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Vapor space characterization of waste tank 241-C-106: Results from samples collected on February 15, 1994

Description: This document presents the details of the inorganic and organic analysis that was performed on samples from the headspace of Hanford waste tank 241-C-106. The results described were obtained to support the safety and toxicological evaluations. A summary of the results for the inorganic and organic analytes is included, as well as, a detailed description of the results which appears in the text.
Date: June 1, 1995
Creator: McVeety, B.D.; Clauss, T.W.; Young, J.S.; Ligotke, M.W.; Goheen, S.C.; Lucke, R.B. et al.
Partner: UNT Libraries Government Documents Department

Advanced materials for solid oxide fuel cells

Description: The purpose of this research is to improve the properties of the current state-of-the-art materials used for solid oxide fuel cells (SOFCs). The objectives are to: (1) develop materials based on modifications of the state-of-the-art materials; (2) minimize or eliminate stability problems in the cathode, anode, and interconnect; (3) Electrochemically evaluate (in reproducible and controlled laboratory tests) the current state-of-the-art air electrode materials and cathode/electrolyte interfacial properties; (4) Develop accelerated electrochemical test methods to evaluate the performance of SOFCs under controlled and reproducible conditions; and (5) Develop and test materials for use in low-temperature SOFCs.
Date: December 31, 1995
Creator: Armstrong, T. & Stevenson, J.
Partner: UNT Libraries Government Documents Department

Chemical structure and dynamics. Annual report 1994

Description: The Chemical Structure and Dynamics program was organized as a major component of Pacific Northwest Laboratory`s Environmental and Molecular Sciences Laboratory (EMSL), a state-of-the-art collaborative facility for studies of chemical structure and dynamics. Our program responds to the need for a fundamental, molecular-level understanding of chemistry at the wide variety of environmentally important interfaces by (1) extending the experimental characterization and theoretical description of chemical reactions to encompass the effects of condensed media and interfaces, and (2) developing a multidisciplinary capability for describing interfacial chemical processes within which the new knowledge generated can be brought to bear on complex phenomena in environmental chemistry and in nuclear waste processing and storage. This research effort was initiated in 1989 and will continue to evolve over the next few years into a program of rigorous studies of fundamental molecular processes in model systems, such as well-characterized surfaces, single-component solutions, clusters, and biological molecules; and studies of complex systems found in the environment (multispecies, multiphase solutions; solid/liquid, liquid/liquid, and gas/surface interfaces; colloidal dispersions; ultrafine aerosols; and functioning biological systems). The success of this program will result in the achievement of a quantitative understanding of chemical reactions at interfaces, and more generally in condensed media, that is comparable to that currently available for gas-phase reactions. This understanding will form the basis for the development of a priori theories for predictions of macroscopic chemical behavior in condensed and heterogeneous media, adding significantly to the value of field-scale environmental models, the prediction of short- and long-term nuclear waste storage stabilities, and other problems related to the primary missions of the DOE.
Date: July 1, 1995
Creator: Colson, S.D.
Partner: UNT Libraries Government Documents Department

Comprehensive facility energy assessment using FEDS

Description: The energy savings and demand reduction opportunities at the Army`s National Training Center at Fort Irwin, California, were evaluated. The Fort Irwin analysis made use of the recently developed Facility Energy Decision Screening (FEDS) System Level-2 software tool. FEDS is a systematic, technology-neutral, and fuel-neutral approach to evaluating energy savings opportunities at large facilities. FEDS analyzes most major building end uses (e.g., heating, cooling, lighting, ventilation, and service hot water), including interactive effects (e.g., the effect of a lighting technology on heating and cooling loads). FEDS output provides specific cost, energy (and demand) charges, and life-cycle cost (LCC) information, by cost-effective energy resource opportunities (EROs). The remaining end uses common to large facilities (e.g., motors, transmission and distribution, vehicles) are analyzed using manual calculation methods. The present value (PV) of the installed cost of all EROs constituting the minimum LCC efficiency resource (i.e., cost-effective) at Fort Irwin is approximately $23.9 million in 1994 dollars (1994$). The PV of the energy and demand, operations and maintenance (O&M), and replacement savings associated with this investment is approximately $87.3 million, for an overall NPV of $63.6 million. This paper will describe the FEDS process and present detailed results of the comprehensive energy resource assessment conducted at Fort Irwin.
Date: December 1, 1994
Creator: Hadley, D.L.; Keller, J.M.; Richman, E.E. & Quinones, R.
Partner: UNT Libraries Government Documents Department

TWEAT `95: User`s documentation update

Description: This report is designed to be a supplement to TWEAT`94 (PVTD-C94-05.01K Rev.1). It is intended to describe the primary features of the Ternary Waste Envelope Assessment Tool software package that have been added in FY`95 and how to use them. It contains only minimal duplication of information found in TWEAT`94 even though all features of TWEAT`94 will still be available. Emphasis on this Update is the binary plotting capability and the OWL Import modifications. Like it`s predecessors, this manual does not provide instructions for modifying the program code itself. The user of TWEAT`95 is expected to be familiar with the basic concepts and operation of the TWEAT software as discussed in TWEAT`94. Software and hardware requirements have not changed since TWEAT`94. TWEAT has now been tested using Macintosh System software versions 6.05 through 7.5.
Date: March 1, 1996
Creator: Robertus, B. & Lambert, R.
Partner: UNT Libraries Government Documents Department

Hanford Waste Vitrification Plant hydrogen generation study: Formation of ammonia from nitrate and nitrate in hydrogen generating systems

Description: The Hanford Waste Vitrification Plant (HWVP) is being designed for the Departrnent of Energy (DOE) to immobilize pretreated highly radioactive wastes in glass for permanent disposal in the HWVP, formic acid is added to the waste before vitrification to adjust glass redox and melter feed rheology. The operation of the glass melter and durability of the glass are affected by the glass oxidation state. Formation of a conductive metallic sludge in an over-reduced melt can result in a shortened melter lifetime. An over-oxidized melt may lead to foaming and loss of ruthenium as volatile RuO{sub 4}. Historically, foaming in the joule heated ceramic melter has been attributed to gas generation in the melt which is controlled by instruction of a reductant such as formic acid into the melter feed. Formic acid is also found to decrease the melter feed viscosity thereby facilitating pumping. This technical report discusses the noble metal catalyzed formic acid reduction of nitrite and/or nitrate to ammonia, a problem of considerable concern because of the generation of a potential ammonium nitrate explosion hazard in the plant ventilation system.
Date: February 1, 1996
Creator: King, R.B. & Bhattacharyya, N.K.
Partner: UNT Libraries Government Documents Department

Integrity assessment plan for PNL 300 area radioactive hazardous waste tank system. Final report

Description: The Pacific Northwest Laboratory (PNL), operated by Battelle Memorial Institute under contract to the U.S. Department of Energy, operates tank systems for the U.S. Department of Energy, Richland Operations Office (DOE-RL), that contain dangerous waste constituents as defined by Washington State Department of Ecology (WDOE) Dangerous Waste Regulations, Washington Administrative Code (WAC) 173-303-040(18). Chapter 173-303-640(2) of the WAC requires the performance of integrity assessments for each existing tank system that treats or stores dangerous waste, except those operating under interim status with compliant secondary containment. This Integrity Assessment Plan (IAP) identifies all tasks that will be performed during the integrity assessment of the PNL-operated Radioactive Liquid Waste Systems (RLWS) associated with the 324 and 325 Buildings located in the 300 Area of the Hanford Site. It describes the inspections, tests, and analyses required to assess the integrity of the PNL RLWS (tanks, ancillary equipment, and secondary containment) and provides sufficient information for adequate budgeting and control of the assessment program. It also provides necessary information to permit the Independent, Qualified, Registered Professional Engineer (IQRPE) to approve the integrity assessment program.
Date: March 1, 1996
Partner: UNT Libraries Government Documents Department

Thermal and combined thermal and radiolytic reactions involving nitrous oxide, hydrogen, and nitrogen in the gas phase; comparison of gas generation rates in supernate and solid fractions of Tank 241-SY-101 simulated waste

Description: This report summarizes progress made in evaluating me by which flammable gases are generated in Hanford double-shell tank wastes, based on the results of laboratory tests using simulated waste mixtures. Work described in this report. was conducted at Pacific Northwest Laboratory (PNL) for the Flammable Gas Safety Project, the purpose of which is to develop information needed to support Westinghouse Hanford Company (WHC) in their efforts to ensure the safe interim storage of wastes at the Hanford Site. This work is related to gas generation studies being performed at Georgia Institute of Technology (GIT), under subcontract to PNL, using simulated wastes, and to studies being performed at VMC using actual wastes.
Date: March 1, 1995
Creator: Bryan, S.A. & Pederson, L.R.
Partner: UNT Libraries Government Documents Department

Chemical structure and dynamics. Annual report 1995

Description: The Chemical Structure and Dynamics program is a major component of Pacific Northwest National Laboratory`s Environmental Molecular Sciences Laboratory (EMSL), providing a state-of-the-art collaborative facility for studies of chemical structure and dynamics. We respond to the need for a fundamental, molecular-level understanding of chemistry at a wide variety of environmentally important interfaces by (1) extending the experimental characterization and theoretical description of chemical reactions to encompass the effects of condensed media and interfaces; (2) developing a multidisciplinary capability for describing interfacial chemical processes within which the new knowledge generated can be brought to bear on complex phenomena in environmental chemistry and in nuclear waste processing and storage; and (3) developing state-of-the-art analytical methods for the characterization of waste tanks and pollutant distributions, and for detection and monitoring of trace atmospheric species.
Date: May 1996
Creator: Colson, S. D. & McDowell, R. S.
Partner: UNT Libraries Government Documents Department

Correlation of XANES features with the scintillation efficiencies of Ce doped alkaline earth lithium silicate glasses

Description: Cerium-activated, lithium-silicate glasses are widely used as thermal neutron detectors because of their versatility, robustness and low cost. The glasses convert the energy of the neutrons to visible light pulses that may be counted. This process, scintillation, is generally thought to be composed of three steps: ionization, energy transfer, and luminescence. If defects are present, they can trap the excitations, altering the scintillation output. These features have been discussed previously. The presence of magnesium in these glasses increases scintillation efficiency, but as previously observed the effect drops by a factor greater than 2.5 with substitution through the series of alkaline earths. Here, cerium activated glasses of composition 20Li{sub 2}O{center_dot}15MO{center_dot}64.4SiO{sub 2}{center_dot}0.6Ce{sub 3}O{sub 3} (where m is Mg, Ca, Sr, or Ba) exhibit scintillation efficiencies that vary by more than a factor of 2.5 with the alkaline earth. Previous work has suggested a correlation between the microstructure of these glasses and scintillation efficiency. Measurements of the Ce L{sub III} x-ray absorption edge in the Mg, Ca and Sr glasses display a feature near the absorption edge that is suggestive of the presence of Ce{sup 4+}. The area of this peak is, in fact, correlated with the scintillation efficiency of the glass. The amount of Ce{sup 4+} indicated by the intensity of this feature is, however, too high to be a permanent population. The authors suspect that the feature is a transient phenomenon related to creation of Ce{sup 4+} and trapped electrons due to photoionization by the x-ray beam.
Date: November 1, 1994
Creator: Blanchard, D.L.; Sunberg, D.S.; Craig, R.A.; Bliss, M. & Weber, M.J.
Partner: UNT Libraries Government Documents Department

Identifying new technologies that save energy and reduce costs to the Federal sector: The New Technology Program

Description: In 1990 the New Technology Demonstration Program (formerly the Test Bed Demonstration Program) was initiated by the US Department of Energy`s Office (DOE`s) of Federal Energy Management Programs with the purpose of accelerating the introduction of new technologies into the Federal sector. The program has since expanded into a multi-laboratory collaborative effort that evaluates new technologies and shares the results with the Federal design and procurement communities. These evaluations are performed on a collaborative basis which typically includes technology manufacturers, Federal facilities, utilities, trade associations, research institutes, and other in partnership with DOE. The end result is a range of effective technology transfer tools that provide operations and performance data on new technologies to Federal designers, building managers, and procurement officials. These tools assist in accelerating a technology`s Federal application and realizing reductions in energy consumption and costs.
Date: November 1, 1995
Creator: Hunt, W.D.M.; Conover, D.R. & Stockmeyer, M.K.
Partner: UNT Libraries Government Documents Department

Hanford radiological protection support services. Annual report for 1995

Description: Various Hanford Site radiation protection services provided by the Pacific Northwest National Laboratory for the U.S. Department of Energy Richland Operations Office and Hanford contractors are described in this annual report for calendar year 1995. These activities include external dosimetry measurements and evaluations, internal dosimetry measurements and evaluations, in vivo measurements, radiological record keeping, radiation source calibration, and instrument calibration and evaluation. For each of these activities, the routine program and any program changes or enhancements are described, as well as associated tasks, investigations, and studies. Program-related publications, presentations, and other staff professional activities are also described.
Date: May 1, 1996
Creator: Lyon, M.; Bihl, D.E. & Carbaugh, E.H.
Partner: UNT Libraries Government Documents Department

Impacts on health and safety from transfer/consolidation of nuclear materials and hazardous chemicals

Description: Environmental restoration plans at the US Department of Energy (USDOE) Hanford Site calls for transfer/consolidation of ``targets/threats,`` namely nuclear materials and hazardous chemicals. Reductions in the health and safety hazards will depend on the plans implemented. Pacific Northwest Laboratory (PNL) estimated these potential impacts, assuming implementation of the current reference plan and employing ongoing risk and safety analyses. The results indicated the potential for ``significant`` reductions in health and safety hazards in the long term (> 25 years) and a potentially ``noteworthy`` reduction in health hazard in the short term ({le} 25 years).
Date: November 1, 1994
Creator: Gallucci, R.H.V.
Partner: UNT Libraries Government Documents Department

Alternative comparison, analysis, and evaluation of solid waste and materials system alternatives

Description: This paper presents a comprehensive analysis of the impact of solid waste technical options on values and objectives that are important to the public. It is written in support of the Solid Waste and Materials Systems Alternatives Study (WHC, 1995). Described are the values that were identified, the major programmatic risks, how the impacts were measured, the performance of alternatives, the methodology used for the analysis, and the implications of the results. Decision analysis was used to guide the collection and analysis of data and the logic of the evaluation. Decision analysis is a structured process for the analysis and evaluation of alternatives. It is theoretically grounded in a set of axioms that capture the basic principles of decision making (von Neuman and Morgenstern 1947). Decision analysis objectively specifies what factors are to be considered, how they are to be measured and evaluated, and heir relative importance. The result is an analysis in which the underlying rationale or logic upon which the decision is based is made explicit. This makes possible open discussion of the decision basis in which facts and values are clearly distinguished, resulting in a well- documented decision that can be clearly explained and justified. The strategy of decision analysis is to analyze the various components relevant to the decision separately and then integrate the individual judgments to arrive at an overall decision. This assures that all the relevant factors are identified and their relative importance is considered. The procedure for obtaining the individual judgments, and the decision rules, for combining them and evaluating alternatives, have both theoretical and empirical foundation in mathematics, economics, and psychology.
Date: September 1, 1995
Creator: Brothers, A.J.
Partner: UNT Libraries Government Documents Department

A brief review of bacterial transport in natural porous media

Description: This report reviews advances in the descriptions of microbial transport processes. The advances can often be translated into technological advances for solute transport, with potential applicability to a number of subsurface concerns related to solutes. The processes involved in microbial transport include physically controlled processes, chemically controlled processes, and biologically controlled processes. The physical processes involved in the transport of microbes include advection, diffusion, dispersion, straining, filtration, and exclusion. Biomass removal by chemical reactions has received less attention, and included electrostatic attraction and hydrophobic sorption. In addition, microbiologic processes affecting the fate and transport of microbes in the subsurface include growth and decay; motility and chemotaxis; biological adhesion; and predation. Interdependencies among these processes arise through coupling, e.g., as multiscale mixing in heterogeneous environments affects nutrient availability (growth) and filtration velocities (attachment).
Date: December 1, 1995
Creator: Ginn, T.R.
Partner: UNT Libraries Government Documents Department

Results of HWVP transuranic process waste treatment laboratory and pilot-scale filtration tests using specially ground zeolite

Description: Process waste streams from the Hanford Waste Vitrification Plant (HWVP) may require treatment for cesium, strontium, and transuranic (TRU) element removal in order to meet criteria for incorporation in grout. The approach planned for cesium and strontium removal is ion exchange using a zeolite exchanger followed by filtration. Filtration using a pneumatic hydropulse filter is planned to remove TRU elements which are associated with process solids and to also remove zeolite bearing the cesium and strontium. The solids removed during filtration are recycled to the melter feed system to be incorporated into the HWVP glass product. Fluor Daniel, Inc., the architect-engineering firm for HWVP, recommended a Pneumatic Hydropulse (PHP) filter manufactured by Mott Metallurgical Corporation for use in the HWVP. The primary waste streams considered for application of zeolite contact and filtration are melter off-gas condensate from the submerged bed scrubber (SBS), and equipment decontamination solutions from the Decontamination Waste Treatment Tank (DWTT). Other waste streams could be treated depending on TRU element and radionuclide content. Laboratory and pilot-scale filtration tests were conducted to provide a preliminary assessment of the adequacy of the recommended filter for application to HWVP waste treatment.
Date: March 1, 1996
Creator: Eakin, D.E.
Partner: UNT Libraries Government Documents Department

Area Monitoring Dosimeter Program for the Pacific Northwest National Laboratory: results for CY 1993 and CY 1994

Description: In January 1993, Pacific Northwest National Laboratory (PNNL) established an area monitoring dosimeter program in accordance with Article 514 of the Department of Energy (DOE) Radiological Control Manual (RCM)(DOE 1994). The purpose of the program was to minimize the number of areas requiring issuance of personnel dosimeters and to demonstrate that doses outside Radiological Buffer Areas are negligible. Article 51 1. la of the RCM requires issuance of personnel dosimeters if individuals are likely to receive a dose of at least 100 mrem annually. The area monitoring TLD program was a useful tool in determining exposure trends in work areas located outside of radiological areas. In several situations, the information obtained from this program was used to relocate staff or radioactive material resulting in potential dose reductions for staff.
Date: March 1996
Creator: Bivins, S. R. & Stoetzel, G. A.
Partner: UNT Libraries Government Documents Department

U.S./Mexico Border environmental study toxics release inventory data, 1988--1992

Description: This is a report on industrial toxic chemical releases and transfers based on information reported to the Toxics Release Inventory (TRI), a database maintained by the USEPA. This document discusses patterns of toxic chemical releases to the atmosphere, to water, to the land, and to underground injection; and transfers of toxic chemicals to Publicly Owned Treatment Works (POTW), and for disposal, treatment and other off-site transfers during the TRI reporting years 1988--1992. Geographic coverage is limited to the US side of the ``Border Area``, the geographic area situated within 100 km of the US/Mexico international boundary. A primary purpose of this study is to provide background information that can be used in the future development of potential ``indicator variables`` for tracking environmental and public health status in the Border Area in conjunction with the implementation of the North American Free Trade Agreement (NAFTA).
Date: February 1, 1996
Creator: O`Brien, R. F. & LoPresti, C. A.
Partner: UNT Libraries Government Documents Department

Federal Emergency Management Information System (FEMIS) system administration guide. Version 1.3

Description: The Federal Emergency Management Information System (FEMIS) is an emergency management planning and analysis tool that was developed by the (Pacific Northwest National Laboratory) (PNNL) under the direction of the U.S. Army Chemical Biological Defense Command. The FEMIS System Administration Guide defines FEMIS hardware and software requirements and gives instructions for installing the FEMIS software package. 91 This document also contains information on the following: software installation for the FEMIS data servers, communication server, mail server, and the emergency management workstations; distribution media loading and FEMIS installation validation and troubleshooting; and system management of FEMIS users, login, privileges, and usage. The system administration utilities (tools), available in the FEMIS client software, are described for user accounts and site profile. This document also describes the installation and use of system and database administration utilities that will assist in keeping the FEMIS system running in an operational environment.
Date: December 1, 1996
Creator: Burford, M.J.; Burnett, R.A. & Downing, T.R.
Partner: UNT Libraries Government Documents Department

Technetium in alkaline, high-salt, radioactive tank waste supernate: Preliminary characterization and removal

Description: This report describes the initial work conducted at Pacific Northwest National Laboratory to study technetium (Tc) removal from Hanford tank waste supernates and Tc oxidation state in the supernates. Filtered supernate samples from four tanks were studied: a composite double shell slurry feed (DSSF) consisting of 70% from Tank AW-101, 20% from AP-106, and 10% from AP-102; and three complexant concentrate (CC) wastes (Tanks AN-107, SY-101, ANS SY-103) that are distinguished by having a high concentration of organic complexants. The work included batch contacts of these waste samples with Reillex{trademark}-HPQ (anion exchanger from Reilly Industries) and ABEC 5000 (a sorbent from Eichrom Industries), materials designed to effectively remove Tc as pertechnetate from tank wastes. A short study of Tc analysis methods was completed. A preliminary identification of the oxidation state of non-pertechnetate species in the supernates was made by analyzing the technetium x-ray absorption spectra of four CC waste samples. Molybdenum (Mo) and rhenium (Re) spiked test solutions and simulants were tested with electrospray ionization-mass spectrometry to evaluate the feasibility of the technique for identifying Tc species in waste samples.
Date: January 1, 1997
Creator: Blanchard, D.L. Jr.; Brown, G.N. & Conradson, S.D.
Partner: UNT Libraries Government Documents Department

Tank Vapor Characterization Project: Headspace vapor characterization of Hanford Waste Tank 241-S-103: Results from samples collected on 06/12/96

Description: This report describes the analytical results of vapor samples taken from the headspace of the waste storage tank 241-S-103 (Tank S-103) at the Hanford Site in Washington State. The results described in this report were obtained to characterize the vapors present in the tank headspace and to support safety evaluations and tank farm operations. The results include air concentrations of selected inorganic and organic analytes and grouped compounds from samples obtained by Westinghouse Hanford Company (WHC) and provided for analysis to Pacific Northwest National Laboratory (PNNL). Analyses were performed by the Vapor Analytical Laboratory (VAL) at PNNL. Analyte concentrations were based on analytical results and, where appropriate, sample volumes provided by WHC. A summary of the inorganic analytes, permanent gases, and total non-methane organic compounds is listed in Table S.1. The three highest concentration analytes detected in SUMMA{trademark} canister and triple sorbent trap samples are also listed in Table S.1. Detailed descriptions of the analytical results appear in the appendices.
Date: January 1, 1997
Creator: Evans, J.C.; Pool, K.H. & Thomas, B.L.
Partner: UNT Libraries Government Documents Department

End-use load control for power system dynamic stability enhancement

Description: Faced with the prospect of increasing utilization of the transmission and distribution infrastructure without significant upgrade, the domestic electric power utility industry is investing heavily in technologies to improve network dynamic performance through a program loosely referred to as Flexible AC Transmission System (FACTS). Devices exploiting recent advances in power electronics are being installed in the power system to offset the need to construct new transmission lines. These devices collectively represent investment potential of several billion dollars over the next decade. A similar development, designed to curtail the peak loads and thus defer new transmission, distribution, and generation investment, falls under a category of technologies referred to as demand side management (DSM). A subset of broader conservation measures, DSM acts directly on the load to reduce peak consumption. DSM techniques include direct load control, in which a utility has the ability to curtail specific loads as conditions warrant. A novel approach has been conceived by Pacific Northwest National Laboratory (PNNL) to combine the objectives of FACTS and the technologies inherent in DSM to provide a distributed power system dynamic controller. This technology has the potential to dramatically offset major investments in FACTS devices by using direct load control to achieve dynamic stability objectives. The potential value of distributed versus centralized grid modulation has been examined by simulating the western power grid under extreme loading conditions. In these simulations, a scenario is analyzed in which active grid stabilization enables power imports into the southern California region to be increased several hundred megawatts beyond present limitations. Modeling results show distributed load control is up to 30 percent more effective than traditional centralized control schemes in achieving grid stability.
Date: February 1, 1997
Creator: Dagle, J. E.; Winiarski, D. W. & Donnelly, M. K.
Partner: UNT Libraries Government Documents Department

Product consistency testing of three reference glasses in stainless steel and perfluoroalkoxy resin vessels

Description: Because of their chemical durability, silicate glasses have been proposed and researched since the mid-1950s as a medium for incorporating high-level radioactive waste (HLW) generated from processing of nuclear materials. A number of different waste forms were evaluated and ranked in the early 1980s; durability (leach resistance) was the highest weighted factor. Borosilicate glass was rated the best waste form available for incorporation of HLW. Four different types of vessels and three different glasses were used to study the possible effect of vessel composition on durability test results from the Production Consistency Test (PCT). The vessels were 45-m 304 stainless steel vessels, 150-m 304 L stainless steel vessels, and 60-m perfluoroalkoxy (PFA) fluoropolymer resin vessels. The three glasses were the Environmental Assessment glass manufactured by Corning Incorporated and supplied by Westinghouse Savannah River company, and West Valley Nuclear Services reference glasses 5 and 6, manufactured and supplied by Catholic University of America. Within experimental error, no differences were found in durability test results using the 3 different glasses in the 304L stainless steel or PFA fluoropolymer resin vessels over the seven-day test period.
Date: March 1, 1995
Creator: Olson, K.M.; Smith, G.L. & Marschman, S.C.
Partner: UNT Libraries Government Documents Department

Characterization of a low-level radioactive waste grout: Sampling and test results

Description: WHC manages and operates the grout treatment facility at Hanford as part of a DOE program to clean up wastes stored at federal nuclear production sites. PNL provides support to the grout disposal program through pilot-scale tests, performance assessments, and formulation verification activities. in 1988 and 1989, over one million gallons of a low-level radioactive liquid waste was processed through the facility to produce a grout waste that was then deposited in an underground vault. The liquid waste was phosphate/sulfate waste (PSW) generated in decontamination of the N Reactor. PNL sampled and tested the grout produced during the second half of the PSW campaign to support quality verification activities prior to grout vault closure. Samples of grout were obtained by inserting nested-tube samplers into the grout slurry in the vault. After the grout had cured, the inner tube of the sampler was removed and the grout samples extracted. Tests for compressive strength, sonic velocity, and leach testing were used to assess grout quality; results were compared to those from pilot-scale test grouts made with a simulated PSW. The grout produced during the second half of the PSW campaign exceeded compressive strength and leachability formulation criteria. The nested tube samplers were effective in collecting samples of grout although their use introduced greater variability into the compressive strength data.
Date: December 1, 1992
Creator: Martin, P.F.C. & Lokken, R.O.
Partner: UNT Libraries Government Documents Department