Early actinide organonitrile compounds and their reactivity.
Description:
The actinide trihalides are an important class of materials . Anhydrous AnX3 compounds have been prepared via high temperature synthetic techniques, but they exis t as polymeric solids, which are insoluble in organic solvents . 1-3 Transuranic complexe s AnI3(THF)X have been prepared by the reaction of metals with CZH4IZ in THF solution s (An = Pu, x = 5; An = Np, x = 4) 4 and can be viewed as a net oxidation of An metal wit h 1 .5 equivalents molecular iodine. A convenient preparation of organ…
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Date:
January 1, 2003
Creator:
Enriquez, A. E. (Alejandro E.); Matonic, J. H. (John H.); Scott, B. L. (Brian L.) & Neu, M. P. (Mary P.)
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