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Procedure for matching synfuel users with potential suppliers. Final report

Description: A procedure has been developed for matching prospective users and producers of synthetic fuels. The matching procedure, which involves a hierarchical screening process, is designed to assist OFC in: locating a supplier for a firm that wishes to obtain synthetic fuel exemption (Fuel Use Act); determining whether the fuel supplier proposed by a petitioner is technically and economically capable of meeting the petitioner's needs; and assisting the Synthetic Fuels Corporation in evaluating pot… more
Date: September 26, 1981
Partner: UNT Libraries Government Documents Department
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Conversion of Hydrogen Sulfide in Coal Gases to Liquid Elemental Sulfur with Monolithic Catalysts

Description: Removal of hydrogen sulfide (H{sub 2}S) from coal gasifier gas and sulfur recovery are key steps in the development of Department of Energy's (DOE's) advanced power plants that produce electric power and clean transportation fuels with coal and natural gas. These plants will require highly clean coal gas with H{sub 2}S below 1 ppmv and negligible amounts of trace contaminants such as hydrogen chloride, ammonia, alkali, heavy metals, and particulate. The conventional method of sulfur removal and… more
Date: September 30, 2007
Creator: Kwon, K. C.
Partner: UNT Libraries Government Documents Department
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Advanced Hot Section Materials and Coatings Test Rig

Description: Phase I of the Hyperbaric Advanced Hot Section Materials & Coating Test Rig Program has been successfully completed. Florida Turbine Technologies has designed and planned the implementation of a laboratory rig capable of simulating the hot gas path conditions of coal gas fired industrial gas turbine engines. Potential uses of this rig include investigations into environmental attack of turbine materials and coatings exposed to syngas, erosion, and thermal-mechanical fatigue. The principle activ… more
Date: September 30, 2006
Creator: Davis, Dan
Partner: UNT Libraries Government Documents Department
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Fundamental characterization of alternate fuel effects in continuous combustion systems

Description: The overall objective of this contract is to assist in the development of fuel-flexible combustion systems for gas turbines as well as Rankine and Stirling cycle engines. The primary emphasis of the program is on liquid hydrocarbons produced from non-petroleum resouces. Fuel-flexible combustion systems will provide for more rapid transition of these alternate fuels into important future energy utilization centers (especially utility power generation with the combined cycle gas turbine). The spe… more
Date: September 11, 1978
Creator: Blazowski, W. S.; Edelman, R. B. & Harsha, P. T.
Partner: UNT Libraries Government Documents Department
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Innovative Coke Oven Gas Cleaning System for Retrofit Applications Quarterly Report: July-September 1991

Description: The EMP consists of a Compliance Monitoring Sampling Program and a Supplemental monitoring Sampling Program. The Compliance Monitoring Sampling Program will be conducted during a summer and a winter Baseline periods during the Pre-Construction/Construction phases of the Project and during a summer and a winter period following the successful Startup and Operational phase of the completed Project. compliance monitoring consist of conducting all the sampling and observation programs associated wi… more
Date: September 21, 1992
Partner: UNT Libraries Government Documents Department
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Desulfurization of hot fuel gas produced from high-chlorine Illinois coals. Technical report, December 1, 1991--February 29, 1992

Description: There is a primary need to increase the utilization of Illinois coal resources by developing new methods of converting the coal into electricity by highly efficient and environmentally acceptable systems. New coal gasification processes are now being developed that can generate electricity with high thermal efficiency in either an integrated gasification combined cycle (IGCC) system or a molten carbonate fuel cell (MCFC). Both of-these new coal-to-electricity pathways require that the coal-deri… more
Date: September 1, 1992
Creator: O`Brien, W. S. & Gupta, R. P.
Partner: UNT Libraries Government Documents Department
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Techno-Economic Feasibility of Highly Efficient Cost-Effective Thermoelectric-SOFC Hybrid Power Generation Systems

Description: Solid oxide fuel cell (SOFC) systems have the potential to generate exhaust gas streams of high temperature, ranging from 400 to 800 C. These high temperature gas streams can be used for additional power generation with bottoming cycle technologies to achieve higher system power efficiency. One of the potential candidate bottoming cycles is power generation by means of thermoelectric (TE) devices, which have the inherent advantages of low noise, low maintenance and long life. This study was to … more
Date: September 30, 2007
Creator: Zhang, Jifeng & Yamanis, Jean
Partner: UNT Libraries Government Documents Department
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Conversion of Hydrogen Sulfide in Coal Gases to Liquid Elemental Sulfur with Monolithic Catalysts

Description: Removal of hydrogen sulfide (H{sub 2}S) from coal gasifier gas and sulfur recovery are key steps in the development of Department of Energy's (DOE's) advanced power plants that produce electric power and clean transportation fuels with coal and natural gas. These plants will require highly clean coal gas with H{sub 2}S below 1 ppmv and negligible amounts of trace contaminants such as hydrogen chloride, ammonia, alkali, heavy metals, and particulate. The conventional method of sulfur removal and… more
Date: September 30, 2009
Creator: Kwon, K. C.
Partner: UNT Libraries Government Documents Department
open access

Stability of Sulfur Capacity Attributed to Zinc Sulfidation on Sorbent Containing Zinc Ferrite-Silica Composite Powder in Pressurized Coal Gas

Description: This paper describes an attempt to divide the total sulfur capacity into its contribution from zinc and iron using a pressurized-type thermobalance. The methodology to estimate the sulfur capacities corresponding to zinc and iron was applied to evaluate the variation in performance during multiple-cycle desulfurization. Primary objective of this paper is providing information on the stability of zinc-related sulfur capacity, which is essentially important to the sulfur removal performance at th… more
Date: September 19, 2002
Creator: Kobayashi, M.; Shirai, H. & Nunokawa, M.
Partner: UNT Libraries Government Documents Department
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Regeneration and Durability of Advanced Zinc Ferrite Sorbent for Hot Coal Gas Desulfurization

Description: In this study, we investigate the regeneration characteristics, desulfurization performance after regeneration and the durability of zinc ferrite sorbent in the desulfurization/regeneration cycles.
Date: September 19, 2002
Creator: Shirai, H.; Kobayashi, M.; Nunokawa, M. & Noda, N.
Partner: UNT Libraries Government Documents Department
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Diffusion Coatings for Corrosion-Resistant Components in Coal Gasification Systems Quarterly Technical Progress Report: Number 7

Description: Heat-exchangers, particle filters, turbines, and other components in integrated coal gasification combined cycle system must withstand the highly sulfiding conditions of the high-temperature coal gas over an extended period of time. The performance of components degrades significantly with time unless expensive high alloy materials are used. Deposition of a suitable coating on a low-cost alloy may improve its resistance to such sulfidation attack, and decrease capital and operating costs. The a… more
Date: September 1, 2005
Creator: Krishnan, Gopala N.; Malhotra, Ripudaman; Alvarez, Esperanza; Lau, Kai-Hung & Sanjurjo, Angel
Partner: UNT Libraries Government Documents Department
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A Reusable Calcium-Based Sorbent for Desulfurizing Hot Coal Gas

Description: The overall objective of this project has been to develop a superior, regenerable, calcium-based sorbent for desulfurizing hot coal gas. The sorbent should be strong, durable, inexpensive to manufacture, and capable of being reused many times. To achieve these objectives the project has focused on the development of the very promising core-in-shell sorbent.
Date: September 19, 2002
Creator: Wheelock, T. D. & Hasler, D. J. L.
Partner: UNT Libraries Government Documents Department
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Fixed bed testing of a molybdenum-promoted zinc titanate for hot gas desulfurization

Description: The following conclusions were made, based upon this study of T-2535 molybdenum-promoted zinc titanate: (1) Results of the half-cycle sulfidation experiments showed that sorbent efficiency and capacity of this formulation of zinc titanate were weak functions of operating-bed temperature. Evidence of diffusion limitations on the sulfidation reaction were observed, particularly at superficial velocities greater than 30 cm/s (1 ft/s). Sorbent performance appeared to be affected by the concentratio… more
Date: September 1, 1993
Creator: Gasper-Galvin, L. D.; Mei, J. S.; Everitt, C. E. & Katta, S.
Partner: UNT Libraries Government Documents Department
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CE IGCC repowering project hot gas clean up system

Description: With sponsorship from the Department of Energy (DOE), and the state of Illinois, Combustion Engineering, Inc. is currently developing a design for a 60 Mw IGCC (Integrated Coal Gasification Combined Cycle) for City Water, Light & Power (CWL&P) in Springfield, Illinois. In addition, to DOE and the state of Illinois, Combustion Engineering, Inc. and CWL&P are contributing to the project. In order to obtain a high thermal efficiency, a hot gas cleanup system has been incorporated for product gas c… more
Date: September 1, 1993
Partner: UNT Libraries Government Documents Department
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Innovative coke oven gas cleaning system for retrofit applications. Quarterly environmental monitoring report No. 2, July 1, 1991--September 30, 1991

Description: The EMP consists of a Compliance Monitoring Sampling Program and a Supplemental monitoring Sampling Program. The Compliance Monitoring Sampling Program will be conducted during a summer and a winter Baseline periods during the Pre-Construction/Construction phases of the Project and during a summer and a winter period following the successful Startup and Operational phase of the completed Project. compliance monitoring consist of conducting all the sampling and observation programs associated wi… more
Date: September 21, 1992
Partner: UNT Libraries Government Documents Department
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Fixed bed testing of a molybdenum-promoted zinc titanate sorbent for hot gas desulfurization

Description: The experimental test program for the molybdenum-promoted zinc titanate with Zn/Ti ratio of 1.91, consists of two series of test: six half-cycle (sulfidation phase) parametric tests and four multi-cycle (sulfidation and regeneration phase) tests. Results of the parametric tests were utilized to select the optimum conditions for multi-cycle tests. The intent of the multi-cycle test series was to demonstrate durability and regenerability of the molybdenum-promoted zinc titanate sorbent. During th… more
Date: September 1, 1993
Creator: Mei, J. S.; Gasper-Galvin, L.; Everitt, C. E. & Katta, S.
Partner: UNT Libraries Government Documents Department
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Bench-scale development of mild gasification char desulfurization. Technical report, 1 March--31 May 1994

Description: The goal of this project is to scale up a process, developed under a previous ICCI grant, for desulfurization of mild gasification char by treatment with hydrogen-rich process-derived fuel gas at 650--760 C and 7--15 atm. The char can be converted into a low-sulfur metallurgical form coke. In the prior study, IBC-105 coal with 4.0 wt% sulfur was converted to chars with less than 1.0 wt% sulfur in a laboratory-scale batch reactor. The susceptibility of the char to desulfurization was correlated … more
Date: September 1, 1994
Creator: Knight, R. A.
Partner: UNT Libraries Government Documents Department
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High temperature hydrogen sulfide removal with tin oxide

Description: The system is based on the absorption of hydrogen sulfide (H{sub 2}S) by stannic (tin) oxide. Two sorbents are required, the first sorbent is tin oxide and the second sorbent is a zinc oxide based material (i.e., zinc ferrite or zinc titanate) which is regenerated by air producing SO{sub 2}. TDA`s process carries out a modified Claus reaction to reduce the SO{sub 2} from the second sorbent generation to elemental sulfur. In this case the sulfided stannic oxide forms stannous sulfide (SnS) which… more
Date: September 1, 1993
Creator: Karpuk, M. E.; Copeland, R. J.; Feinberg, D.; Wickham, D.; Windecker, B. & Yu, J.
Partner: UNT Libraries Government Documents Department
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Particulate characterization for PFBC filter systems

Description: Southern Research Institute is participating, as a subcontractor to Southern Company Services (SCS), in METC`s project to establish a Power Systems Development Facility at Wilsonville, Alabama. This plant will serve as a facility for the development and testing of advanced systems for coal-based power generation. An important part of the program will be to test and evaluate various kinds of particulate control devices and systems for operation at high temperatures and high pressures. The hot ga… more
Date: September 1, 1993
Creator: Pontius, D. H.
Partner: UNT Libraries Government Documents Department
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Fluid-bed HGD PDU

Description: METC is constructing an on-site, fluid-bed, hot-gas desulfurization (HGD) process development unit (PDU) to support the US Department of Energy`s (DOE) Integrated Gasification Combined Cycle power systems program. Once operational, this PDU will be used to develop process scale-up and performance data for a number of configurations and to demonstrate fully coupled sulfidation-regeneration operations. Its size and gas throughput should also enable the PDU to address some of the actual engineerin… more
Date: September 1, 1993
Creator: Bissett, L. A.
Partner: UNT Libraries Government Documents Department
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Testing of zinc titanate desulfurization sorbents for moving-bed applications

Description: Sorbents developed for moving-bed systems must comply with a minimum of chemical and mechanical durability performance characteristics in order to be considered acceptable for long-term operation. Among the desired properties, a sorbent must have: (1) High chemical reactivity, as measured by the rate of sulfur absorption and the total sulfur loading on the sorbent. (2) High mechanical strength, as measured by the pellet crush strength and the attrition resistance; (3) Suitable pellet morphology… more
Date: September 1, 1993
Creator: Ayala, R. E.; Gal, E. & Gupta, R. P.
Partner: UNT Libraries Government Documents Department
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METC Fluid-bed Test Rigs/Test Program

Description: Since its last runs in December 1989, the 6-inch gasifier has been modified to enlarge the reactor inside diameter to 10 inches. Recent runs have shown stable operation and increased carbon conversion with the new gasifier size. As a 10-inch reactor, the METC FBG has logged over 150 hours online with Montana Rosebud coal. Table 2 shows typical solids analyses for an April 1993 run. A series of hot gas desulfurization tests using a batch-mode, fluidized bed to contact the coal gas with sulfur ca… more
Date: September 1, 1993
Creator: Walczak, S. C.; Rockey, J. M. & Rutten, J.
Partner: UNT Libraries Government Documents Department
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Applications of moving granular-bed filters to advanced systems

Description: The contract is arranged as a base contract with three options. The objective of the base contract is to develop conceptual design(s) of moving granular bed filter and ceramic candle filter technology for control of particles from integrated gasification combined cycle (IGCC) systems, pressurized fluidized-bed combustors (PFBC), and direct coal fueled turbine (DCFT) environments. The conceptual design(s) of these filter technologies are compared, primarily from an economic perspective. The gran… more
Date: September 1, 1993
Creator: Wilson, K. W.; Haas, J. C. & Eshelman, M. B.
Partner: UNT Libraries Government Documents Department
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Improved plasma torch and data analysis software for an on-line, multielement ICP spectrometer designed for application to high temperature and pressure fossil fuel process streams

Description: Rising concerns about the potential release of harmful elements into the environment from coal utilization have driven the development of new analytical capabilities. Especially useful to the suite of advanced technologies under development by the Morgantown Energy Technology Canter, (METC), would be a process monitor to perform real-time, multi-clement trace analysis in a high temperature and high pressure environment. The inductively coupled plasma (ICP) spectrometer has the potential to perf… more
Date: September 1, 1993
Creator: Yip, J.; Pearce, K. D.; Christy, C. E.; Barill, B. A.; Monteleone, S. M. & Chisholm, W. P.
Partner: UNT Libraries Government Documents Department
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