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in creator/contributor: "Paviet-Hartmann, P. Patricia"  
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Spectroscopic Investigation of the Formation of Radiolysis by-Products by 13/9 Mev Linear Accelerator of Electrons (LAE) in Salt Solutions.

Description: In the near-field chemistry of a salt repository, the radiolytically-induced redox reactions in concentrated saline solution are of particular importance because the radiolysis of saline solutions results in oxidizing chlorine-containing species, which may oxidize actinide species to higher oxidation states. If the brines are irradiated, the solutions containing radiolytic species such as hypochlorite, hypochlorous acid or hydrogen peroxide, their pH and Eh may be altered. The oxidation and com… more
Date: January 1, 2001
Creator: Paviet-Hartmann, P. (Patricia); Dziewinski, J. J. (Jacek J.); Marczak, Stanislaw; Lu, N. (Ningping) & Walthall, M. (Mark)
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Partner: UNT Libraries Government Documents Department
open access

Spectroscopic investigation of the formation of hypochlorite, radiolysis by-product in 5 M NaCI featuring high-energy proton beam line experiments.

Description: Because geological salt formations are considered possible sites for radioactive waste disposal, plausible inundation scenario of salt repository will allow chloride brines to be formed, which consequently will be exposed to radiation from the waste. Key radioelements in Intermediate Level Waste (ILW),H igh Level Waste (HLW) or TRU waste have been found to be plutonium, americium, neptunium, uranium, and technetium. Therefore, the effect of radiolysis on high-saline brine under simulated reposi… more
Date: January 1, 2002
Creator: Hartmann, T. (Thomas); Wetteland, C. J. (Christopher, J.); Marczak, Stanislaw; Walthall, M. (Mark) & Paviet-Hartmann, P. (Patricia)
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Partner: UNT Libraries Government Documents Department
open access

Simulation of radiolysis in the near field of a nuclear repository and the spectrophotometric investigation of the formation of radiolysis by-products by applying high energy beam-like experiments

Description: In the event of inundation of a nuclear waste repository located in a geological salt formation, chloride brines in contact with nuclear waste will be exposed to different kind of radiation depending on waste-form conditions. Ionizing radiations, however, have the ability to significantly affect the groundwater chemistry of the brines through the formation of free radicals, ionic- and molecular species; among them the typical byproducts of a-radiolysis: hypochlorite (OC1-) and hypochlorous acid… more
Date: January 1, 2002
Creator: Hartmann, T. (Thomas); Paviet-Hartmann, P. (Patricia); Wetteland, C. J. (Christopher, J.); Lu, N. (Ningping); Ware, S. D. (Stuart D.) & Sage, S. (Sondra)
Item Type: Refine your search to only Article
Partner: UNT Libraries Government Documents Department
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