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Determination of ocean/atmosphere carbon dioxide flux within OMP survey area. Final technical progress report, June, 1 1993--May 31, 1995

Description: Determination of the net flux of atmospheric CO{sub 2} with the ocean at the continental margin is one of the three principal goals of the Ocean Margins Program. The work reported here represents the initial phase of that determination, as carried out during two cruises within the OMP survey area in 1993 and 1994. The interannual variability was addressed through the occupation of hydrographic stations of nearly identical location one year apart, while the spatial variability in the air-sea PCO{sub 2} difference (ApCO{sub 2}), representing the driving force for net CO{sub 2} flux, was addressed during a survey of much of the continental shelf between the survey area off North Carolina and Georges Bank. Not addressed by the initial cruises was the seasonal variability of the net CO{sub 2} flux, since both scoping cruises were mounted during the same season of the respective years.
Date: October 17, 1995
Creator: Chipman, D. W. & Takahashi, T.
Partner: UNT Libraries Government Documents Department

Development of gas chromatographic system for dissolved organic carbon analysis in seawater

Description: During the first six months of this two-year grant, we have completed the construction of the analytical portion of a prototype gas chromatograph-based system for the analysis of dissolved organic carbon in seawater. We also have begun testing the procedures to be used to cryogenically concentrate and transfer carbon dioxide from the oxidizing atmosphere of the high-temperature furnace into the reducing hydrogen carrier gas of the gas chromatograph. During the second half of the first year, we will construct the high-temperature catalytic oxidation furnace and test the entire system on laboratory-prepared aqueous solutions of various organic compounds. Also during this period, we will take part in an initial scoping study within the Cape Hatteras field area on board the R/V Gyre. This study will involve both the collection of samples of seawater for organic and inorganic carbon analysis and the measurement of surface-water pCO[sub 2].
Date: December 1, 1992
Creator: Chipman, D.W. & Takahashi, T.
Partner: UNT Libraries Government Documents Department

Development of gas chromatographic system for dissolved organic carbon analysis in seawater. Annual progress report

Description: During the first six months of this two-year grant, we have completed the construction of the analytical portion of a prototype gas chromatograph-based system for the analysis of dissolved organic carbon in seawater. We also have begun testing the procedures to be used to cryogenically concentrate and transfer carbon dioxide from the oxidizing atmosphere of the high-temperature furnace into the reducing hydrogen carrier gas of the gas chromatograph. During the second half of the first year, we will construct the high-temperature catalytic oxidation furnace and test the entire system on laboratory-prepared aqueous solutions of various organic compounds. Also during this period, we will take part in an initial scoping study within the Cape Hatteras field area on board the R/V Gyre. This study will involve both the collection of samples of seawater for organic and inorganic carbon analysis and the measurement of surface-water pCO{sub 2}.
Date: December 1, 1992
Creator: Chipman, D. W. & Takahashi, T.
Partner: UNT Libraries Government Documents Department

Investigation of carbon dioxide in the South Atlantic and northern Weddell Sea areas (WOCE Sections A-12 and A-21) during the METEOR expedition 11/5, January--March 1990

Description: This report summarizes the results of investigation the oceanographic expedition aboard the F/S METEOR in South Atlantic Ocean including the Drake Passage, the northern Weddell Sea and the eastern South Atlantic during the austral summer of January through March 1990. The total CO{sub 2} concentration in about 1300 seawater samples and CO{sub 2} partial pressure (pCO{sub 2}) in about 870 seawater samples collected at 77 stations were determined aboard the ship using a coulometer and equilibrator/gas chromatograph system. The temperature, salinity, dissolved oxygen and nutrient salt data presented in this report were determined by other participants of the expedition including the members of the Oceanographic Data Facility of the Scripps Institution of Oceanography, Argentine Hydrographic Office and German institutions.
Date: December 1, 1991
Creator: Chipman, D.W.; Takahashi, Taro; Breger, D. & Sutherland, S.C.
Partner: UNT Libraries Government Documents Department

Measurements of the total CO[sub 2] concentration and partial pressure of CO[sub 2] in seawater during WOCE expeditions in the South Pacific Ocean

Description: During the first year of the grant, we participated in three WOCE expeditions (a total of 152 days at sea) in the South Pacific Ocean, and the field phase of the proposed investigation has been successfully completed. The total CO[sub 2] concentration and pCO[sub 2] were determined at sea in 4419 water samples collected at 422 stations. On the basis of the shipboard analyses of SIO Reference Solutions for CO, and a comparison with the results of previous expeditions, the overall precision of our total CO[sub 2] determinations is estimated to be about [plus minus]2 uM/kg. The deep water data indicate that there is a CO[sub 2] maximum centered about 2600 meters deep. This appears to represent a southward return flow from the North Pacific. The magnitude and distribution of the CO, maximum observed along the 135.0[degrees]W meridian differ from those observed along the 150.5[degrees]W meridian due to Tuamotu Archipelago, a topographic high which interferes with the southward return flow. The surface water pCO[sub 2] data indicate that the South Pacific sub-tropical gyre water located between about 15[degrees]S and 50[degrees]S is a sink for atmospheric CO[sub 2].
Date: June 29, 1993
Creator: Takahashi, T.; Goddard, J. G.; Chipman, D. W. & Rubin, S. I.
Partner: UNT Libraries Government Documents Department

Investigation of carbon dioxide in the South Atlantic and northern Weddell Sea areas (WOCE Sections A-12 and A-21) during the METEOR expedition 11/5, January--March 1990. Final technical report

Description: This report summarizes the results of investigation the oceanographic expedition aboard the F/S METEOR in South Atlantic Ocean including the Drake Passage, the northern Weddell Sea and the eastern South Atlantic during the austral summer of January through March 1990. The total CO{sub 2} concentration in about 1300 seawater samples and CO{sub 2} partial pressure (pCO{sub 2}) in about 870 seawater samples collected at 77 stations were determined aboard the ship using a coulometer and equilibrator/gas chromatograph system. The temperature, salinity, dissolved oxygen and nutrient salt data presented in this report were determined by other participants of the expedition including the members of the Oceanographic Data Facility of the Scripps Institution of Oceanography, Argentine Hydrographic Office and German institutions.
Date: December 1, 1991
Creator: Chipman, D. W.; Takahashi, Taro; Breger, D. & Sutherland, S. C.
Partner: UNT Libraries Government Documents Department

Measurements of the total CO{sub 2} concentration and partial pressure of CO{sub 2} in seawater during WOCE expeditions in the South Pacific Ocean. Progress report, [January 1, 1993--December 31, 1993]

Description: During the first year of the grant, we participated in three WOCE expeditions (a total of 152 days at sea) in the South Pacific Ocean, and the field phase of the proposed investigation has been successfully completed. The total CO{sub 2} concentration and pCO{sub 2} were determined at sea in 4419 water samples collected at 422 stations. On the basis of the shipboard analyses of SIO Reference Solutions for CO, and a comparison with the results of previous expeditions, the overall precision of our total CO{sub 2} determinations is estimated to be about {plus_minus}2 uM/kg. The deep water data indicate that there is a CO{sub 2} maximum centered about 2600 meters deep. This appears to represent a southward return flow from the North Pacific. The magnitude and distribution of the CO, maximum observed along the 135.0{degrees}W meridian differ from those observed along the 150.5{degrees}W meridian due to Tuamotu Archipelago, a topographic high which interferes with the southward return flow. The surface water pCO{sub 2} data indicate that the South Pacific sub-tropical gyre water located between about 15{degrees}S and 50{degrees}S is a sink for atmospheric CO{sub 2}.
Date: June 29, 1993
Creator: Takahashi, T.; Goddard, J. G.; Chipman, D. W. & Rubin, S. I.
Partner: UNT Libraries Government Documents Department

Measurements of carbon dioxide in the Southern Ocean along the WOCE S-4 section. Annual progress report

Description: During the fist year of this two-year grant, we have completed the data acquisition phase at sea along the WOCE-S4 section located along 67{degree}S between 73{degree}W and 172{degree}E in the Pacific sector of the Southern Ocean. The expedition was carried out aboard the Russian Research Ship ``Akademik IOFFE`` in the period February 14 through April 6, 1992. The total CO{sub 2} concentration and pCO{sub 2} in a total of about 1290 water samples were determined using a coulometer for total CO{sub 2} and an equilibrator/gas chromatograph system for pCO{sub 2}. Surface water samples were analyzed at all the 112 hydrographic stations occupied. Complete or partial profiles were obtained at 58 stations. In addition, a total of 172 determinations were made at sea for 62 bottles of the Standard Reference Solution.
Date: August 1, 1992
Creator: Chipman, D. W.; Rubin, S. I. & Takahashi, T.
Partner: UNT Libraries Government Documents Department

Investigation of carbon dioxide in the central South Pacific Ocean (WOCE Sections P-16C and P-17C) during the TUNES/2 expedition of the R/V Thomas Washington, July--August, 1991. Final technical report

Description: This report summarizes the results of carbon dioxide and associated hydrographic measurements made during the oceanographic expedition, TUNES/2, aboard the R/V Thomas Washington in the central South Pacific Ocean. During the 40 day expedition, the total carbon dioxide concentration in 1000 seawater samples were determined using a coulometer system and the pCO(sub 2) in 940 seawater samples were determined using an equilibrator/gas chromatograph system. The alkalinity values in 900 water samples were computed using these measurements. In addition, 156 coulometric measurements were made for the Certified Reference Solutions (Batch No. 6) and yielded a mean value of 2303.2 +or- 1.5umol/kg. The chemical characteristics for the major water masses have been determined.
Date: December 1, 1993
Creator: Takahashi, T.; Goddard, J. G.; Rubin, S.; Chipman, D. W. & Sutherland, S. C.
Partner: UNT Libraries Government Documents Department

Carbon dioxide, hydrographic, and chemical data obtained during the R/V Akademik Ioffe cruise in the South Pacific Ocean (WOCE Section S4P, February--April 1992)

Description: This data documentation discusses the procedures and methods used to measure total carbon dioxide (TCO{sub 2}) and partial pressure of CO{sub 2} (pCO{sub 2}) in discrete water samples during the Research Vessel (R/V) Akademik Ioffe Expedition in the South Pacific Ocean. Conducted as part of the World Ocean Circulation Experiment (WOCE), the cruise began in Montevideo, Uruguay, on February 14, 1992, and ended in Wellington, New Zealand, on April 6, 1992. WOCE Section S4P, located along {approximately}67{degree}S between 73{degree}W and 172{degree}E, was completed during the 51-day expedition. One hundred and thirteen hydrographic stations were occupied. Hydrographic and chemical measurements made along WOCE Section S4P included pressure, temperature, salinity, and oxygen measured by a conductivity, temperature, and depth sensor; bottle salinity; bottle oxygen, phosphate; nitrate; nitrite; silicate, TCO{sub 2}; and pCO{sub 2} measured at 4 C.
Date: July 1, 1997
Creator: Chipman, D. W.; Takahashi, Taro; Rubin, S.; Sutherland, S. C.; Koshlyakov, M. H. & Kozyr, A.
Partner: UNT Libraries Government Documents Department

Carbon dioxide, hydrographic, and chemical data obtained in the South Pacific Ocean (WOCE Sections P16A/P17A, P17E/P19S, and P19C, R/V Knorr, October 1992--April 1993)

Description: This data documentation discusses the procedures and methods used to measure total carbon dioxide concentration (TCO{sub 2}) and partial pressure of CO{sub 2} (pCO{sub 2}) in discrete water samples collected during three expeditions of the Research Vessel (R/V) Knorr in the South Pacific Ocean. Conducted as part of the World Ocean Circulation Experiment (WOCE), the first cruise (WOCE Section P16A/P17A) began in Papeete, Tahiti, French Polynesia, on October 6, 1992, and returned to Papeete on November 25, 1992. The second cruise (WOCE Section P17E/P19S) began in Papeete on December 4, 1992, and finished in Punta Arenas, Chile, on January 22, 1993. The third expedition (WOCE Section P19C) started in Punta Arenas, on February 22 and finished in Panama City, Panama, on April 13, 1993. During the three expeditions, 422 hydrographic stations were occupied. Hydrographic and chemical measurements made along WOCE Sections P16A/P17A, P17E/P19S, and P19C included pressure, temperature, salinity, and oxygen [measured by conductivity, temperature, and depth (CTD) sensor], as well as discrete measurements of salinity, oxygen, phosphate, nitrate, nitrite, silicate, chlorofluorocarbons (CFC-11, CFC-12), TCO{sub 2}, and pCO{sub 2} measured at 4 and 20 C. In addition, potential temperatures were calculated from the measured variables.
Date: June 1, 1998
Creator: Rubin, S.; Goddard, J.G.; Chipman, D.W.; Takahashi, Taro; Sutherland, S.C.; Reid, J.L. et al.
Partner: UNT Libraries Government Documents Department