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DI-TERTIABYBUTYLNITROXIDE, A HILL REAGENT

Description: Di-tertiarybutylnitroxide (DTBN), which they have tried to use as a trapping agent to identify the species giving rise to the photo-induced EPR signals in photosynthetic materials, functions as a Hill reagent with spinach chloroplasts. Evidence is presented which indicates that the reduction of DTBN is affected by photosystem II of the electron transport system of spinach chloroplasts. The reduced form of DTBN, the hydroxylamine, undergoes a photo-oxidation with spinach chloroplasts. Possible e… more
Date: January 1, 1970
Creator: Corker, Gerald A.; Klein, Melvin P.; La Font, Didier & Calvin,Melvin.
Partner: UNT Libraries Government Documents Department
open access

Measurement of Pair Interactions in Neodymium Ethyl Sulfate

Description: The EPR spectrum of single ions of /sup 143/Nd in a crystal of Neodymium Ethyl Sulfate, predominantly of isotope /sup 142/Nd, was observed under condition of very high Boltzmann factor, i.e., high fields and low temperatures. It was found that the interactions with neighboring ions displaced the hyperfine lines from uniform spacing, and that by measuring the deviation it was possible to find the nearest neighbor interaction. The departure from a purely magnetic dipolar interaction is smaller th… more
Date: August 1, 1970
Creator: King, A. R. & Jeffries, C. D.
Partner: UNT Libraries Government Documents Department
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