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Gas generation from radiolytic attack of TRU-contaminated hydrogenous waste

Description: In 1970, the Waste Management and Transportation Division of the Atomic Energy Commission ordered a segregation of transuranic (TRU)-contaminated solid wastes. Those below a contamination level of 10 nCi/g could still be buried; those above had to be stored retrievably for 20 y. The possibility that alpha-radiolysis of hydrogenous materials might produce toxic, corrosive, and flammable gases in retrievably stored waste prompted an investigation of gas identities and generation rates in the labo… more
Date: June 1, 1979
Creator: Zerwekh, A.
Partner: UNT Libraries Government Documents Department
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Gas generation and migration studies involving recently generated /sup 238/Pu-contaminated waste for the TRU Waste Sampling Program

Description: This study is part of the multicontractor TRU Waste Sampling Program. Radiolytically generated gases were vented through a filtering device to determine its effectiveness in maintaining hydrogen concentrations within acceptably safe levels. In the second part of the study measurements were made to determine the ability of these gases, particularly hydrogen, to migrate through a sealed rigid polyethylene drum liner. Void volumes in these drums were found to be generally in excess of 90%. The car… more
Date: July 1, 1986
Creator: Zerwekh, A. & Warren, J.L.
Partner: UNT Libraries Government Documents Department
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TRU waste-sampling program

Description: As part of a TRU waste-sampling program, Los Alamos National Laboratory retrieved and examined 44 drums of /sup 238/Pu- and /sup 239/Pu-contaminated waste. The drums ranged in age from 8 months to 9 years. The majority of drums were tested for pressure, and gas samples withdrawn from the drums were analyzed by a mass spectrometer. Real-time radiography and visual examination were used to determine both void volumes and waste content. Drum walls were measured for deterioration, and selected drum… more
Date: August 1, 1985
Creator: Warren, J.L. & Zerwekh, A.
Partner: UNT Libraries Government Documents Department
open access

The effect of vibration on alpha radiolysis of transuranic (TRU) waste

Description: This paper reports on previously unpublished scoping work related to the potential for vibration to redistribute radionuclides on transuranic (TRU) waste. If this were to happen, the amount of gases generated, including hydrogen, could be increased above the undisturbed levels. This could be an important consideration for transport of TRU wastes either at DOE sites or from them to a future repository, e.g., the Waste Isolation Pilot Plant (WIPP). These preliminary data on drums of real waste se… more
Date: February 1, 1993
Creator: Zerwekh, A.; Kosiewicz, S. & Warren, J.
Partner: UNT Libraries Government Documents Department
open access

The effect of vibration on alpha radiolysis of transuranic (TRU) waste

Description: This paper reports on previously unpublished scoping work related to the potential for vibration to redistribute radionuclides on transuranic (TRU) waste. If this were to happen, the amount of gases generated, including hydrogen, could be increased above the undisturbed levels. This could be an important consideration for transport of TRU wastes either at DOE sites or from them to a future repository, e.g., the Waste Isolation Pilot Plant (WIPP). These preliminary data on drums of real waste se… more
Date: January 1, 1993
Creator: Zerwekh, A.; Kosiewicz, S. (Los Alamos National Lab., NM (United States)) & Warren, J. (NFT, Inc., Lakewood, CO (United States))
Partner: UNT Libraries Government Documents Department
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