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Assessment of research and development (R and D) needs in ammonia safety and environmental control

Description: This report characterizes the ammonia industry operations, reviews current knowledge of ammonia release and subsequent impacts, summarizes the status of release prevention and control methods and identify research and development needs for safety and environmental control. Appendices include: accidental spills and human exposure; adiabatic mixing of liquid nitrogen and air; fire and explosion hazards; and environmental impact rating tables. (PSB)
Date: September 1, 1981
Creator: Brenchley, D.L.; Athey, G.F. & Bomelburg, H.J.
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
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Catalyst and process development for hydrogen preparation from future fuel cell feedstocks. Quarterly progress report, October 1, 1979-December 31, 1979. [Pt/Rh, Ni/Rh, Ni/Pt/Rh, Ni, Ni/Ru, Ni/Pt, Ni/Co]

Description: Twelve steam reforming catalysts were evaluated using an autothermal reforming screening unit. Duplicate tests were run with two samples to determine test variability. The samples tested contained either base metals, precious metals, or combinations of base and precious metals. The test was capable of distinguishing among samples where gross variations in composition are the main factor; for example, catalysts containing 2% by weight precious metals are more active than catalysts containing 15%… more
Date: January 1, 1980
Creator: Yarrington, R M; Feins, I R; Hwang, H S & Mayer, C P
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
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Fusion utilization projections in the United States energy economy

Description: The following topics are discussed in some detail in this report: (1) applications of fusion energy, (2) fusion implementation in the US energy system, (3) reactor performance requirements, (4) technology for electric applications, and (5) technology for synthetic fuel/chemical applications. (MOW)
Date: November 1, 1979
Creator: Powell, J.R. & Fillo, J.A.
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
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Progress report on the development of the General Atomic thermochemical water-splitting process

Description: The major accomplishments of the DOE funded part of the GA thermochemical water-splitting program are reported. They include: completion of installation of all bench-scale equipment; operation and preliminary data acquisition for bench-scale subunits I and II; design, installation and operation of a system for iodine removal from the low phase; review and modification of Section III of the engineering flowsheet resulting in an increase in process efficiency and decrease in capital cost; and com… more
Date: August 1, 1980
Creator: Besenbruch, G.E.; Allen, C.L.; Brown, L.C.; McCorkle, K.; Rode, J.S.; Norman, J.H. et al.
Item Type: Refine your search to only Article
Partner: UNT Libraries Government Documents Department
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Development of BEACON technology. Quarterly report, April-June 1982

Description: The BEACON process involves the catalytic deposition of a highly reactive form of carbon from a gas stream which contains carbon monoxide. The carbon-depleted gas is combusted with air to produce power, and the carbon is reacted with steam to produce methane or hydrogen. Experiments were continued this quarter with the objective of improving the carbon deposition efficiency using a Paraho retort off-gas mixture. Analysis has shown that the use of the Paraho off-gas to make hydrogen would be att… more
Date: March 1, 1983
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
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Low cost hydrogen/novel membrane technology for hydrogen separation from synthesis gas, Phase 1. [Poly(methyl pentene) and poly(etherimide)]

Description: This report summarizes the development of polymer membranes useful in the separation of hydrogen from coal-derived synthesis gas during period 1 October 1985--30 September 1986. During the last year several high performance membranes were developed for the separation of hydrogen from nitrogen and carbon monoxide. The heat resistant resins poly(methyl pentene) (TPX), Mitsui Petrochemical Industries, New York, NY and poly(etherimide) (ULTEM, General Electric, Pittsfield, MA) have been selected as… more
Date: January 1, 1986
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
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Catalyst and process development for hydrogen preparation from future fuel cell feedstocks. Quarterly report, April 1-June 30, 1980. [Pt/Pd]

Description: Phase II of the contract, which involved catalyst preparation and evaluation, was nearly completed this quarter. Phase III, which calls for the design and construction of a fuel processor, was started. During the quarter, four types of tests were run on the small scale catalyst screening unit. The operating line for coke-free operations was found to be approximately between 0.41 to 0.44 O/sub 2//C level. Screening at lower O/sub 2//C levels led to problems with plugging. In other tests, increas… more
Date: July 1, 1980
Creator: Yarrington, R M; Feins, I R & Hwang, H S
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
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Photoproduction of hydrogen by membranes of green photosynthetic bacteria

Description: Photoproduction of H/sub 2/ from ascorbate by unit-membrane vesicles from Chlorobium limicola f. thiosulfatophilum was achieved with a system containing gramicidin D, tetramethyl-p-phenylenediamine, methyl viologen, dithioerythritol, Clostridium hydrogenase, and an oxygen-scavenging mixture of glucose, glucose oxidase, ethanol, and catalase. Maximum quantum yield was less than one percent. Half maximum rate of H/sub 2/ production occurred at a white-light intensity of approximately 0.15 cm/sup … more
Date: January 1, 1980
Creator: Bernstein, J D & Olson, J M
Item Type: Refine your search to only Article
Partner: UNT Libraries Government Documents Department
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Low cost hydrogen/novel membranes technology for hydrogen separation from synthesis gas, Phase 1. [Palladium-silver/poly(etherimide), polysulfone/poly(dimethylsiloxane)/poly(ether-esteramide)composite membranes]

Description: During this quarter, work continued on the development of high-flux palladium-silver membranes for the separation of hydrogen from carbon dioxide. Palladium-silver/poly(etherimide) composite membranes were prepared by a vacuum sputtering technique. The influence of different poly(etherimide) support membranes on the performance of palladium-silver membranes was investigated. All membranes tested showed a hydrogen/carbon dioxide selectivity lower than that of the uncoated poly(etherimide)/poly(d… more
Date: January 1, 1987
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
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Low cost hydrogen/novel membrane technology for hydrogen separation from synthesis gas, Phase 1. [Polyetherimide, cellulose acetate and ethylcellulose]

Description: The goal of this program is to develop polymer membranes useful in the preparation of hydrogen from coal-derived synthesis gas. During this quarter the first experiment were aimed at developing high performance composite membranes for the separation of hydrogen from nitrogen and carbon monoxide. Three polymers have been selected as materials for these membranes: polyetherimide cellulose acetate and ethylcellulose. This quarter the investigators worked on polyetherimide and cellulose acetate mem… more
Date: January 1, 1986
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
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Development of BEACON technology. Quarterly report, October-December 1982

Description: The BEACON process involves the catalytic deposition of a highly reactive form of carbon from a gas stream which contains carbon monoxide. The carbon-depleted gas is combusted with air to produce power, and the carbon is reacted with steam to produce methane or hydrogen. During the quarter both SOHIO and TRW worked on catalysts which would suppress methane formation during steaming thus increasing the amount of hydrogen formed. At SOHIO a C77-K2 catalyst promoted with a Class II compound showed… more
Date: April 1, 1983
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
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Catalyst and process development for hydrogen preparation from future fuel cell feedstocks. Quarterly progress report, January 1, 1980-March 31, 1980. [Pt/Rh, Pd, Pt, Rh, Ni/Rh, Rh/Re, Ni]

Description: Catalysts are being screened to steam reform hydrocarbons in an autothermal reformer (STR). Twenty-one samples have been screened in a 1-in.-diam (ATR) reactor using No. 2 oil as the hydrocarbon feed. A series of platinum-rhodium catalysts were evaluated to study the effect of varying compositions. A sample containing 1.7% Pt/0.3% Rh was most active but the difference among the samples was within the range of test variability. Development of a more realistic test has been started. The effect of… more
Date: April 1, 1980
Creator: Yarrington, R M; Feins, I R & Hwang, H S
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
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Catalyst and process development for the H/sub 2/ preparation from future fuel cell feedstocks. Quarterly progress report, October 1, 1978-December 31, 1978

Description: The work done under this contract in the last quarter of 1978 was concerned with Phase I, which involved preliminary catalyst and process evaluation. The processes under study are hydrogen assisted steam reforming (HASR), catalytic partial oxidation (CPO), and autothermal steam reforming (ATR). Existing Engelhard test units were modified to carry out preliminary runs using the first two processes. Technical analysis to support work in this area consisted of heat and material balances constraine… more
Date: January 1, 1979
Creator: Yarrington, R M; Feins, I R; Hwang, H S & Mayer, C P
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
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Solar/hydrogen systems for the 1985 to 2000 time frame. Volume I. Solar/hydrogen systems assessment. Final report

Description: The findings of a study of opportunities for commercialization of systems capable of producing hydrogen from solar energy are presented in two volumes. A compendium of monographs by specialists in the fields of solar energy conversion technologies, hydrogen production technologies and related technology descriptions from the general literature comprise Volume II. This data base was used to support an evaluation and selection process that identified four candidate solar/hydrogen systems best sui… more
Date: June 1, 1980
Creator: Foster, R. W.; Tison, R. R.; Escher, W. J.D. & Hanson, J. A.
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
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NMR studies of hydrogen relaxation and diffusion in TiFeH/sub x/ and TiFe/sub 1-y/Mn/sub y/H/sub x/

Description: TiFe and related intermetallic compounds react directly with hydrogen gas to form hydrides which are suitable for energy storage applications. Although some of the characteristics of these materials have been evaluated, many important physical properties such as crystal structures, electronic structures, and hydrogen diffusion behavior are unknown. Since nuclear magnetic resonance (NMR) provides detailed information on the physical states of the hydrogen atoms, various NMR parameters are being … more
Date: January 1, 1977
Creator: Bowman, R.C. Jr.; Carter, G.C.; Chabre, Y. & Attalla, A.
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
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Comparative analysis of hydrogen fire and explosion incidents. Quarterly report No. 1, September 1, 1977--November 30, 1977

Description: A hydrogen accident data base covering industrial and other forms of hydrogen use is being developed. Ten different sources of hydrogen accident reports have contributed 168 reports for the period 1971-1976 and 402 reports for the years prior to 1971. Additional data are being sought through a survey of major hydrogen consuming industries. National gas consumption and accident data have also been collected to serve as a basis for comparison with the hydrogen accident data. During the next quart… more
Date: December 1, 1977
Creator: Zalosh, R. G.
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
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Vectorially photoinduced electron-transfer processes across water-in-oil interfaces of microemulsions

Description: Artificial photosynthetic devices are potential fuel sources. The basic idea in the design of such devices is a photosensitized electron-transfer that yields chemical species capable of reducing and oxidizing water to hydrogen and oxygen. A fundamental difficulty in effecting this transfer is the thermodynamically favored back reactions of the intermediary redox species. An interfacial model composed of a water-in-oil microemulsion is suggested to provide the separation of these redox species, … more
Date: July 1, 1980
Creator: Willner, I.; Otvos, J. W. & Calvin, M.
Item Type: Refine your search to only Article
Partner: UNT Libraries Government Documents Department
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Thermochemical water-splitting cycle, bench-scale investigations and process engineering. Annual report, October 1, 1978-September 30, 1979

Description: A program to investigate thermochemical water splitting has been under way at General Atomic Company (GA) since October 1972. This document is an annual progress report of Department of Energy (DOE) sponsored process development work on the GA sulfur-iodine thermochemical water splitting cycle. The work consisted of laboratory bench-scale investigations, demonstration of the process in a closed-loop cycle demonstrator, and process engineering design studies. A bench-scale system, consisting of … more
Date: March 1980
Creator: Caprioglio, G.; McCorkle, K. H.; Besenbruch, G. E. & Rode, J. S.
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
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Study of hydrogen-powered versus battery-powered automobiles

Description: A study conducted to compare the technological status and the resultant potential vehicle characteristics for hydrogen- and battery-powered automobiles that could be produced from 1985 to 2000 is documented in 3 volumes. The primary objectives of the study were: the assessments of applicable energy storage and propulsion technology for the two basic vehicle types (applied to four-passenger cars); a rigorous comparison of vehicle weight, size, and usefulness versus design range; and an investiga… more
Date: May 1, 1979
Creator: Donnelly, J.J. Jr.; Greayer, W.C.; Nichols, R.J. & Escher, W.J.D.
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
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Operating experience with a liquid-hydrogen fueled Buick and refueling system

Description: An investigation of liquid-hydrogen storage and refueling systems for vehicular applications was made in a recently completed project. The vehicle used in the project was a 1979 Buick Century sedan with a 3.8-L displacement turbocharged V6 engine and an automatic transmission. The vehicle had a fuel economy for driving in the high altitude Los Alamos area that was equivalent to 2.4 km/L of liquid hydrogen or 8.9 km/L of gasoline on an equivalent energy basis. About 22% less energy was required … more
Date: January 1, 1982
Creator: Stewart, W.F.
Item Type: Refine your search to only Article
Partner: UNT Libraries Government Documents Department
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LASL thermochemical hydrogen program status on October 31, 1977. [Cycles using sulfuric acid as an intermdiate]

Description: The LASL Hydrogen Program is continuing its investigation of practical schemes to decompose water thermochemically for hydrogen production. Efforts were and are being devoted to process improvements in cycles that use sulfuric acid as an intermediate. Sulfuric acid-hydrogen bromide cycles are being studied as a means of overcoming the heat penalty in drying acid solutions. An alternate approach involves the use of insoluble bismuth sulfate that is precipitated from acid solution. Preliminary en… more
Date: January 1, 1977
Creator: Cox, K.E. & Bowman, M.G.
Item Type: Refine your search to only Article
Partner: UNT Libraries Government Documents Department
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