted with steam to produce methane or hydrogen. Experiments were continued this quarter with the objective of improving the carbon deposition efficiency using a Paraho retort off-gas mixture. Analysis has shown that the use of the Paraho off-gas to make hydrogen would be att… more
Date: March 1, 1983
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
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Research on oil recovery mechanisms in heavy oil reservoirs

Description: The goal of the Stanford University Petroleum Research Institute is to conduct research directed toward increasing the recovery of heavy oils. Presently, SUPRI is working in five main directions: To assess the influence of different reservoir conditions (temperature and pressure) on the absolute and relative permeability to oil and water and on capillary pressure; To evaluate the effect of different reservoir parameters on the in-situ combustion process. This project includes the study of the k… more
Date: January 1, 1991
Creator: Brigham, W.E.; Aziz, K. & Ramey, H.J. Jr.
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
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Direct conversion of light hydrocarbon gases to liquid fuel

Description: The objective of this program is to investigate the direct conversion of light gaseous hydrocarbons, such as those produced during Fischer-Tropsch synthesis or as a product of gasification, to liquid transportation fuels via a partial oxidation process. The process will be tested in an existing pilot plant to obtain credible mass balances. Specific objectives to be met include determination of optimal process conditions, investigation of various processing options (e.g. feed injection, product … more
Date: January 1, 1991
Creator: Foral, M.J.
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
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Methane entrained in geopressured aquifers, Texas Gulf Coast

Description: Six tests of geopressured aquifers have yielded between 3.6 to 4.5 m/sup 3//m/sup 3/ (20 to 25 scf/bbl) of gas. These low gas concentrations are attributed to high salinities, that in all tests exceeded 100,000 mg/l, but undersaturated conditions cannot be ruled out completely. Research efforts are designed to delineate the geographic and stratigraphic variations in salinity and to recognize regional and local trends so that zones of lower salinity and higher gas concentration can be identified… more
Date: July 1, 1980
Creator: Morton, R. A.
Item Type: Refine your search to only Article
Partner: UNT Libraries Government Documents Department
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Application of direct contact heat exchangers to geothermal power production cycles. Project review, December 1, 1974--May 31, 1977

Description: Work performed on the development of direct contact heat exchanger power cycles for geothermal applications is reviewed. The period covered in the report is from the inception of the project in 1974 through May 31, 1977. Results from a large experimental program on heat exchanger develpment as well as from many analyses of components and cycle performance and economics are given. A number of working fluids and operating conditions have been considered, and no major obstacles for the implementat… more
Date: January 1, 1977
Creator: Jacobs, H. R.; Boehm, R. F. & Hansen, A. C.
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
open access

Anaerobic fermentation of simulated in-situ oil shale retort water

Description: The feasibility of removing soluble organics from oil shale retort water by anaerobic digestion with methane production was experimentally investigated. The following conclusions were made. The retort water studied had to be pretreated to remove toxic and add deficient constituents before it could be successfully treated with the anaerobic fermentation process. Pretreatment included pH adjustment to 7, ammonia reduction, and nutrient addition. A digested sludge from a conventional municipal sew… more
Date: November 1, 1977
Creator: Ossio, E. A.; Fox, J. P.; Thomas, J. F. & Poulson, R. E.
Item Type: Refine your search to only Article
Partner: UNT Libraries Government Documents Department
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Process and analytical studies of enhanced low severity co-processing using selective coal pretreatment

Description: This report describes progress on research during the eleventh quarter of this contract dealing with applications of coal pretreatment techniques in coal/oil co-processing and direct hydroliquefaction. The objectives of the project are to investigate various coal pretreatment techniques and to determine the effect of these pretreatment procedures on the reactivity of the coal. Reactivity enhancement will be evaluated under both direct hydroliquefaction and co-processing conditions. Coal convers… more
Date: 1991-06~
Creator: Baldwin, R. M.; Gaur, S. & Miller, R. L.
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
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Evaluation of the gas production economics of the gas hydrate cyclic thermal injection model. [Cyclic thermal injection]

Description: The objective of the work performed under this directive is to assess whether gas hydrates could potentially be technically and economically recoverable. The technical potential and economics of recovering gas from a representative hydrate reservoir will be established using the cyclic thermal injection model, HYDMOD, appropriately modified for this effort, integrated with economics model for gas production on the North Slope of Alaska, and in the deep offshore Atlantic. The results from this e… more
Date: May 1, 1985
Creator: Kuuskraa, V.A.; Hammersheimb, E. & Sawyer, W.
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
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Damage to fused silica windows while under simultaneous exposure to flowing solvents and laser radiation and 308nm

Description: This paper reports the results of a study to determine the degrading effects of flowing dye solvents on the laser damage threshold of fused-silica windows at 308nm. Thresholds were measured at the SiO/sub 2/solvent interface in a test cell. Bare SiO/sub 2/ tested in air at 308nm (20ns) typically exhibits a threshold ranging from 4 to 10 Jcm/sup 2/; with the solvent cyclohexane in contact, a threshold as low as 0.3 Jcm/sup 2/ was measured. The damage data indicate that window lifetime (number of… more
Date: January 1, 1987
Creator: Mauro, B. R.; Foltyn, S. R. & Sanders, V. E.
Item Type: Refine your search to only Article
Partner: UNT Libraries Government Documents Department
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Methane oxidation over dual redox catalysts

Description: The objective of this research is to develop approaches to direct catalytic oxidation of methane over oxides that are doubly doped with transition metal ions. The desired process aims at employing a double redox mechanism, where one redox couple is utilized for activation of oxygen and another for the trapping of CH{sub 3} radicals. The methyl radicals can either recombine, giving C{sub 2} hydrocarbons, or be converted, via electron transfer reaction, to carbocations. The latter species can rea… more
Date: September 1, 1989
Creator: Klier, Kamil; Herman, Richard G. & Sojka, Zbigniew
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
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Investigation and evaluation of geopressured-geothermal wells

Description: Over the life of the project, 1143 wildcat wells were screened for possible use. Although many did not meet the program's requirement for sand development, a surprisingly large number were abandoned because of downhole mechanical problems. Only 94 of these wells were completed as commercial hydrocarbon producers. Five wells of opportunity were funded for testing. Of these, two were evaluated for their hydraulic energy, thermal energy, and recoverable methane, and three were abandoned because of… more
Date: September 1, 1980
Creator: Hartsock, J.H. & Rodgers, J.A.
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
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Preliminary economic evaluation of the Alkox process

Description: A new chemical process has been invented at Battelle Pacific Northwest Laboratories for converting alkanes to alcohols. This new chemistry has been named the Alkox Process.'' Pacific Northwest Laboratory prepared a preliminary economic analysis for converting cyclohexane to cyclohexanol, which may be one of the most attractive applications of the Alkox process. A process flow scheme and a material balance were prepared to support rough equipment sizing and costing. The results from the economic… more
Date: September 1, 1991
Creator: Silva, L.J.; Lilga, M.A.; Camaioni, D.M. & Snowden, L.J.
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
open access

Development of BEACON technology. Quarterly report, October-December 1982

Description: The BEACON process involves the catalytic deposition of a highly reactive form of carbon from a gas stream which contains carbon monoxide. The carbon-depleted gas is combusted with air to produce power, and the carbon is reacted with steam to produce methane or hydrogen. During the quarter both SOHIO and TRW worked on catalysts which would suppress methane formation during steaming thus increasing the amount of hydrogen formed. At SOHIO a C77-K2 catalyst promoted with a Class II compound showed… more
Date: April 1, 1983
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
open access

Extraction and identification of organic materials present in soot from a natural gas flame

Description: Aliphatic and polynuclear aromatic hydrocarbons are readily extracted from soot formed from a natural gas flame using methylene chloride and ultrasonic agitation. Identification of 24 organic compounds via capillary column GC retention times and GC-MS data is reported along with details of experimental procedures.
Date: January 1, 1978
Creator: Vick, R.D. & Avery, M.J.
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
open access

Geopressured-geothermal energy development: government incentives and institutional structures

Description: The following subjects are included: a geothermal resource overview, the evolution of the current Texas geopressured-geothermal institutional structure, project evaluation with uncertainty and the structure of incentives, the natural gas industry, the electric utility industry, potential governmental participants in resource development, industrial users of thermal energy, current government incentives bearing on geopressured-geothermal development, six profiles for utilization of the geopressu… more
Date: January 1, 1979
Creator: Frederick, D.O.; Prestwood, D.C.L.; Roberts, K. & Vanston, J.H. Jr.
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
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