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Clean energy from municipal solid waste. Technical progress report number 3

Description: Development of the computer models for slurry carbonization have begun and were based upon the collected data (mass balances, yield, temperatures, and pressures) from the previous pilot plant campaigns. All computer models are being developed with Aspen`s SpeedUp{trademark} software. The primary flow sheet with major alternatives has been developed and the majority of equipment descriptions and models, cost algorithms, and baseline parameters have been input to SpeedUp. The remaining modeling p… more
Date: January 5, 1996
Creator: Klosky, M.
Partner: UNT Libraries Government Documents Department
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Experimental Investigation of the Classical Rayleigh-Taylor Instability

Description: The evolution of the Rayleigh-Taylor (RT) instability in a compressible medium has been investigated at an accelerating embedded interface and at the ablation front in a series of experiments on the Nova laser. The x-ray drive generated in a gold hohlraum ablatively accelerated a planar target consisting of a doped plastic pusher backed by a higher density titanium payload with perturbations placed at the plastic-Ti interface. The targets were diagnosed by face-on and side-on radiography. In pr… more
Date: May 21, 1996
Creator: Budil, K. S.; Remington, B. A.; Peyser, T. A.; Mikaelian, K. O.; Rubenchik, A. M.; Berning, M. et al.
Partner: UNT Libraries Government Documents Department
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Direct liquefaction Proof-of-Concept Program, Hydrocarbon Technologies, Inc., Lawrenceville, New Jersey. Final topical report, Bench Run 02 (227-91)

Description: This report presents the results of Bench Run PB-02, conducted under the DOE Proof of Concept - Bench Option Program in direct coal liquefaction at Hydrocarbon Technologies, Inc. in Lawrenceville, New Jersey. Bench Run PB-02 was the second of the nine runs planned in the POC Bench Option Contract between the U.S. DOE and Hydrocarbon Technologies, Inc. The primary goal of this bench run was to evaluate the hybrid catalyst system, consisting of a dispersed slurry catalyst in one of the hydroconve… more
Date: September 1, 1996
Creator: Comolli, A. G.; Pradhan, V. R.; Lee, T. L. K.; Karolkiewicz, W. F. & Popper, G.
Partner: UNT Libraries Government Documents Department
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Direct liquefaction proof-of-concept program: POC bench option run 01 (227-90). Final report

Description: This report presents the results of bench-scale work, Bench Run PB-01, conducted under the DOE Proof of Concept-Bench Option Program in direct coal liquefaction at Hydrocarbon Technologies, Inc. in Lawrenceville, New Jersey. The Bench Run PB-01 was the first of nine runs planned under the POC Bench Option Contract between the US DOE and Hydrocarbon Technologies, Inc. The primary goal of this bench run was to evaluate the most successful of the process improvements concepts, evolving out of the … more
Date: May 1, 1996
Creator: Comolli, A. G.; Pradhan, V. R.; Lee, T. L. K.; Karolkiewicz, W. F. & Popper, G.
Partner: UNT Libraries Government Documents Department
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Extraction and analysis of pollutant organics from contaminated solids using off-line supercritical fluid extraction (SFE) and on-line SFE-infrared spectroscopy. Task 2. Semiannual report, November 1995--March 1996

Description: This document describes activities in the following tasks associated with a project on environmental management technology decontamination and commercialization: A commercialized version of a field-portable instrument for performing supercritical fluid extraction (SFE) with on-line Fourier transform infrared (FT-IR) detection;pyrolysis of plastic wastes associated with mixtures of radioactive wastes;management and reporting activities; centrifugal membrane filtration with application to tank wa… more
Date: April 1, 1996
Creator: Hawthorne, S.B.
Partner: UNT Libraries Government Documents Department
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Positron beam lifetime spectroscopy of atomic scale defect distributions in bulk and microscopic volumes

Description: We are developing a defect analysis capability based on two positron beam lifetime spectrometers: the first is based on a 3 MeV electrostatic accelerator and the second on our high current linac beam. The high energy beam lifetime spectrometer is operational and positron lifetime analysis is performed with a 3 MeV positron beam on thick samples. It is being used for bulk sample analysis and analysis of samples encapsulated in controlled environments for {ital in}{ital situ} measurements. A seco… more
Date: May 1, 1996
Creator: Howell, R. H.; Cowan, T. E.; Hartley, J.; Sterne, P. & Brown, B.
Partner: UNT Libraries Government Documents Department
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Catalytic multi-stage liquefaction (CMSL)

Description: Reported herein are the details and the results of laboratory and bench scale experiments that were conducted at Hydrocarbon Technologies, Inc. under DOE Contract No. DE-AC22-93PC92147 during the period of October 1, 1992, to December 31, 1995. The program results described herein build on the previous technology base and investigating additional methods to improve the economics of producing transportation fuels from coal. This included purely physical parameters, coal treatment and variation i… more
Date: November 1, 1996
Creator: Comolli, A. G.; Ganguli, P.; Karolkiewicz, W. F.; Lee, T. L. K.; Pradhan, V. R.; Popper, G. et al.
Partner: UNT Libraries Government Documents Department
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Direct liquefaction proof-of-concept program. Topical report

Description: This report presents the results of work conducted under the DOE Proof-of-Concept Program in direct coal liquefaction at Hydrocarbon Technologies, Inc. in Lawrenceville, New Jersey, from February 1994 through April 1995. The work includes modifications to HRI`s existing 3 ton per day Process Development Unit (PDU) and completion of the second PDU run (POC Run 2) under the Program. The 45-day POC Run 2 demonstrated scale up of the Catalytic Two-Stage Liquefaction (CTSL Process) for a subbitumino… more
Date: December 1, 1996
Creator: Comolli, A. G.; Lee, L. K. & Pradhan, V. R.
Partner: UNT Libraries Government Documents Department
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Changes to the LANL gas-driven two-stage gun: Magnetic gauge instrumentation, etc.

Description: Our gas-driven two-stage gun was designed and built to do initiation studies on insensitive high explosives as well as other equation of state experiments on inert materials. Our preferred method of measuring initiation phenomena involves the use of magnetic particle velocity gauges. In order to accommodate this type of gauging in our two-stage gun, projectile velocity was sacrificed in favor of a larger experimental target area (obtained by using a 50 mm diameter launch tube). We have used mag… more
Date: December 31, 1996
Creator: Sheffield, S. A.; Gustavsen, R. L.; Martinez, A. R. & Alcon, R. R.
Partner: UNT Libraries Government Documents Department
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The degradation of TPX components by oxygen, elevated temperature, and ionizing radiation

Description: TPX is PMP or poly(4-methyl-1-pentene). It has several commercially important characteristics such as high optical transparency, high crystalline melting point, etc., leading to numerous applications including infrared windows, lenses, membranes, food packaging. The life components fabricated from this material may be limited by thermal oxidative and radiation-induced degradation. A preliminary review of the scientific literature was conducted to obtain relevant information on the effects of ox… more
Date: May 31, 1996
Creator: Farmer, J.C.
Partner: UNT Libraries Government Documents Department
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Catalytic multi-stage liquefaction (CMSL)

Description: Under contract with the U.S. Department of Energy, Hydrocarbon Technologies, Inc. has conducted a series of eleven catalytic, multi-stage, liquefaction (CMSL) bench scale runs between February, 1991, and September, 1995. The purpose of these runs was to investigate novel approaches to liquefaction relating to feedstocks, hydrogen source, improved catalysts as well as processing variables, all of which are designed to lower the cost of producing coal-derived liquid products. This report summariz… more
Date: November 1, 1996
Creator: Comolli, A. G.; Ganguli, P.; Karolkiewicz, W. F.; Lee, T. L. K.; Pradhan, V. R.; Popper, G. A. et al.
Partner: UNT Libraries Government Documents Department
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Hypervelocity microparticle characterization

Description: To protect spacecraft from orbital debris requires a basic understanding of the processes involved in hypervelocity impacts and characterization of detectors to measure the space environment. Both require a source of well characterized hypervelocity particles. Electrostatic acceleration of charged microspheres provides such a source. Techniques refined at the Los Alamos National Laboratory provided information on hypervelocity impacts of particles of known mass and velocity ranging from 20-1000… more
Date: November 1, 1996
Creator: Idzorek, George C.
Partner: UNT Libraries Government Documents Department
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An inverse problem by boundary element method

Description: Boundary Element Methods (BEM) have been established as useful and powerful tools in a wide range of engineering applications, e.g. Brebbia et al. In this paper, we report a particular three dimensional implementation of a direct boundary integral equation (BIE) formulation and its application to numerical simulations of practical polymer processing operations. In particular, we will focus on the application of the present boundary element technology to simulate an inverse problem in plastics p… more
Date: February 1, 1996
Creator: Tran-Cong, T.; Nguyen-Thien, T. & Graham, A. L.
Partner: UNT Libraries Government Documents Department
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Compatibility of packaging components with simulant mixed waste

Description: The purpose of hazardous and radioactive materials packaging is to enable these materials to be transported without posing a threat to the health or property of the general public. To achieve this aim, regulations in the US have been written establishing general design requirements for such packagings. While no regulations have been written specifically for mixed waste packaging, regulations for the constituents of mixed wastes, i.e., hazardous and radioactive substances, have been codified by … more
Date: April 1, 1996
Creator: Nigrey, P. J. & Dickens, T. G.
Partner: UNT Libraries Government Documents Department
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Utilization of low NO{sub x} coal combustion by-products. Quarterly report, October--December 1995

Description: Accomplishments to date are described for the following tasks. Task 2, Laboratory characterization, involved sample collection, material characterization, and laboratory testing of ash processing operations. The paper describes settling tests, leaf filter tests, centrifuge tests, and hydrocyclone tests. No pilot plant tests (Task 3) were performed this quarter. Task 4, Product testing, involves concrete testing (effect of power plant ashes on concrete properties), concrete block/brick, plastic … more
Date: January 1, 1996
Partner: UNT Libraries Government Documents Department
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The detection and measurement of the electrical mobility size distributions associated with radon decay products

Description: The potential risk of lung cancer has evoked interest in the properties of radon decay products. There are two forms of this progeny: either attached to ambient aerosols, or still in the status of ions/molecules/small clusters. This ``unattached`` activity would give a higher dose per unit of airborne activity than the ``attached`` progeny that are rather poorly deposited. In this thesis, a system for determining unattached radon decay products electrical mobility size distribution by measuring… more
Date: April 1, 1996
Creator: Fei, Lin
Partner: UNT Libraries Government Documents Department
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Adhesive bonding via exposure to microwave radition and resulting mechanical evaluation

Description: Adhesive bonding/joining through microwave radiation curing has been evaluated as an alternative processing technology. This technique significantly reduces the required curing time for the adhesive while maintaining equivalent physical characteristics as the adhesive material is polymerized (crosslinked). This results in an improvement in the economics of the process. Testing of samples cured via microwave radiation for evaluation of mechanical properties indicated that the obtained values fro… more
Date: April 1, 1996
Creator: Paulauskas, F. L.; Warren, C. D. & Meek, T. T.
Partner: UNT Libraries Government Documents Department
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Recovery and separation of high-value plastics from discarded household appliances

Description: Argonne National Laboratory is conducting research to develop a cost- effective and environmentally acceptable process for the separation of high-value plastics from discarded household appliances. The process under development has separated individual high purity (greater than 99.5%) acrylonitrile-butadiene-styrene (ABS) and high- impact polystyrene (HIPS) from commingled plastics generated by appliance-shredding and metal-recovery operations. The process consists of size-reduction steps for t… more
Date: March 1996
Creator: Karvelas, D. E.; Jody, B. J.; Poykala, J. A., Jr.; Daniels, E. J. & Arman, B.
Partner: UNT Libraries Government Documents Department
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Hydrogen production from municipal solid waste

Description: We have modified a Municipal Solid Waste (MSW) hydrothermal pretreatment pilot plant for batch operation and blowdown of the treated batch to low pressure. We have also assembled a slurry shearing pilot plant for particle size reduction. Waste paper and a mixture of waste paper/polyethylene plastic have been run in the pilot plant with a treatment temperature of 275{degrees}C. The pilot-plant products have been used for laboratory studies at LLNL. The hydrothermal/shearing pilot plants have pro… more
Date: June 28, 1996
Creator: Wallman, P. H.; Richardson, J. H. & Thorsness, C. B.
Partner: UNT Libraries Government Documents Department
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Utilization of Low NOx Coal Combustion by-Products. Quarterly Report, January 1 - March 31, 1996

Description: Work performed during the period January 1 through March 31, 1996 is described. Tasks included material characterization of ash; pilot plant testing; product testing for concrete, concrete block/brick, plastic fillers, activated carbon and metal matrix composites; and a market analysis for plastic fillers, activated carbon and carbon black, and market research and development.
Date: December 31, 1996
Partner: UNT Libraries Government Documents Department
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Utilization of low NOx coal combustion by-products. Quarterly report, April 1 - June 30, 1996

Description: This project is studying a beneficiation process to make power plant fly ash a more useful by-product. Accomplishments for this reporting period are presented for the following tasks: laboratory characterization which includes sample collection, material characterization and laboratory testing of ash processing operations; product testing including concrete, concrete block/brick, plastic fillers and activated carbon; and market and economic analysis. Appendix A contains data on fly ash material… more
Date: December 31, 1996
Partner: UNT Libraries Government Documents Department
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Determination of unconverted HDPE in coal/plastics co-liquefaction stream samples

Description: In several coal/plastics liquefaction runs performed by Hydrocarbon Technologies, Inc. (HTI), a substantial amount of incompletely converted high-density polyethylene (HDPE) was present in ash-free recycle resid streams when either the ROSE-SR unit was used in Run POC-2, or the pressure filter unit was used in Runs CMSL-8 and CMSL-9. This indicates that the HDPE is less reactive than coal at the liquefaction conditions used. In these ash-free streams, there is no solid organic or inorganic mate… more
Date: December 31, 1996
Creator: Robbins, G.A.; Winschel, R.A. & Burke, F.P.
Partner: UNT Libraries Government Documents Department
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Finite element studies of the influence of pile-up on the analysis of nanoindentation data

Description: Methods currently used for analyzing nanoindentation load-displacement data give good predictions of the contact area in the case of hard materials, but can underestimate the contact area by as much as 40% for soft materials which do not work harden. This underestimation results from the pile-up which forms around the hardness impression and leads to potentially significant errors in the measurement of hardness and elastic modulus. Finite element simulations of conical indentation for a wide ra… more
Date: May 1, 1996
Creator: Bolshakov, A.; Pharr, G. M. & Oliver, W. C.
Partner: UNT Libraries Government Documents Department
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ABS plastic RPCs

Description: After investigating a number of materials, we discovered that an ABS plastic doped with a conducting polymer performs well as the resistive electrode in a narrow gap RPC (resistive plate chamber). Operating in the streamer mode, we find efficiencies of 90-96% with low noise and low strip multiplicities. We have also studied a variety of operating gases and found that a mixture containing SF{sub 6}, a non-ozone depleting gas, argon and isobutane gives good streamer mode performance, even with is… more
Date: February 1, 1996
Creator: Ables, E.; Bionta, R.; Olson, H.; Ott, L.; Parker, E.; Wright, D. et al.
Partner: UNT Libraries Government Documents Department
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