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ELECTRICAL PROPERTIES OF ORGANIC SOLIDS. I. KINETICS AND MECHANISMOF CONDUCTIVITY OF METAL-FREE PHTHALOCYANINE

Description: Techniques involving the use of high-intensity short-duration light pulses have been applied t o the study of the kinetics of photoconductivity in films of metal-free phthalocyanine. These experiments, in conjunction with measurements of steady-state photoconductivity, are consistent with the following scheme. The principal route for the formation of charge carriers is via the first excited singlet state, although the lowest triplet state can, t o some extent, contribute to charge - carrier pro… more
Date: July 29, 1959
Creator: Tollin, Gordon; Kearns, David R. & Calvin, Melvin.
Partner: UNT Libraries Government Documents Department
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ELECTRICAL PROPERTIES OF ORGANIC SOLIDS. II: EFFECTS OF ADDEDELECTRON ACCEPTOR ON METAL-FREE PHTHALOCYANINE

Description: The addition of ortho-chloranil to the surface of films of metal-free phthalocyanine has been found (a) to increase the dark conductivity of such films by as much as 10{sup 7}, (b) to increase the steady-state photoconductivity by as much as 10{sup 5}, and (c) to result in the formation of unpaired electrons whose concentration decreases reversibly as a result of illumination. These systems exhibit a light-induced polarization, the phthalocyanine layer becoming more positive with respect t o th… more
Date: July 29, 1959
Creator: Kearns, David R.; Tollin, Gordon & Calvin, Melvin
Partner: UNT Libraries Government Documents Department
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