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Preliminary Hazard Analysis for the Remote-Handled Low-Level Waste Disposal Project

Description: The need for remote handled low level waste (LLW) disposal capability has been identified. A new onsite, remote-handled LLW disposal facility has been identified as the highest ranked alternative for providing continued, uninterrupted remote-handled LLW disposal capability for remote-handled LLW that is generated as part of the nuclear mission of the Idaho National Laboratory and from spent nuclear fuel processing activities at the Naval Reactors Facility. Historically, this type of waste has b… more
Date: October 1, 2010
Creator: Harvego, Lisa & Lehto, Mike
Partner: UNT Libraries Government Documents Department
open access

Safety Design Strategy for the Remote Handled Low-Level Waste Disposal Project

Description: In accordance with the requirements of U.S. Department of Energy (DOE) Order 413.3A, “Program and Project Management for the Acquisition of Capital Assets,” safety must be integrated into the design process for new or major modifications to DOE Hazard Category 1, 2, and 3 nuclear facilities. The intended purpose of this requirement involves the handling of hazardous materials, both radiological and chemical, in a way that provides adequate protection to the public, workers, and the environment.… more
Date: October 1, 2010
Creator: Mecham, Gary
Partner: UNT Libraries Government Documents Department
open access

EVALUATION OF POTENTIAL ELUANTS FOR NON-ACID ELUTION OF CESIUM FROM RESORCINOL-FORMALDEHYDE RESIN

Description: Small-column ion exchange (SCIX) units installed in high-level waste tanks to remove Cs-137 from highly alkaline salt solutions are among the waste treatment plans in the DOE-complex. Spherical Resorcinol-Formaldehyde (sRF) is the ion exchange resin selected for use in the Hanford Waste Treatment and Immobilization Plant (WTP). It is also the primary ion exchange material under consideration for SCIX at the Hanford site. The elution step of the multi-step ion exchange process is typically done … more
Date: December 22, 2010
Creator: Adu-Wusu, K. & Pennebaker, F.
Partner: UNT Libraries Government Documents Department
open access

Low Cost, High Efficiency, High Pressure Hydrogen Storage

Description: A technical and design evaluation was carried out to meet DOE hydrogen fuel targets for 2010. These targets consisted of a system gravimetric capacity of 2.0 kWh/kg, a system volumetric capacity of 1.5 kWh/L and a system cost of $4/kWh. In compressed hydrogen storage systems, the vast majority of the weight and volume is associated with the hydrogen storage tank. In order to meet gravimetric targets for compressed hydrogen tanks, 10,000 psi carbon resin composites were used to provide the high … more
Date: March 31, 2010
Creator: Leavitt, Mark
Partner: UNT Libraries Government Documents Department
open access

TECHNICAL COMPARISON OF CANDIDATE ION EXCHANGE MEDIA FOR SMALL COLUMN ION EXCHANGE (SCIX) APPLICATIONS IN SUPPORT OF SUPPLEMENTAL LAW PRETREATMENT

Description: At-tank supplemental pretreatment including both filtration and small column ion exchange is currently under evaluation to facilitate salt waste retrieval and processing in the Hanford tank farms. Spherical resorcinol formaldehyde (sRF) resin is the baseline ion exchange resin for use in the Waste Treatment and Immobilization Plant (WTP). This document provides background and technical rationale to assist in determining whether spherical resorcinol formaldehyde (sRF) is also the appropriate ion… more
Date: December 28, 2010
Creator: AA, RAMSEY & MR, THORSON
Partner: UNT Libraries Government Documents Department
open access

Analysis of SNL/MSU/DOE fatigue database trends for wind turbine blade materials.

Description: This report presents an analysis of trends in fatigue results from the Montana State University program on the fatigue of composite materials for wind turbine blades for the period 2005-2009. Test data can be found in the SNL/MSU/DOE Fatigue of Composite Materials Database which is updated annually. This is the fifth report in this series, which summarizes progress of the overall program since its inception in 1989. The primary thrust of this program has been research and testing of a broad ran… more
Date: December 1, 2010
Creator: Mandell, John F. (Montana State University, Bozeman, MT); Ashwill, Thomas D.; Wilson, Timothy J. (Montana State University, Bozeman, MT); Sears, Aaron T. (Montana State University, Bozeman, MT); Agastra, Pancasatya (Montana State University, Bozeman, MT); Laird, Daniel L. et al.
Partner: UNT Libraries Government Documents Department
open access

CHARACTERIZATION OF CYCLED SPHERICAL RESORCINOL-FORMALDEHYDE ION EXCHANGE RESIN

Description: This report presents characterization data for two spherical resorcinol-formaldehyde (sRF) resin beds that had processed cesium in non-radioactive and radioactive cycles. All column cycle operations for the resin beds including loading, displacements, elution, regeneration, breakthroughs, and solution analyses are reported in Nash and Duignan, 2009a. That report covered four ion exchange (IX) campaigns using the two {approx}11 mL beds in columns in a lead-lag arrangement. The first two campaign… more
Date: February 23, 2010
Creator: Nash, C. & Duignan, M.
Partner: UNT Libraries Government Documents Department
open access

Next Generation Bipolar Plates for Automotive PEM Fuel Cells

Description: The results of a successful U.S. Department of Energy (DoE) funded two-year $2.9 MM program lead by GrafTech International Inc. (GrafTech) are reported and summarized. The program goal was to develop the next generation of high temperature proton exchange membrane (PEM) fuel cell bipolar plates for use in transportation fuel cell applications operating at temperatures up to 120 °C. The bipolar plate composite developed during the program is based on GrafTech’s GRAFCELL resin impregnated flexib… more
Date: April 15, 2010
Creator: Adrianowycz, Orest; Norley, Julian; Stuart, David J.; Flaherty, David; Wayne, Ryan; Williams, Warren et al.
Partner: UNT Libraries Government Documents Department
open access

RAPID SEPARATION METHOD FOR ACTINIDES IN EMERGENCY AIR FILTER SAMPLES

Description: A new rapid method for the determination of actinides and strontium in air filter samples has been developed at the Savannah River Site Environmental Lab (Aiken, SC, USA) that can be used in emergency response situations. The actinides and strontium in air filter method utilizes a rapid acid digestion method and a streamlined column separation process with stacked TEVA, TRU and Sr Resin cartridges. Vacuum box technology and rapid flow rates are used to reduce analytical time. Alpha emitters are… more
Date: February 3, 2010
Creator: Maxwell, S.; Noyes, G. & Culligan, B.
Partner: UNT Libraries Government Documents Department
open access

Conceptual Safety Design Report for the Remote Handled Low-Level Waste Disposal Facility

Description: A new onsite, remote-handled LLW disposal facility has been identified as the highest ranked alternative for providing continued, uninterrupted remote-handled LLW disposal for remote-handled LLW from the Idaho National Laboratory and for spent nuclear fuel processing activities at the Naval Reactors Facility. Historically, this type of waste has been disposed of at the Radioactive Waste Management Complex. Disposal of remote-handled LLW in concrete disposal vaults at the Radioactive Waste Manag… more
Date: February 1, 2010
Creator: Christensen, Boyd D.
Partner: UNT Libraries Government Documents Department
open access

RESORCINOL-FORMALDEHYDE ION EXCHANGE RESIN CHEMISTRY FOR HIGH LEVEL WASTE TREATMENT

Description: A principal goal at the Savannah River Site is to safely dispose of the large volume of liquid nuclear waste held in many storage tanks. In-tank ion exchange technology is being considered for cesium removal using a polymer resin made of resorcinol formaldehyde that has been engineered into microspheres. The waste under study is generally lower in potassium and organic components than Hanford waste; therefore, the resin performance was evaluated with actual dissolved salt waste. The ion exchang… more
Date: January 14, 2010
Creator: Nash, C. & Duignan, M.
Partner: UNT Libraries Government Documents Department
open access

Micro Ion Source Program NA22 Plutonium Detection Portfolio Final Report

Description: The purpose of the micro ion source program was to enhance the performance of thermal ionization mass spectrometry (TIMS) for various actinides and fission products. The proposal hypothesized that when ions are created at the ion optic center of the mass spectrometer, ion transmission is significantly increased and the resulting ion beam is more sharply focused. Computer modeling demonstrated this logic. In order to prove this hypothesis it was first necessary to understand the chemistry and ph… more
Date: September 1, 2010
Creator: Delmore, James E.
Partner: UNT Libraries Government Documents Department
open access

Uranium Adsorption on Ion-Exchange Resins - Batch Testing

Description: The uranium adsorption performance of five resins (Dowex 1, Dowex 21K 16-30 [fresh], Dowex 21K 16-30 [regenerated], Purofine PFA600/4740, and ResinTech SIR-1200) were tested using unspiked, nitrate-spiked, and nitrate-spiked/pH adjusted source water from well 299-W19-36. These batch tests were conducted in support of a resin selection process in which the best resin to use for uranium treatment in the 200-West Area groundwater pump-and-treat system will be identified. The results from these tes… more
Date: December 1, 2010
Creator: Mattigod, Shas V.; Golovich, Elizabeth C.; Wellman, Dawn M.; Cordova, Elsa A. & Smith, Ronald M.
Partner: UNT Libraries Government Documents Department
open access

Tc-99 Ion Exchange Resin Testing

Description: Pacific Northwest National Laboratory was contracted by CHPRC to evaluate the release of 99Tc from spent resin used to treat water from well 299-W15-765 and stored for several years. The key questions to be answered are: 1) does 99Tc readily release from the spent ion exchange resin after being in storage for several years; 2) if hot water stripping is used to remove the co-contaminant carbon tetrachloride, will 99Tc that has been sequestered by the resin be released; and 3) can spent resin be … more
Date: August 1, 2010
Creator: Valenta, Michelle M.; Parker, Kent E. & Pierce, Eric M.
Partner: UNT Libraries Government Documents Department
open access

Natural Fiber Composites: A Review

Description: The need for renewable fiber reinforced composites has never been as prevalent as it currently is. Natural fibers offer both cost savings and a reduction in density when compared to glass fibers. Though the strength of natural fibers is not as great as glass, the specific properties are comparable. Currently natural fiber composites have two issues that need to be addressed: resin compatibility and water absorption. The following preliminary research has investigated the use of Kenaf, Hibiscus … more
Date: March 7, 2010
Creator: Westman, Matthew P.; Fifield, Leonard S.; Simmons, Kevin L.; Laddha, Sachin & Kafentzis, Tyler A.
Partner: UNT Libraries Government Documents Department
open access

REMOVAL OF CESIUM FROM SAVANNAH RIVER SITE WASTE WITH SPHERICAL RESORCINOL FORMALDEHYDE ION EXCHANGE RESIN EXPERIMENTAL TESTS

Description: A principal goal at the Savannah River Site (SRS) is to safely dispose of the large volume of liquid nuclear waste held in many storage tanks. In-tank ion exchange (IX) columns are being considered for cesium removal. The spherical form of resorcinol formaldehyde ion exchange resin (sRF) is being evaluated for decontamination of dissolved saltcake waste at SRS, which is generally lower in potassium and organic components than Hanford waste. The sRF performance with SRS waste was evaluated in tw… more
Date: March 31, 2010
Creator: Duignan, M. & Nash, C.
Partner: UNT Libraries Government Documents Department
open access

Determination of 237NP and Pu Isotopes in Large Soil Samples by Inductively Coupled Plasma Mass Spectrometry

Description: A new method for the determination of {sup 237}Np and Pu isotopes in large soil samples has been developed that provides enhanced uranium removal to facilitate assay by inductively coupled plasma mass spectrometry (ICP-MS). This method allows rapid preconcentration and separation of plutonium and neptunium in large soil samples for the measurement of {sup 237}Np and Pu isotopes by ICP-MS. {sup 238}U can interfere with {sup 239}Pu measurement by ICP-MS as {sup 238}UH{sup +} mass overlap and {sup… more
Date: July 26, 2010
Creator: Maxwell, S.
Partner: UNT Libraries Government Documents Department
open access

Decomposition of Rare Earth Loaded Resin Particles

Description: The Fuel Cycle R and D (FCR and D) program within the Department of Energy Office of Nuclear Energy (DOE-NE) is evaluating nuclear fuel cycle options, including once-through, modified open, and fully closed cycles. Each of these scenarios may utilize quite different fuel management schemes and variation in fuel types may include high thermal conductivity UO{sub 2}, thoria-based, TRISO, metal, advanced ceramic (nitride, carbide, composite, etc.), and minor actinide (MA) bearing fuels and targets… more
Date: September 1, 2010
Creator: Voit, Stewart L & Rawn, Claudia J
Partner: UNT Libraries Government Documents Department
open access

Technology Selections for Cylindrical Compact Fabrication

Description: A variety of process approaches are available and have been used historically for manufacture of cylindrical fuel compacts. The jet milling, fluid bed overcoating, and hot press compacting approach being adopted in the U.S. AGR Fuel Development Program for scale-up of the compacting process involves significant paradigm shifts from historical approaches. New methods are being pursued because of distinct advantages in simplicity, yield, and elimination of process mixed waste. Recent advances in … more
Date: October 1, 2010
Creator: Phillips, Jeffrey A.
Partner: UNT Libraries Government Documents Department
open access

Conceptual Safety Design Report for the Remote Handled Low-Level Waste Disposal Facility

Description: A new onsite, remote-handled LLW disposal facility has been identified as the highest ranked alternative for providing continued, uninterrupted remote-handled LLW disposal for remote-handled LLW from the Idaho National Laboratory and for spent nuclear fuel processing activities at the Naval Reactors Facility. Historically, this type of waste has been disposed of at the Radioactive Waste Management Complex. Disposal of remote-handled LLW in concrete disposal vaults at the Radioactive Waste Manag… more
Date: May 1, 2010
Creator: Christensen, Boyd D.
Partner: UNT Libraries Government Documents Department
open access

POTENTIAL IMPACT OF TANK F FLUSH SOLUTION ON H-CANYON EVAPORATOR OPERATION

Description: Previous chemical analysis of a sample from the liquid heel found in Tank F of the High Activity Drain (HAD) system in F/H laboratory revealed the presence of n-paraffin, tributyl phosphate (TBP), Modifier from the Modular Caustic-Side Solvent Extraction Unit (MCU) process and a vinyl ester resin that is very similar to the protective lining on Tank F. Subsequent analyses detected the presence of a small amount of diisopropylnaphthalene (DIN) (major component of Ultima Gold{trademark} AB liquid… more
Date: September 13, 2010
Creator: Kyser, E.; Fondeur, F. & Fink, S.
Partner: UNT Libraries Government Documents Department
open access

PRELIMINARY REPORT ON EVALUATION OF POTENTIAL ELUANTS FOR NON-ACID ELUTION OF CESIUM FROM RESORCINOL-FORMALDEHYDE RESIN

Description: Small-column ion exchange (SCIX) units installed in high-level waste tanks to remove Cs-137 from highly alkaline salt solutions are among the waste treatment plans in the DOE-complex. Spherical Resorcinol-Formaldehyde (sRF) is the ion exchange resin selected for use in the Hanford Waste Treatment and Immobilization Plant (WTP). It is also the primary ion exchange material under consideration for SCIX at the Hanford site. The elution step of the multi-step ion exchange process is typically done … more
Date: September 1, 2010
Creator: Adu-Wusu, K. & Pennebaker, F.
Partner: UNT Libraries Government Documents Department
open access

An Engineering Evaluation of Spherical Resorcinol Formaldehyde Resin

Description: A small column ion exchange (SCIX) system has been proposed for removal of cesium from caustic, supernatant, and dissolved salt solutions stored or generated from high-level tank wastes at the US Department of Energy (DOE) Hanford Site and Savannah River Sites. In both instances, deployment of SCIX systems, either in-tank or near-tank, is a means of expediting waste pretreatment and dispositioning with minimal or no new infrastructure requirements. Conceptually, the treatment approach can utili… more
Date: September 1, 2010
Creator: Birdwell Jr, Joseph F; Lee, Denise L; Taylor, Paul Allen; Collins, Robert T & Hunt, Rodney Dale
Partner: UNT Libraries Government Documents Department
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