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Heteroatom speciation in coal liquefaction via FTIR coupled with liquid chromatography. Quarterly progress report, October 1-December 31, 1983

Description: The objectives of the research are (1) evaluate the potential of FT-IR for qualitative functional group detection in chromatographic fractions of highly polar materials, (2) develop separation techniques with the aid of FT-IR detection for concentration of oxygen, nitrogen and sulfur functionalities in synfuels, (3) describe and quantify the various heteroatom functionalities in selected solvent refined coal fractions, (4) place speciation techniques on-line with chromatographic separations, (5… more
Date: May 1, 1984
Creator: Taylor, L.T.
Partner: UNT Libraries Government Documents Department
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Heavy recycle solvent studies in two-stage coal liquefaction. Final technical report, September 1, 1982-December 30, 1983

Description: The objective of this program has been to study the chemistry of the components with high boiling points in a direct coal liquefaction recycle solvent and to identify those components which lead to higher overall yields and improved product stability in the initial coal dissolution step of direct coal liquefaction processes. The major conclusions are: -454 C recycle solvent is primarily aromatic hydrocarbons (73%) and contains almost no asphaltenes; +454 C recycle solvent is primarily asphalten… more
Date: January 10, 1984
Creator: Longanbach, J. R.
Partner: UNT Libraries Government Documents Department
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Measurement of the intensity of the cosmic background radiation at 3. 0 cm

Description: The intensity of the cosmic background radiation (CBR) has been measured at a wavelength of 3.0 cm as part of a program to measure th Rayleigh-Jeans spectrum of the CBR at five wavelengths between 0.33 cm and 12 cm. The instrument used is a dual-antenna Dicke-switched radiometer with a double-sideband noise temperature of 490 K and a sensitivity of 46 mK/Hz/sup 1/2/. The entire radiometer is mounted on bearings. The atmospheric emission was measured by rotating the radiometer, and thus directin… more
Date: January 1, 1984
Creator: Friedman, S.D.
Partner: UNT Libraries Government Documents Department
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Simulation of winds as seen by a rotating vertical axis wind turbine blade

Description: The objective of this report is to provide turbulent wind analyses relevant to the design and testing of Vertical Axis Wind Turbines (VAWT). A technique was developed for utilizing high-speed turbulence wind data from a line of seven anemometers at a single level to simulate the wind seen by a rotating VAWT blade. Twelve data cases, representing a range of wind speeds and stability classes, were selected from the large volume of data available from the Clayton, New Mexico, Vertical Plane Array … more
Date: February 1, 1984
Creator: George, R.L.
Partner: UNT Libraries Government Documents Department
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Observation of lines above 2000 A in OVIII and CVI in the PLT tokamak due to charge-exchange processes: diagnostic applications

Description: Hydrogen-like oxygen and carbon lines from high-n transitions with wavelengths above 2000 A were observed as a result of charge-exchange processes during neutral beam injection of hydrogen atoms into the Princeton Large Torus (PLT) tokamak. The lines are: OVIII 2976 A (8 ..-->.. 7 transitions), CVI 3434 A (7 ..-->.. 6), and CVI 5291 A (8 ..-->.. 7). Application of these lines for Doppler ion temperature measurements and initial obeservations of neutral beam vertical and horizontal distributions… more
Date: February 1984
Creator: Suckewer, S.; Skinner, C. H.; Stratton, B.; Bell, R.; Cavallo, A.; Hosea, J. et al.
Partner: UNT Libraries Government Documents Department
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Fusion reaction spectra produced by anisotropic fast ions in the PLT tokamak

Description: For beam-target fusion reactions, collimated measurements of the energy spectrum of one of the reaction products can provide information on the degree of anisotropy of the reacting beam ions. Measurements of the spectrum of 15 MeV protons produced by reactions between energetic /sup 3/He ions and relatively cold deuterons during fast wave minority heating in the PLT tokamak indicate that the velocity distribution of fast /sup 3/He ions is peaked perpendicular to the tokamak magnetic field.
Date: February 1, 1984
Creator: Heidbrink, W. W.
Partner: UNT Libraries Government Documents Department
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HOTSPUR progress report: neutron source spectrum characterization, and /sup 6/Li(n,x. cap alpha. ) and /sup 7/Li(n,x. cap alpha. ) cross section determination

Description: As a prerequisite to high accuracy measurements involving the bulk configuration of /sup 6/LiD we must have a good grasp of the details of the RTNS-I neutron source energy spectrum. Experiments to this end involving neutron yield vs deuteron energy, ratios of foil activation of selected elements, and pulse height distributions of a Si surface barrier detector are described. With this knowledge, the /sup 4/He-production cross sections for /sup 6/Li and /sup 7/Li are found experimentally to be 0.… more
Date: April 2, 1984
Creator: Goldberg, E. & Haight, R.
Partner: UNT Libraries Government Documents Department
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Recycle slurry oil characterization. Technical report, October 1, 1982-March 31, 1983

Description: This report includes the results of analysis of the integrated two-stage liquefaction (ITSL) process development unit (PDU) runs using Illinois 6, Burning Star coal from March 1982, to February 1983. One hundred fixty-six samples were analyzed. In addition, several sets of experiments designed to answer specific questions related to ITSL were performed, samples from H-Coal Pilot Plant Run 9 were analyzed and analytical methods were developed. Conclusions derived from this work are presented. 11… more
Date: February 1, 1984
Creator: Winschel, R.A. & Burke, F.P.
Partner: UNT Libraries Government Documents Department
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Chemical aspects of /sup 237/ Np Moessbauer spectroscopy

Description: The /sup 237/Np Moessbauer effect has been especially useful in studies of neptunium chemistry, by virtue of its excellent resolution and straightforward experimental techniques. Neptunium can have valences from +3 to +7, and a broad range of compounds can be prepared that are analogous to those of other actinide elements. Studies on neptunium compounds, for example, have a ready application to the analogous compounds of uranium and plutonium. The emphasis in this paper will be on the applicati… more
Date: January 1, 1984
Creator: Karraker, D G
Partner: UNT Libraries Government Documents Department
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Neutron spectrum measurements using proton recoil proportional counters: results of measurements of leakage spectra for the Little Boy assembly

Description: Measurements of degraded fission-neutron spectra using recoil proportional counters are done routinely for studies involving fast reactor mockups. The same techniques are applicable to measurements of neutron spectra required for personnel dosimetry in fast neutron environments. A brief discussion of current applications of these methods together with the results of a measurement made on the LITTLE BOY assembly at Los Alamos are here described.
Date: January 1, 1984
Creator: Bennett, E.F. & Yule, T.J.
Partner: UNT Libraries Government Documents Department
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Pion production in heavy ion reactions near absolute thresholds

Description: Pion production in heavy ion collisions at energies below the free nucleon-nucleon threshold, i.e., at energies, where the pion mass exceeds the kinetic energy of a projectile nucleon in the zero momentum frame, has been discussed for a long time in terms of probing the intrinsic Fermi motion in the projectile and target nuclei. However, as the beam energy is lowered, this process gets more and more unlikely and below a certain energy it should not be observed anymore. In a sharp cut-off Fermi … more
Date: January 1, 1984
Creator: Stachel, J.; Braun-Munzinger, P.; Paul, P.; Zhang, P. H.; Obenshain, F. E.; Plasil, F. et al.
Partner: UNT Libraries Government Documents Department
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Comparison of calculations and measurements of neutron leakage from the Little Boy replica

Description: Measurements of the neutron leakage spectra from 0.6 to 10 MeV are compared with several calculations and earlier measurements of coarse models of Little Boy. Results indicate excellent agreement except at the nose of the device where the neutron exit path is longer, and neutron streaming through geometric discontinuities may present problems. As a result of the agreement, the longstanding difference between calculations and measurements of the Ichiban critical asembly can be resolved: the resu… more
Date: January 1, 1984
Creator: Forehand, H. M.; Whalen, P. P. & Malenfant, R. E.
Partner: UNT Libraries Government Documents Department
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Stack contamination effects during small-scale combustion testing of synthetic fuels

Description: The Analytical Chemistry Branch at the Pittsburgh Energy Technology Center has undertaken the assessment of the possible environmental impact of substituting synfuels for petroleum-based fuels in utility and industrial boilers. The assessment is based on a study of results obtained from the analysis of trace organic compounds present in the exaust gases of a fully instrumented 20-hp firetube boiler. The stack gases from petroleum-based fuels, synfuels, and methanol combustion tests have been sa… more
Date: January 1, 1984
Creator: Douglas, L.J.; Gibbon, G.A. & White, C.M.
Partner: UNT Libraries Government Documents Department
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Edge region hydrogen line emission in the PDX tokamak

Description: Measurements of the H/sub ..cap alpha../ line shape and of the spatial distribution of the H/sub ..cap alpha../ emissivity in the PDX tokamak are interpreted in terms of molecular dissociation reactions at the plasma edge. The influx of molecules is shown to be roughly proportional to the edge emission intensity over a wide range of temperatures. The H/sub 2/ particle lifetime is estimated for various types of discharges in PDX.
Date: February 1, 1984
Creator: McNeill, D.H.; Bell, M.G.; Grek, B. & LeBlanc, B.
Partner: UNT Libraries Government Documents Department
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Influence of materials and counting-rate effects on /sup 3/He neutron spectrometry

Description: The high energy resolution of the Cuttler-Shalev /sup 3/He neutron spectrometer causes spectral measurements with this instrument to be strongly susceptible to artifacts caused by the presence of scattering or absorbing materials in or near the detector or the source, and to false peaks generated by pileup coincidences of the rather long-risetime pulses from the detector. These effects are particularly important when pulse-height distributions vary over several orders of magnitude in count rate… more
Date: January 1, 1984
Creator: Evans, A.E.
Partner: UNT Libraries Government Documents Department
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Methyltrihydroborate complexes of the lanthanides and actinides

Description: Reaction of MC1/sub 4/ (M = Zr, Hf, U, Th, Np) with LiBH/sub 3/CH/sub 3/ in chlorobenzene produces volatile, hexane-soluble M(BH/sub 3/CH/sub 3/)/sub 4/. Crystal structures are monomeric, tetrahedral species. Lewis base adducts prepared include U(BH/sub 3/CH/sub 3/)/sub 4/.THT, Th(BH/sub 3/CH/sub 3/)/sub 4/.L (L = THF (tetrahydrofuran), THT (tetrahydrothiophene), SMe/sub 2/, OMe/sub 2/), U(BH/sub 3/CH/sub 3/)/sub 4/.2L (L = THF, pyridine, NH/sub 3/), Th(BH/sub 3/CH/sub 3/)/sub 4/.2L (L = THF, T… more
Date: November 1, 1984
Creator: Shinomoto, R.S.
Partner: UNT Libraries Government Documents Department
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First order variation of the dispersion function with particle energy deviation

Description: The variation of the dispersion function with the particle energy deviation can presently be calculated from second order transfer matrices; its periodic solution is determined numerically. The general differential equations for the dispersion function deduced from the complete equation of motion to second order are solved, using Green's function integral leading to an analytical expression of the periodic solution of the dispersion function D/sub 0/ and of the first order perturbation, D/sub 1… more
Date: December 1, 1984
Creator: Delahaye, J. P. & Jaeger, J.
Partner: UNT Libraries Government Documents Department
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Time-resolved x-ray line emission studies of thermal transport in multiple beam uv-irradiated targets

Description: Thermal transport in spherical targets irradiated with multiple, nanosecond duration laser beams, has been a topic of much discussion recently. Different inferences on the level of thermal flux inhibition have been drawn from plasma velocity and x-ray spectroscopic diagnostics. We present new measurements of thermal transport on spherical targets made through time-resolved x-ray spectroscopic measurements of the progress of the ablation surface through thin layers of material on the surface of … more
Date: January 1, 1984
Creator: Jaanimagi, P.A.; Henke, B.L.; Delettrez, J. & Richardson, M.C.
Partner: UNT Libraries Government Documents Department
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Recent results from proton capture to giant resonances built on highly-excited states

Description: New measurements of the (p,..gamma..) reaction on natural targets of K and Ca at intermediate proton energies (E/sub p/ = 11 to 36 MeV) reveal excitation functions that are dominated by excited-state giant dipole resonances (ESGDR's) built upon single-particle states in /sup 40/Ca and /sup 41/Sc. These ESGDR's all peak near E/sub ..gamma../ = 20 MeV and have widths which increase monotonically with the final state's excitation energy. The integrated, inverse (..gamma..,P/sub 0/) cross sections … more
Date: January 1, 1984
Creator: Dowell, D. H.
Partner: UNT Libraries Government Documents Department
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Investigations of molecular orbitals with accel-decel beams

Description: Quasimolecular transition energies can be found directly from the impact-parameter dependence of interference structure observed in measured K x-ray spectra. As these experiments require a K-vacancy bearing projectile at collision velocities small compared to the equivalent K-shell electron velocity, the accel-decel technique has to be used. Such an experiment was performed at the BNL Tandem Accel-Decel Facility for collisions of Cl/sup 16 +/ with Ar at energies ranging from 2.5 to 20 MeV. A ne… more
Date: September 1, 1984
Creator: Meron, M.; Johnson, B. M.; Jones, K. W.; Schuch, R.; Schmidt-Boecking, H. & Tserruya, I.
Partner: UNT Libraries Government Documents Department
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Use of the ORACLE DBMS in determining the response of complex scientific instrumentation

Description: In the Laser Fusion Program at Lawrence Livermore National Laboratory, a single laser fusion experiment lasts only a billionth of a second but in this time high speed instrumentation collects data that when digitized will create a data bank of several megabytes. This first level of data must be processed in several stages to put it in a form useful for interpretation of the experiments. One stage involves unfolding the source characteristics from the data and response of the instrument. This in… more
Date: June 27, 1984
Creator: Auerbach, J.M.; DeMartini, B.J. & McCauley, E.W.
Partner: UNT Libraries Government Documents Department
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Fusion Energy Division annual progress report period ending December 31, 1983

Description: The Fusion Program carries out work in a number of areas: (1) experimental and theoretical research on two magnetic confinement concepts - the ELMO Bumpy Torus (EBT) and the tokamak, (2) theoretical and engineering studies on a third concept - the stellarator, (3) engineering and physics of present-generation fusion devices, (4) development and testing of diagnostic tools and techniques, (5) development and testing of materials for fusion devices, (6) development and testing of the essential te… more
Date: September 1, 1984
Partner: UNT Libraries Government Documents Department
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Ultra-sensitive isotopic analysis by resonance ionization mass spectrometry

Description: A high-powered pulsed dye laser has been interfaced to a commerical ion microprobe mass analyzer. This combination should provide ultra-high sensitivity for isotope ratio measurements of selected elements in environmental samples. The technique is an outgrowth of resonance ionization mass spectrometry which has demonstrated high precision for isotope ratio determinations of uranium and plutonium using thermal filament atomization. Sputter atomization using a pulsed argon ion beam represents a s… more
Date: January 1, 1984
Creator: Donohue, D. L.; Christie, W. H.; Goeringer, D. E. & McKown, H. S.
Partner: UNT Libraries Government Documents Department
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Some aspects of quark fragmentation: comparison of heavy (c) and light quarks (u,d,s)

Description: The data that the author presents come from the first two years of operation of the High Resolution Spectrometer (HRS) at PEP, and correspond to an integrated luminosity of 106 +- 5 pb/sup -1/ (20 pb/sup -1/ from the first year and 86 pb/sup -1/ from the second year's running). Since the quark-meson transitions may have a particularly simple form at the values of the momentum fraction Z = 2p/sub meson//..sqrt..s, we emphasize this aspect of the data, and show how a sample of e/sup +/e/sup -/ ..… more
Date: January 1, 1984
Creator: Derrick, M.
Partner: UNT Libraries Government Documents Department
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