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Light alkane conversion processes - Suprabiotic catalyst systems for selective oxidation of light alkane gases to fuel oxygenates.

Description: The objective of the work presented in this paper is to develop new, efficient catalysts for the selective transformation of the light alkanes in natural gas to alcohols for use as liquid transportation fuels, fuel precursors and chemical products. There currently exists no DIRECT one-step catalytic air-oxidation process to convert these substrates to alcohols. Such a one-step route would represent superior useful technology for the utilization of natural gas and similar refinery-derived light … more
Date: July 1, 1992
Creator: Lyons, J. E.
Partner: UNT Libraries Government Documents Department
open access

Light alkane conversion processes - Suprabiotic catalyst systems for selective oxidation of light alkane gases to fuel oxygenates

Description: The objective of the work presented in this paper is to develop new, efficient catalysts for the selective transformation of the light alkanes in natural gas to alcohols for use as liquid transportation fuels, fuel precursors and chemical products. There currently exists no DIRECT one-step catalytic air-oxidation process to convert these substrates to alcohols. Such a one-step route would represent superior useful technology for the utilization of natural gas and similar refinery-derived light … more
Date: January 1, 1992
Creator: Lyons, J.E.
Partner: UNT Libraries Government Documents Department
open access

Catalytic conversion of light alkanes. Final report, January 1, 1990--October 31, 1994

Description: During the course of the first three years of the Cooperative Agreement (Phase I-III), we uncovered a family of metal perhaloporphyrin complexes which had unprecedented activity for the selective air-oxidation of fight alkanes to alcohols. The reactivity of fight hydrocarbon substrates with air or oxygen was in the order: isobutane>propane>ethane>methane, in accord with their homolytic bond dissociation energies. Isobutane was so reactive that the proof-of concept stage of a process for produci… more
Date: December 31, 1998
Partner: UNT Libraries Government Documents Department
open access

Catalytic conversion of light alkanes - phase V. Topical report, February 1993--October 1994

Description: We have made excellent progress toward a practical route from field butanes to MTBE, the oxygenate of choice for high-octane, clean-burning, environmentally acceptable reformulated gasoline. We have evaluated two proprietary process possibilities with a potential commercial partner and have conducted a joint catalyst evaluation program. The first of the two potential processes considered during the past quarter utilizes a two-step route from isobutane to tert-butyl alcohol, TBA. Not only is TBA… more
Date: December 31, 1998
Partner: UNT Libraries Government Documents Department
open access

Catalytic conversion of light alkanes: Proof of concept stage

Description: During the stage at which this work ended, our program consisted of two phases which were running concurrently, a research phase and a proof-of-concept phase. The function of the research phase is to design synthesize and perform laboratory tests on new materials in order to enhance the catalytic properties of the suprabiotic systems generated in our laboratories. Increases in catalytic activity and process selectivity as well as extensions of structure-activity relationships are examined. The … more
Date: June 1, 1995
Creator: Lyons, J.E.
Partner: UNT Libraries Government Documents Department
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