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Mixing of process heels, process solutions, and recycle streams: Results of the small-scale radioactive tests

Description: Various recycle streams will be combined with the low-activity waste (LAW) or the high-level waste (HLW) feed solutions during the processing of the Hanford tank wastes by BNFL, Inc. In addition, the LAW and HLW feed solutions will also be mixed with heels present in the processing equipment. This report describes the results of a test conducted by Battelle to assess the effects of mixing specific process streams. Observations were made regarding adverse reactions (mainly precipitation) and effects on the Tc oxidation state (as indicated by K{sub d} measurements with SuperLig{reg_sign} 639). The work was conducted according to test plan BNFL-TP-29953-023, Rev. 0, Small Scale Mixing of Process Heels, Solutions, and Recycle Streams. The test went according to plan, with only minor deviations from the test plan. The deviations from the test plan are discussed in the experimental section.
Date: May 17, 2000
Creator: Lumetta, G. J.; Bramson, J. P.; Farmer, O. T., III; Greenwood, L. R.; Hoopes, F. V.; Mann, M. A. et al.
Partner: UNT Libraries Government Documents Department

C-106 High-Level Waste Solids: Washing/Leaching and Solubility Versus Temperature Studies

Description: This report describes the results of a test conducted by Battelle to assess the effects of inhibited water washing and caustic leaching on the composition of the Hanford tank C-106 high-level waste (HLW) solids. The objective of this work was to determine the composition of the C-106 solids remaining after washing with 0.01M NaOH or leaching with 3M NaOH. Another objective of this test was to determine the solubility of various C-106 components as a function of temperature. The work was conducted according to test plan BNFL-TP-29953-8,Rev. 0, Determination of the Solubility of HLW Sludge Solids. The test went according to plan, with only minor deviations from the test plan. The deviations from the test plan are discussed in the experimental section.
Date: January 26, 2000
Creator: Lumetta, G. J.; Bates, D. J.; Berry, P. K.; Bramson, J. P.; Darnell, L. P.; Farmer, O. T., III et al.
Partner: UNT Libraries Government Documents Department