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Ligand Rearrangements of Organometallic Complexes inSolution

Description: Many chemical reactions utilize organometallic complexes as catalysts. These complexes find use in reactions as varied as bond activation, polymerization, and isomerization. This thesis outlines the construction of a new ultrafast laser system with an emphasis on the generation of tunable mid-infrared pulses, data collection, and data analysis.
Date: May 8, 2006
Creator: Shanoski, Jennifer E.
Partner: UNT Libraries Government Documents Department

The nature and role of bridged carbonyl intermediates in theultrafast photo-induced rearrangement of Ru3(CO)12.

Description: The photochemistry of the trimetal cluster,Ru(3)(CO)12, was investigated on the ultrafast timescale using UV-vis pump, infrared probe spectroscopy in order to study the transient intermediates formed upon photoexcitation.
Date: September 18, 2005
Creator: Glascoe, Elizabeth A.; Kling, Matthias F.; Shanoski, Jennifer E. & Harris, Charles B.
Partner: UNT Libraries Government Documents Department