Pyrolyzed macrocycle/carbon blends for advanced electrocatalysts
Description:
Pyrolysis of metallated macrocycle compounds involves a vapor phase condensation to form a solid, condensation product that is carbonaceous and electronically conductive. Reaction of these vapors with hot carbon surfaces permits condensation on these surfaces that prepares active electrocatalytic carbons. The role of the metal ion in these processes is not clear, although the chelate clearly acts to carry the metal into the vapor phase. Rapid peroxide decomposition results only with the composi…
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Date:
January 1, 1986
Creator:
Vanderborgh, N.E. & Rieke, P.C.
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Partner:
UNT Libraries Government Documents Department