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Kinetics of the radiation-induced exchange reactions of H/sub 2/, D/sub 2/, and T/sub 2/: a review

Description: Mixtures of H/sub 2/--T/sub 2/ or D/sub 2/--T/sub 2/ will exchange to produce HT or DT due to catalysis by the tritium ..beta.. particle. The kinetics of the reaction D/sub 2/ + T/sub 2/ = 2DT may play an important role in designing liquid or solid targets of D/sub 2/--DT--T/sub 2/ for implosion fusion, and distillation schemes for tritium cleanup systems in fusion reactors. Accordingly, we have critically reviewed the literature for information on the kinetics and mechanism of radiation-induce… more
Date: January 6, 1978
Creator: Pyper, J.W. & Briggs, C.K.
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
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Diagnosing vegetation injury caused by air pollution

Description: The structure and function of plants in relation to air pollution injury is discussed. The sources, atmospheric chemistry, monitoring data, symptomatology, factors affecting plant response, injury threshold doses, air quality standards, relative sensitivity of plants, and leaf tissue analysis are discussed for major air pollutants. Among the pollutants discussed are: the photochemical oxidants (ozone, PAN, nitrogen oxides, sulfur dioxide, and fluorides). Minor pollutants discussed in the same f… more
Date: February 1, 1978
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
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Anion exchange of 58 elements in hydrobromic acid and in hydriodic acid

Description: Anion exchange distributions of 58 elements have been measured from 0.1-8.7M HBr and from 0.1-7.4M HI onto three strong-base resins, 8 and 4% cross-linked and macroporous. Data were obtained by 16- to 18-h dynamic batch contacts. Anion exchange in these media is compared to that in HCl. The effect of resin cross-linkage is considerably greater in HI media than in HBr and HCl media. Examples are presented of potentially useful separations using HBr and HI media alone and in combination with HCl.
Date: February 1, 1978
Creator: Marsh, S. F.; Alarid, J. E.; Hammond, C. F.; McLeod, M. J.; Roensch, F. R. & Rein, J. E.
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
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Experimental investigation of the chemistry of excited states of rare gases. First quarterly progress report, October 15, 1977--January 15, 1978

Description: The quenching of XeF(B) was studied using the steady-state photolysis of XeF/sub 2/ as the source of XeF(B). The product states from the sensitized reaction of Xe(/sup 3/P/sub 1/) with Cl/sub 2/ and COCl/sub 2/ also were studied. The new XeF(B) quenching rate constants are described. The pulsed laser induced fluorescence technique was used to measure radiative lifetimes and two-body quenching rate constant (with Ar) for the low energy Xe(6p)* states. Serious signal/noise problems for the lowest… more
Date: February 1978
Creator: Setser, D. W.
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
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Precipitation kinetics of a continuous precipitator, with application to the precipitation of ammonium polyuranate

Description: A mathematical model describing the kinetics of continuous precipitation was developed which accounts for crystal nucleation, crystal growth, primary coagulation, and secondary coagulation. Population density distributions, average particle sizes, dominant particle sizes, and suspension density fractions of the crystallites, primary agglomerates, and secondary agglomerates leaving the continuous precipitator can be determined. This kinetic model was applied to the continuous precipitation of am… more
Date: April 1, 1978
Creator: Hoyt, R.C.
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
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Preconcentration of plutonium radionuclides from natural waters. [Pu in Eniwetok ground water, lagoon and open ocean waters]

Description: A large volume water sampler using manganese dioxide impregnated cartridges for the in situ separation of plutonium in sea water and ground water was studied. Plutonium concentrations obtained by this technique are compared with a radiochemical coprecipitation method. Consistent results were obtained between the two methods for water samples from the Pacific Ocean and Enewetak lagoon. Different results were noted from samples collected in the Enewetak reef and ground water stations. Using this … more
Date: February 1, 1978
Creator: Wong, K. M.; Nioshkin, V. E. & Jokela, T. A.
Item Type: Refine your search to only Article
Partner: UNT Libraries Government Documents Department
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Shippingport Atomic Power Station steam generator tube damage and water chemistry control (1965--1975)

Description: The four stainless steel tubed steam generators in the Shippingport Atomic Power Station were replaced in 1964 with larger, horizontal, NiCrFe Alloy 600 tubed units consistent with a power uprating of the plant. Each of the four Alloy 600 tubed units experienced tube leakage attributed to corrosion by water treatment chemicals (sodium phosphates) which concentrated locally on the tubes in inadequately flushed crevices. Corrective and preventive actions include tube plugging, flow blockage, conv… more
Date: January 1978
Creator: Singley, W. J.
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
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Removal of uv-induced pyrimidine dimers from the replicated and unreplicated DNA of human fibroblasts

Description: Excision repair in uv irradiated human fibroblasts has been examined in portions of DNA replicating after irradiation versus those remaining unreplicated. Two approaches, one using a uv-endonuclease to estimate pyrimidine dimers remaining in DNA, the other using density labeling to measure excision resynthesis, indicate that the extent of repair is the same for both replicated and unreplicated DNA.
Date: January 1, 1978
Creator: Waters, R.
Item Type: Refine your search to only Article
Partner: UNT Libraries Government Documents Department
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Quadrupole mass-filter sensitivities of H/sub 2/, HD, D/sub 2/, and T/sub 2/, and the kinetics of. beta. -particle induced exchange between H/sub 2/, D/sub 2/, and T/sub 2/ at 25. 4/sup 0/C

Description: We have constructed a quadrupole-mass filter system to measure the equilibrium constants and rates of reaction of the ..beta..-particle-induced exchanges between H/sub 2/, D/sub 2/, and T/sub 2/ at cryogenic temperatures. Even with careful calibration experiments at 25.4/sup 0/C, we could not completely remove the mass discrimination inherent in our method. We estimate the accuracy of our mixture analyses to be +-2.2% in the D/sub 2/-DT-T/sub 2/ system, and +-9% in the H/sub 2/-HT-T/sub 2/ syst… more
Date: January 11, 1978
Creator: Pyper, J. W.; Kelly, E. M.; Magistad, J. G.; Tsugawa, R. T.; Roberts, P. E. & Souers, P. C.
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
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Secondary recovery of plutonium and americium from process waste streams by solvent extraction

Description: A solvent extraction process is being evaluated for the secondary recovery of plutonium and americium from Rocky Flats waste streams. The bidentate organophosphorus compounds dihexyl-N,N-diethylcarbamylmethylene phosphonate and its dibutyl analogue have been shown to be selective extractants for the actinides from solutions of nitric acid. The results from laboratory test runs in which the organophosphorus extractants were used for processing secondary waste solutions will be presented. Solvent… more
Date: January 16, 1978
Creator: Hagan, P. G. & Navratil, J. D.
Item Type: Refine your search to only Article
Partner: UNT Libraries Government Documents Department
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Materials technology for accelerator production of fissile isotopes

Description: The materials used for the accelerator production of fissile isotopes must enable the facility to achieve maximum fuel production at a minimum cost. Neutron production in the target would be maximized by use of thorium cooled with Pb--56 percent Bi or with sodium. The thorium should be ion-plated with approximately 1 mil of nickel or stainless steel for retention of fission products. The target container will have to be replaced at frequent intervals because of the copious quantities of neutron… more
Date: February 1, 1978
Creator: Horak, J.A.
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
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Kinetics of the ambient temperature dissolution of plutonium metal in sulfamic acid

Description: The stoichiometry and the kinetics of the ambient temperature dissolution of alpha-phase plutonium in sulfamic acid has been determined. Hydrogen off-gas rates and plutonium concentrations were calculated as functions of time for a variety of dissolving conditions. Calculations show that nominal 2.2 kg Pu buttons (surface area, 171 cm/sup 2/) should yield solutions containing 60 +- 10 g Pu/L after a one-hour dissolving cycle. Hydrogen off-gas rates were calculated to vary from as high as 780 mL… more
Date: March 1, 1978
Creator: Gray, L.W.
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
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Limnological aspects of acid precipitation

Description: Lakes and streams in parts of Norway, Sweden, Canada, and the United States are being severely impacted by acidic precipitation. Scientists meeting at Sagamore, New York, agreed that this is the most serious limnological problem today. The factor responsible for determining the sensitivity of surface waters to acidification is alkalinity derived by weathering of soils and bedrock in the watershed. Acidification, defined as a reduction in alkalinity, can be quantified if preacidification alkalin… more
Date: January 1, 1978
Creator: Hendrey, G.R. (ed.)
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
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Apparatus for simultaneously measuring electrical conductivity and oxygen fugacity

Description: Electrical conductivity studies of silicates are useful in determining temperature vs depth in the earth. Realistic laboratory measurements of conduction mechanisms require that exact determinations of oxygen fugacity (fo{sub 2}) be made in the experimental environment. An apparatus is described that monitors system fo{sub 2} with a calcia-doped zirconia-oxygen cell while measuring electrical conductivity of iron-bearing silicates at high temperature (greater than 1000 K). The fo{sub 2} calcula… more
Date: January 31, 1978
Creator: Netherton, R. & Duba, A.
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
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Simultaneous analysis of uranium and nitrate

Description: A direct spectrophotometric method has been developed for the determination of 20 to 200 g/l of uranium in the presence of 3 to 5 M nitric acid. A dual-wavelength analysis is used to eliminate the enhancing effect of nitrate ion on the uranium visible spectra. The precision and accuracy of the simultaneous analysis of uranium and nitrate were compared using combinations of the four uranium wavelength maxima, occurring at 426, 416, 403 and 359 nm. Calculations based on 426 and 416 nm data yielde… more
Date: April 1, 1978
Creator: Bostick, D.T.
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
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Procedure for the analysis of americium in complex matrices

Description: A radioanalytical procedure for the analysis of americium in complex matrices has been developed. Clean separations of americium can be obtained from up to 100 g of sample ash, regardless of the starting material. The ability to analyze large masses of material provides the increased sensitivity necessary to detect americium in many environmental samples. The procedure adequately decontaminates from rare earth elements and natural radioactive nuclides that interfere with the alpha spectrometric… more
Date: February 1, 1978
Creator: Knab, D.
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
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Experimental Engineering Section semiannual progress report, March 1-August 31, 1976. Volume 2. Biotechnology and environmental programs

Description: This volume contains the progress report of the biotechnology and environmental programs in the Experimental Engineering Section of the Chemical Technology Division. Research efforts in these programs during this report period have been in five areas: (1) environmental research; (2) centrifugal analyzer development; (3) advanced analytical systems development; (4) bioengineering research; and (5) bioengineering development. Summaries of these programmatic areas are contained in Volume I.
Date: March 1, 1978
Creator: Pitt, Jr., W. W. & Mrochek, J. E.
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
open access

Reaction of uranyl nitrate solutions with amberlite IRC-72 cation exchange resin at 30/sup 0/C: a kinetic investigation for the HTGR fuel recycle plant

Description: A kinetic investigation of the reaction of uranyl nitrate solution with Amberlite IRC-72 cation exchange resin was conducted at 30/sup 0/C under conditions similar to those anticipated for a High-Temperature Gas-Cooled Reactor fuel refabrication facility. A simplified mass transfer analogue expression was developed to evaluate the effects of process parameters on the resin loading rate. Correlation of the experimental data with the integrated rate expression depended only on the determination o… more
Date: January 1, 1978
Creator: Shaffer, J. H.; Shockley, W. E. & Evans, R. B., III
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
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Radiolytic gas production from concrete containing Savannah River Plant waste

Description: To determine the extent of gas production from radiolysis of concrete containing radioactive Savannah River Plant waste, samples of concrete and simulated waste were irradiated by /sup 60/Co gamma rays and /sup 244/Cm alpha particles. Gamma radiolysis simulated radiolysis by beta particles from fission products in the waste. Alpha radiolysis indicated the effect of alpha particles from transuranic isotopes in the waste. With gamma radiolysis, hydrogen was the only significant product; hydrogen … more
Date: January 1, 1978
Creator: Bibler, N.E.
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
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Steam generator tube denting simulation testing. [PWR]

Description: Tube denting has been reported in steam generators in a number of commercial nuclear power plants in recent years. In order to aid in understanding of the mechanism leading to tube denting in the steam generators, a Bettis laboratory test program was initiated to attempt to reproduce tube denting and to investigate the effects of chemistry, design, and temperature. The results of the tests indicate that denting can be reproduced in the small model steam generator test apparatus devised for this… more
Date: February 1978
Creator: Battaglia, P. J. & Singley, W. J.
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
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Mound Laboratory tritium environmental study: 1976--1977

Description: In the course of an extensive investigation of tritium in the aquifer underlying the Mound Facility site, an unusual behavior was noted for a beta-emitting radionuclide contaminant present in the environs of the abandoned Miami-Erie Canal adjacent to the laboratory site. The soil contaminant was determined to be tritium, of which 90% was in the form of a relatively stable or bound species that was not readily exchangeable with the free water in the soil. (Bound-to-exchangeable transfer half-tim… more
Date: April 10, 1978
Creator: Kershner, C.J. & Rhinehammer, T.B.
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
open access

Beneficial uses of nuclear fission wastes

Description: Sandia is investigating the use of /sup 137/Cs from radioactive waste to reduce the pathogen levels of municipal sewage sludges so that they can be used in agriculture, either as fertilizer or as feed supplement. The Sandia Irradiator for Dried Sewage Solids (SIDSS) is a pilot plant for treating 16 tons per day to a dose of 500 krad, using 1 MCi of /sup 137/Cs. A larger (25 ton/day) demonstration plant is also planned. A cost/benefit study of this application was made. Use of /sup 99/Tc for mar… more
Date: March 31, 1978
Creator: Sivinski, H.D.
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
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