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Iraq liquid radioactive waste tanks maintenance and monitoring program plan.

Description: The purpose of this report is to develop a project management plan for maintaining and monitoring liquid radioactive waste tanks at Iraq's Al-Tuwaitha Nuclear Research Center. Based on information from several sources, the Al-Tuwaitha site has approximately 30 waste tanks that contain varying amounts of liquid or sludge radioactive waste. All of the tanks have been non-operational for over 20 years and most have limited characterization. The program plan embodied in this document provides guida… more
Date: October 1, 2011
Creator: Dennis, Matthew L.; Cochran, John Russell & Sol Shamsaldin, Emad (Iraq Ministry of Science and Technology)
Partner: UNT Libraries Government Documents Department
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INSTALLATION OF BUBBLERS IN THE SAVANNAH RIVER SITED DEFENSE WASTE PROCESSING FACILITY MELTER

Description: Savannah River Remediation (SRR) LLC assumed the liquid waste contract at the Savannah River Site (SRS) in the summer of 2009. The main contractual agreement was to close 22 High Level Waste (HLW) tanks in eight years. To achieve this aggressive commitment, faster waste processing throughout the SRS liquid waste facilities will be required. Part of the approach to achieve faster waste processing is to increase the canister production rate of the Defense Waste Processing Facility (DWPF) from app… more
Date: December 8, 2010
Creator: Smith, M. & Iverson, D.
Partner: UNT Libraries Government Documents Department
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RESULTS FOR THE FOURTH QUARTER 2010 TANK 50 WAC SLURRY SAMPLE: CHEMICAL AND RADIONUCLIDE CONTAMINANT RESULTS

Description: This report details the chemical and radionuclide contaminant results for the characterization of the 2010 Fourth Quarter sampling of Tank 50 for the Saltstone Waste Acceptance Criteria (WAC). Information from this characterization will be used by Liquid Waste Operations (LWO) to support the transfer of low-level aqueous waste from Tank 50 to the Salt Feed Tank in the Saltstone Facility in Z-Area, where the waste will be immobilized. This information is also used to update the Tank 50 Waste Cha… more
Date: February 22, 2011
Creator: Reigel, M.
Partner: UNT Libraries Government Documents Department
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TANK 21 AND TANK 24 BLEND AND FEED STUDY: BLENDING TIMES, SETTLING TIMES, AND TRANSFERS

Description: The Salt Disposition Integration (SDI) portfolio of projects provides the infrastructure within existing Liquid Waste facilities to support the startup and long term operation of the Salt Waste Processing Facility (SWPF). Within SDI, the Blend and Feed Project will equip existing waste tanks in the Tank Farms to serve as Blend Tanks where salt solutions of up to 1.2 million gallons will be blended in 1.3 million gallon tanks and qualified for use as feedstock for SWPF. In particular, Tanks 21 a… more
Date: May 31, 2012
Creator: Lee, S.; Leishear, R. & Poirier, M.
Partner: UNT Libraries Government Documents Department
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ASSESSMENT OF THE ABILITY OF STANDARD SLURRY PUMPS TO MIX SOLIDS WITH LIQUIDS IN TANK 50H

Description: Tank 50H is the feed tank for the Saltstone Production Facility (SPF). In the summer of 2011, Tank 50H contained two standard slurry pumps and two quad volute slurry pumps. Current requirements for mixing operation is to run three pumps for one hour prior to initiating a feed transfer to SPF. Savannah River Site (SRS) Liquid Waste moved both of the Quad Volute pumps from Tank 50H to Tank 51H to replace pumps in Tank 51H that were failing. In addition, one of the standard pumps in Tank 50H exhib… more
Date: November 11, 2011
Creator: Poirier, M.
Partner: UNT Libraries Government Documents Department
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Numerical Modeling of 90Sr and 137Cs Transport from a Spill in the B-Cell of the 324 Building, Hanford Site 300 Area

Description: To characterize the extent of contamination under the 324 Building, a pit was excavated on the north side of the building in 2010 by Washington Closure Hanford LLC (WCH). Horizontal closed-end steel access pipes were installed under the foundation of the building from this pit and were used for measuring temperatures and exposure rates under the B-Cell. The deployed sensors measured elevated temperatures of up to 61 C (142 F) and exposure rates of up to 8,900 R/hr. WCH suspended deactivation of… more
Date: March 19, 2012
Creator: Rockhold, Mark L.; Bacon, Diana H.; Freedman, Vicky L.; Lindberg, Michael J. & Clayton, Ray E.
Partner: UNT Libraries Government Documents Department
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Hanford Waste Physical and Rheological Properties: Data and Gaps

Description: The Hanford Site in Washington State manages 177 underground storage tanks containing approximately 250,000 m3 of waste generated during past defense reprocessing and waste management operations. These tanks contain a mixture of sludge, saltcake and supernatant liquids. The insoluble sludge fraction of the waste consists of metal oxides and hydroxides and contains the bulk of many radionuclides such as the transuranic components and 90Sr. The saltcake, generated by extensive evaporation of aque… more
Date: August 1, 2011
Creator: Wells, Beric E.; Kurath, Dean E.; Mahoney, Lenna A.; Onishi, Yasuo; Huckaby, James L.; Cooley, Scott K. et al.
Partner: UNT Libraries Government Documents Department
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2010 Annual Wastewater Reuse Report for the Idaho National Laboratory Site's Central Facilities Area Sewage Treatment Plant

Description: This report describes conditions, as required by the state of Idaho Wastewater Reuse Permit (#LA-000141-03), for the wastewater land application site at Idaho National Laboratory Site’s Central Facilities Area Sewage Treatment Plant from November 1, 2009, through October 31, 2010. The report contains the following information: • Site description • Facility and system description • Permit required monitoring data and loading rates • Status of special compliance conditions • Discussion of the fac… more
Date: February 1, 2011
Creator: lewis, Mike
Partner: UNT Libraries Government Documents Department
open access

RADIUM AND THORIUM SORPTION BY MONOSODIUM TITANATE (MST) AND MODIFIED MST (mMST)

Description: A series of tests were planned to examine the removal of Ra and Th by monosodium titanate (MST) and modified monosodium titanate (mMST). Simulated waste solutions were prepared containing Ra and Th, along with Sr, Np, Pu, and U. Following simulant preparation the simulants were filtered through 0.45-m filters. Analysis of the simulants indicated no Th in the filtered solution. This is due to the very low solubility of Th in alkaline solutions. Based on the reported detection limits for {sup 228… more
Date: February 15, 2012
Creator: Taylor-Pashow, K. & Hobbs, D.
Partner: UNT Libraries Government Documents Department
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RESULTS FOR THE SECOND QUARTER 2011 TANK 50 WAC SLURRY SAMPLE: CHEMICAL AND RADIONUCLIDE CONTAMINANT RESULTS

Description: The Saltstone Facility is designed and permitted to immobilize and dispose of low-level radioactive and hazardous liquid waste (salt solution) remaining from the processing of radioactive material at the Savannah River Site. Low-level waste (LLW) streams from the Effluent Treatment Project (ETP), H-Canyon, the DDA (Deliquification, Dissolution, and Adjustment) process, and the decontaminated salt solution product from the Actinide Removal Process/Modular Caustic Side Solvent Extraction (CSSX) U… more
Date: August 25, 2011
Creator: Eibling, R.
Partner: UNT Libraries Government Documents Department
open access

SELECTIVE REMOVAL OF STRONTIUM AND CESIUM FROM SIMULATED WASTE SOLUTION WITH TITANATE ION EXCHANGERS IN A FILTER CARTRIDGE CONFIGURATION

Description: This report describes experimental results for the selective removal of strontium and cesium from simulated waste solutions using monosodium titanate (MST) and crystalline silicotitanate (CST)-laden filter cartridges. Four types of ion exchange cartridge media (CST and MST designed by both 3M and POROX{reg_sign}) were evaluated. In these proof-of-principle tests effective uptake of both Sr-85 and Cs-137 was observed. However, the experiments were not performed long enough to determine the satur… more
Date: May 26, 2011
Creator: Oji, L.; Martin, K. & Hobbs, D.
Partner: UNT Libraries Government Documents Department
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TANK 26F SUPERNATANT AND 2F EVAPORATOR EDUCTOR PUMP SAMPLE CHARACTERIZATION RESULTS

Description: In an effort to understand the reasons for system plugging problems in the SRS 2F evaporator, supernatant samples were retrieved from the evaporator feed tank (Tank 26F) and solids were collected from the evaporator eductor feed pump for characterization. The variable depth supernatant samples were retrieved from Tank 26F in early December of 2010 and samples were provided to SRNL and the F/H Area laboratories for analysis. Inspection and analysis of the samples at SRNL was initiated in early M… more
Date: August 23, 2011
Creator: King, W.; Hay, M. & Coleman, C.
Partner: UNT Libraries Government Documents Department
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INVESTIGATING SUSPENSION OF MST, CST, AND SIMULATED SLUDGE SLURRIES IN A PILOT-SCALE WASTE TANK

Description: The Small Column Ion Exchange (SCIX) process is being developed to remove cesium, strontium, and actinides from Savannah River Site (SRS) Liquid Waste using an existing waste tank (i.e., Tank 41H) to house the process. Savannah River National Laboratory (SRNL) is conducting pilot-scale mixing tests to determine the pump requirements for suspending and resuspending monosodium titanate (MST), crystalline silicotitanate (CST), and simulated sludge. The purpose of this pilot scale testing is for th… more
Date: May 24, 2011
Creator: Poirier, M.; Qureshi, Z.; Restivo, M.; Steeper, T. & Williams, M.
Partner: UNT Libraries Government Documents Department
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PILOT SCALE TESTING OF MONOSODIUM TITANATE MIXING FOR THE SRS SMALL COLUMN ION EXCHANGE PROCESS - 11224

Description: The Small Column Ion Exchange (SCIX) process is being developed to remove cesium, strontium, and select actinides from Savannah River Site (SRS) Liquid Waste using an existing waste tank (i.e., Tank 41H) to house the process. Savannah River National Laboratory (SRNL) is conducting pilot-scale mixing tests to determine the pump requirements for suspending monosodium titanate (MST), crystalline silicotitanate (CST), and simulated sludge. The purpose of this pilot scale testing is to determine the… more
Date: January 25, 2011
Creator: Poirier, M.; Restivo, M.; Williams, M.; Herman, D. & Steeper, T.
Partner: UNT Libraries Government Documents Department
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Deep Vadose Zone-Applied Field Research Initiative Fiscal Year 2011 Annual Report

Description: This annual report describes the background of the Deep Vadose Zone-Applied Field Research Initiative, and some of the programmatic approaches and transformational technologies in groundwater and deep vadose zone remediation developed during fiscal year 2011. The Department of Energy (DOE) Office of Technology Innovation and Development's (OTID) mission is to transform science into viable solutions for environmental cleanup. In 2010, OTID developed the Impact Plan, Science and Technology to Red… more
Date: October 1, 2011
Creator: Wellman, Dawn M.; Johnson, Timothy C.; Smith, Ronald M.; Truex, Michael J. & Matthews, Hope E.
Partner: UNT Libraries Government Documents Department
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Immobilization and Limited Reoxidation of Technetium-99 by Fe(II)-Goethite

Description: This report summarizes the methodology used to test the sequestration of technetium-99 present in both deionized water and simulated Hanford Tank Waste Treatment and Immobilization Plant waste solutions.
Date: September 30, 2010
Creator: Um, Wooyong; Chang, Hyun-shik; Icenhower, Jonathan P.; Qafoku, Nikolla; Smith, Steven C.; Serne, R. Jeffrey et al.
Partner: UNT Libraries Government Documents Department
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Secondary Waste Form Screening Test Results—THOR® Fluidized Bed Steam Reforming Product in a Geopolymer Matrix

Description: Screening tests are being conducted to evaluate waste forms for immobilizing secondary liquid wastes from the Hanford Tank Waste Treatment and Immobilization Plant (WTP). Plans are underway to add a stabilization treatment unit to the Effluent Treatment Facility to provide the needed capacity for treating these wastes from WTP. The current baseline is to use a Cast Stone cementitious waste form to solidify the wastes. Through a literature survey, DuraLith alkali-aluminosilicate geopolymer, flui… more
Date: July 14, 2011
Creator: Pires, Richard P.; Westsik, Joseph H.; Serne, R. Jeffrey; Mattigod, Shas V.; Golovich, Elizabeth C.; Valenta, Michelle M. et al.
Partner: UNT Libraries Government Documents Department
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SELECTIVE REMOVAL OF STRONTIUM AND CESIUM FROM SIMULATED WASTE SOLUTION WITH TITANATE ION-EXCHANGERS IN A FILTER CARTRIDGE CONFIGURATIONS-12092

Description: Experimental results for the selective removal of strontium and cesium from simulated waste solutions with monosodium titanate and crystalline silicotitanate laden filter cartridges are presented. In these proof-of-principle tests, effective uptake of both strontium-85 and cesium-137 were observed using ion-exchangers in this filter cartridge configuration. At low salt simulant conditions, the instantaneous decontamination factor for strontium-85 with monosodium titanate impregnated filter memb… more
Date: January 3, 2012
Creator: Oji, L.; Martin, K. & Hobbs, D.
Partner: UNT Libraries Government Documents Department
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CORROSION TESTING OF CARBON STEEL IN OXALIC ACID CHEMICAL CLEANING SOLUTIONS

Description: Radioactive liquid waste has been stored in underground carbon steel tanks for nearly 60 years at the Savannah River Site. The site is currently in the process of removing the waste from these tanks in order to place it into vitrified, stable state for longer term storage. The last stage in the removal sequence is a chemical cleaning step that breaks up and dissolves metal oxide solids that cannot be easily pumped out of the tank. Oxalic acid has been selected for this purpose because it is an … more
Date: October 14, 2011
Creator: Wiersma, B.; Mickalonis, J.; Subramanian, K. & Ketusky, E.
Partner: UNT Libraries Government Documents Department
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STABLE SR VS 85SR SORPTION FROM SIMULATED WASTE SOLUTIONS BY MST AND MMST

Description: A series of tests were performed to examine the sorption of stable Sr versus the sorption of {sup 85}Sr by monosodium titanate (MST) and modified monosodium titanate (mMST) from simulated waste solutions. Earlier testing indicated a discrepancy between the decontamination factors (DFs) obtained by measuring the stable Sr concentrations by inductively coupled plasma - mass spectroscopy (ICP-MS) and the {sup 85}Sr activities by gamma spectroscopy. One hypothesis to explain this discrepancy was th… more
Date: April 2, 2012
Creator: Taylor-Pashow, K. & Hobbs, D.
Partner: UNT Libraries Government Documents Department
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ASSESSMENT OF THE ABILITY OF STANDARD SLURRY PUMPS TO MIX MISCIBLE AND IMMISCIBLE LIQUIDS IN TANK 50H

Description: Tank 50H is the feed tank for the Saltstone Production Facility (SPF). At present, Tank 50H contains two standard slurry pumps and two Quad Volute slurry pumps. Current requirements and mixing operation is to run three pumps for one hour prior to initiating a feed transfer to SPF. Savannah River Site (SRS) Liquid Waste would like to move one or both of the Quad Volute pumps from Tank 50H to Tank 51H to replace pumps in Tank 51H that are failing. In addition, one of the standard pumps in Tank 50… more
Date: June 15, 2011
Creator: Poirier, M.
Partner: UNT Libraries Government Documents Department
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FULL SCALE TESTING TECHNOLOGY MATURATION OF A THIN FILM EVAPORATOR FOR HIGH-LEVEL LIQUID WASTE MANAGEMENT AT HANFORD - 12125

Description: Simulant testing of a full-scale thin-film evaporator system was conducted in 2011 for technology development at the Hanford tank farms. Test results met objectives of water removal rate, effluent quality, and operational evaluation. Dilute tank waste simulant, representing a typical double-shell tank supernatant liquid layer, was concentrated from a 1.1 specific gravity to approximately 1.5 using a 4.6 m{sup 2} (50 ft{sup 2}) heated transfer area Rototherm{reg_sign} evaporator from Artisan Ind… more
Date: January 26, 2012
Creator: AR, TEDESCHI; JE, CORBETT; RA, WILSON & J, LARKIN
Partner: UNT Libraries Government Documents Department
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ACID EVAPORATION OF ULTIMA GOLD TM AB LIQUID SCINTILLATION COCKTAIL RESIDUE

Description: Prior analyses of samples from the F/H Lab solutions showed the presence of diisopropylnapthalene (DIN), a major component of Ultima Gold{trademark} AB liquid scintillation cocktail (LSC). These solutions are processed through H-Canyon Tank 10.5 and ultimately through the 17.8E evaporator. Similar solutions originated in SRNL streams sent to the same H Canyon tanks. This study examined whether the presence of these organics poses a process-significant hazard for the evaporator. Evaporation and … more
Date: December 21, 2011
Creator: Kyser, E.; Fondeur, F. & Crump, S.
Partner: UNT Libraries Government Documents Department
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VARIABILITY OF KD VALUES IN CEMENTITIOUS MATERIALS AND SEDIMENTS

Description: Measured distribution coefficients (K{sub d} values) for environmental contaminants provide input data for performance assessments (PA) that evaluate physical and chemical phenomena for release of radionuclides from wasteforms, degradation of engineered components and subsequent transport of radionuclides through environmental media. Research efforts at SRNL to study the effects of formulation and curing variability on the physiochemical properties of the saltstone wasteform produced at the Sal… more
Date: February 2, 2012
Creator: Almond, P.; Kaplan, D. & Shine, E.
Partner: UNT Libraries Government Documents Department
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