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Design, Synthesis and Study of Dendrimers as Nanoscaffolds for Solar Energy Harvest

Description: Designing molecules in which the vectorial motions of charges can be controlled has been of significant research interest in the recent past. Covalent linear arrays of chromophores or other molecular assemblies such as liquid crystals, zeolites, polymers, peptides, and amphiphiles have all been used as components for this purpose. Significant amount of this effort also involved the use of dendrimers as the molecular architecture. The structural feature in which multiple functionalities are pres… more
Date: January 25, 2008
Creator: Thayumanavan, Sankaran
Partner: UNT Libraries Government Documents Department
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HAZARDOUS MATERIALS IN AQUATIC ENVIRONMENTS OF THE MISSISSIPPI RIVER BASIN

Description: In December 1992, the CBR was awarded a five-year grant of $25M from the US Department of Energy Office of Environmental Management (DOE-EM) to study pollution in the Mississippi River system. The ''Hazardous Materials in Aquatic Environments of the Mississippi River Basin'' project was an interdisciplinary, collaborative research and education project aimed at elucidating the nature and magnitude of toxic materials that contaminate aquatic environments. This project funded 15 collaborative clu… more
Date: December 1, 2003
Creator: McLachlan, John A.
Partner: UNT Libraries Government Documents Department
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The Preparation & Catalytic Applications of Silica. Final Report

Description: This final report covers the entire period from its inception in 11/01/1985 through the final funding period, 10/30/2002. The grant was initiated when the PI was on the Faculty in the Department of Chemical Engineering at the University of Illinois at Chicago and continued without interruption when he moved to Tulane University in August 1990. The designation number on the award may have changed as a result of a shift from Argonne National Laboratory to Oak Ridge and then back to Argonne. This … more
Date: December 31, 1985
Creator: Gonzales, R.
Partner: UNT Libraries Government Documents Department
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Sequence and time correlation in munti-electron systems

Description: The project was completed with over 12 papers published in the final contract period in the field of atomic collisions. Also more than 12 contributed talks were given and more than 4 invited talks. The general ideas were related to how time works in quantum systems and how this can be used to control atomic and chemical reactions.
Date: February 2, 2004
Creator: McGuire, Jim
Partner: UNT Libraries Government Documents Department
open access

GROWTH, SURFACE CHARACTERIZATION, AND REACTIVITY OF TIO2 ANATASE FILMS-EPSCOR

Description: TiO2 is as promising photocatalyst for environmental degradation of organic compounds and solar energy conversion. Commercial titania is a mixture of rutile and anatase phases, and, for as of yet unknown reasons, anatase is the photocatalytically more active form. In contrast to rutile, atomic-scale information on well-characterized anatase surfaces and their chemical properties was virtually absent at the beginning of this project. We have performed surface science investigations of anatase wi… more
Date: December 15, 2004
Creator: Diebold, Ulrike
Partner: UNT Libraries Government Documents Department
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Fundamental Mechanistic Investigations of Silane and Chlorocarbon Addition to Low Valent Palladium Species and their Application to Catalysis

Description: The collaboration between Mark Fink (Tulane University) and R. Morris Bullock (Brookhaven National Laboratory, currently at PNL) is an effort to understand some of the fundamental processes involved in catalytic bond activations with low coordinate palladium species. The project involves the photochemical generation of reactive low-valent palladium species as transients using nanosecond laser flash photolysis and the subsequent investigation of their reactions with chloroarenes and hydrosilanes… more
Date: January 27, 2009
Creator: Fink, Mark J.
Partner: UNT Libraries Government Documents Department
open access

Field-Portable Immunoassay Instruments and Reagents to Measure Chelators and Mobile Forms of Uranium

Description: A collaborator in the Chemistry Department at Tulane University, Dr. Harry Ensley, has synthesized a new bifunctional chelator with specificity for ionic mercury (Hg2+) and methymercury (MeHg+). These chelators are based upon phenantholine derivative containing sulfhydryl functional groups. Experiments are underway to generate protein conjugates of this chelator to use in immunizations and screening.
Date: June 1, 2005
Creator: Blake, Diane A.
Partner: UNT Libraries Government Documents Department
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Field-Portable Immunoassay Instruments and Reagents to Measure Chelators and Mobile Forms of Uranium

Description: The goals for the 3-year project period are (1) to test and validate the present uranium sensor and develop protocols for its use at the NABIR Field Research Center; (2) to develop new reagents that will provide superior performance for the present hand-held immunosensor; and (3) to develop new antibodies that will permit this sensor to also measure other environmental contaminants (chromium, mercury, and/or DTPA). Sensor design modifications are underway via international collaborations. New r… more
Date: June 1, 2003
Creator: Blake, Diane A.
Partner: UNT Libraries Government Documents Department
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Field-Portable Immunoassay Instruments and Reagents to Measure Chelators and Mobile Forms of Uranium

Description: Progress Report Date: 01/23/06 (report delayed due to Hurricane Katrina) Report of results to date: The goals of this 3-year project are to: (1) update and successfully deploy our present immunosensors at DOE sites; (2) devise immunosensor-based assays for Pb(II), Hg(II), chelators, and/or Cr(III) in surface and groundwater; and (3) develop new technologies in antibody engineering that will enhance this immunosensor program. Note: Work on this project was temporarily disrupted when Hurricane Ka… more
Date: January 23, 2006
Creator: Blake, Diane A.
Partner: UNT Libraries Government Documents Department
open access

Final Technical Report - In-line Uranium Immunosensor

Description: In this project, personnel at Tulane University and Sapidyne Instruments Inc. developed an in-line uranium immunosensor that could be used to determine the efficacy of specific in situ biostimulation approaches. This sensor was designed to operate autonomously over relatively long periods of time (2-10 days) and was able to provide near real-time data about uranium immobilization in the absence of personnel at the site of the biostimulation experiments. An alpha prototype of the in-line immmuno… more
Date: July 5, 2006
Creator: Blake, Diane A.
Partner: UNT Libraries Government Documents Department
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Studies of Novel Quantum Phenomena in Ruthenates

Description: Strongly correlated oxides have been the subject of intense study in contemporary condensed matter physics, and perovskite ruthenates (Sr,Ca)n+1RunO3n+1 have become a new focus in this field. One of important characteristics of ruthenates is that both lattice and orbital degrees of freedom are active and are strongly coupled to charge and spin degrees of freedom. Such a complex interplay of multiple degrees of freedom causes the properties of ruthenates to exhibit a gigantic response to externa… more
Date: April 8, 2011
Creator: Mao, Zhiqiang
Partner: UNT Libraries Government Documents Department
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Field-Portable Immunoassay Instruments and Reagents to Measure Chelators and Mobile Forms of Uranium

Description: Previous studies from our laboratory have demonstrated the feasibility of immunoassays for identification and quantification of specific metal ions. Our ultimate goal for this project is to (1) isolate and characterize antibodies that recognize the most mobile form of uranium, UO22+; (2) assemble, test, and validate a new field-portable immunosensor based on these antibodies; (3) prepare new monoclonal antibodies to the primary chelators (EDTA and DTPA) found in DOE wastes.
Date: June 1, 2001
Creator: Blake, Diane A.
Partner: UNT Libraries Government Documents Department
open access

Environmental Analysis of Endocrine Disrupting Effects from Hydrocarbon Contaminants in the Ecosystem

Description: This annual report summarizes the progress of three years of a three-year grant awarded to the Center for Bioenvironmental Research (CBR) at Tulane and Xavier Universities. The objective of this project is to determine how environmental contaminants, namely hydrocarbons, can act as hormones or anti-hormones in different species present in aquatic ecosystems. The three major areas of research include (1) a biotechnology based screening system to identify potential hormone mimics and antagonists;… more
Date: June 1, 2000
Creator: McLachlan, John A.
Partner: UNT Libraries Government Documents Department
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Final report of research supported by DOE Grant No. DE-FG02-96ER14635: Photochemical studies of two component systems within the restricted spaces of zeolites.

Description: Most chemistry in nature occurs within a closed and confined space. In contrast to this time-evolved [m?] organic chemists have focused their interests in developing reaction methods in solution. The price for this is paid in terms of non-selectivity in product formation, expensive reagents, and enormous wastes. Eventually 'man-developed' solution methods to make molecules have to be replaced by more selective, more environmentally friendly, and less expensive strategies. One approach in this d… more
Date: May 5, 2002
Creator: Ramamurthy, V.
Partner: UNT Libraries Government Documents Department
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Environmental Analysis of Endocrine Disrupting Effects from Hydrocarbon Contaminants in the Ecosystem - Final Report - 09/15/1996 - 09/14/2000

Description: The three major components of the research included: (a) a biotechnology based screening system to identify potential hormone mimics and antagonists (b) an animal screening system to identify biomarkers of endocrine effects and (c) a literature review to identify compounds at various DOE sites that are potential endocrine disruptors. Species of particular interest in this study were those that can serve as sentinel species (e.g., amphibians) and thus provide early warning signals for more wides… more
Date: September 14, 2000
Creator: McLachlan, John A.
Partner: UNT Libraries Government Documents Department
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Technology and Risk Sciences Program. FY99 Annual Report

Description: In making the transition from weapons production to environmental restoration, DOE has found that it needs to develop reliable means of defining and understanding health and environmental risks and of selecting cost-efficient environmental management technologies so that cleanup activities can be appropriately directed. Through the Technology and Risk Sciences Project, the Entergy Spatial Analysis Research Laboratory attempts to provide DOE with products that incorporate spatial analysis techni… more
Date: January 1, 2000
Creator: Regens, James L.
Partner: UNT Libraries Government Documents Department
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