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Scrubbing of iodine from gas streams with mercuric nitrate-conversion of mercuric iodate product to barium iodate for fixation in concrete

Description: A bench-scale model of a mercuric nitrate scrubber for removal of iodine from off-gas streams was constructed and operated in conjunction with a mercuric iodate-to-barium iodate conversion system to determine the feasibility of total recycle of all processing solutions. The two main aspects of the system examined were (1) the extent of contamination of the barium iodate product, and (2) the effect of cross-contamination of various process solutions on the efficiency of the process. The experime… more
Date: June 1, 1980
Creator: Rogers, G. C.; Moore, J. G. & Morgan, M. T.
Partner: UNT Libraries Government Documents Department
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Environmental control implications of generating electric power from coal

Description: Environmental control technologies applicable to the coal-to-electricity process are evaluated in an ongoing project at Argonne National Laboratory. Part of the evaluation involves technology comparisons from a total system point of view. This report describes a highly versatile procedure developed for making those comparisons. The core of the procedure is a simulation mechanism of interconnected modules, each corresponding to a portion of the system stretching from raw coal to power plant emis… more
Date: June 1, 1977
Creator: Livengood, C D
Partner: UNT Libraries Government Documents Department
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LFCM (liquid-fed ceramic melter) processing characteristics of mercury

Description: An experimental-scale liquid-fed ceramic melter was used in a series of tests to evaluate the processing characteristics of mercury in simulated defense waste under various melter operating conditions. This solidification technology had no detectable capacity for incorporating mercury into its borosilicate, vitreous, product, and essentially all the mercury fed to the melter was lost to the off-gas system as gaseous effluent. An ejector venturi scrubber condensed and collected 97% of the mercur… more
Date: June 1, 1990
Creator: Goles, R.W.; Sevigny, G.J. & Andersen, C.M.
Partner: UNT Libraries Government Documents Department
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Separation of flue-gas scrubber sludge into marketable products. Third quarterly technical progress report, March 1, 1994--May 31, 1994

Description: Column flotation represents a significant improvement over conventional flotation for many applications. This improvement consists of increased selectivity between hydrophobic and hydrophilic particles, which allows the column to produce higher-purity products. A schematic of the column used is given in Figure 1. The basic procedure for the flotation column experiments was as follows: 500 grams of the sludge from Plant A (prepared as described in the Second Quarterly Report) was suspended at 40… more
Date: June 1, 1994
Creator: Kawatra, S. K.; Eisele, T. C. & Shoop, K.
Partner: UNT Libraries Government Documents Department
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Emerging flue-gas cleanup technologies for combined control of SO{sub 2} and NO{sub x}

Description: Enactment of the 1990 Clean Air Act Amendments, as well as passage of legislation at the state level has raised the prospect of more stringent nitrogen oxides (NO{sub x}) emission regulations and has fueled research and development efforts on a number technologies for the combined control of sulfur dioxide (SO{sub 2}) and NO{sub x}. The integrated removal of both SO{sub 2} and NO{sub x} in a single system can offer significant advantages over the use of several separate processes, including suc… more
Date: June 1, 1994
Creator: Livengood, C. D. & Markussen, J. M.
Partner: UNT Libraries Government Documents Department
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Comparison of pre- and post-combustion carbon removal

Description: Conventional approaches to reduce CO{sub 2} emissions, including fuel switching among fossil fuels, renewables, nuclear, end-use conservation, and increased efficiency, nearly all lead to reduction in coal use. Carbon removal technologies along have the potential to allow continued use of coal. All approaches must compete economically, technically, and environmentally for market share within the context of the total energy system. MARKAL, a dynamic energy systems model, was used to simulate thi… more
Date: June 1, 1992
Creator: Morris, S. C.; Lee, J.; Goldstein, G. & Steinberg, M.
Partner: UNT Libraries Government Documents Department
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Microbial stabilization of sulfur-laden sorbents. Technical report, 1 December 1993--28 February 1994

Description: Clean coal technologies that involve limestone for sulfur capture generate lime/limestone products laden with sulfur at various oxidation states. If sulfur is completely stabilized as sulfate, the spend sorbent is ready for commercial utilization as gypsum. However, the presence of reduced sulfur species required additional processing. Thermal oxidation of reduced sulfur can result in undesirable release of SO{sub 2}. Microbial oxidation might provide an inexpensive and effective alternative. S… more
Date: June 1, 1994
Creator: Miller, K. W.
Partner: UNT Libraries Government Documents Department
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The Homogeneus Forcing of Mercury Oxidation to provide Low-Cost Capture

Description: Trace amounts of mercury are found in all coals. During combustion, or during thermal treatment in advanced coal processes, this mercury is vaporized and can be released to the atmosphere with the ultimate combustion products. This has been a cause for concern for a number of years, and has resulted in a determination by the EPA to regulate and control these emissions. Present technology does not, however, provide inexpensive ways to capture or remove mercury. Mercury that exits the furnace in … more
Date: June 30, 2007
Creator: Kramlich, John & Castiglone, Linda
Partner: UNT Libraries Government Documents Department
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Dissolver Off-gas Hot Operations Authorization (AFCI CETE Milestone Report)

Description: The head-end processing of the Coupled-End-to-End (CETE) Demonstration includes fuel receipt, fuel disassembly, exposure of fuel (e.g., by segmenting the fuel pins), voloxidation of the fuel to separate tritium, and fuel dissolution. All of these processing steps with the exception of the dissolution step will be accomplished in the Irradiated Fuels Examination Laboratory (IFEL) (Building 3525). The final headend step will be performed in the Radiochemical Engineering Development Center (Buildi… more
Date: June 1, 2009
Creator: Jubin, Robert Thomas
Partner: UNT Libraries Government Documents Department
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CHARACTERIZATION OF DWPF MELTER OFF-GAS QUENCHER AND STEAM ATOMIZED SCRUBBER DEPOSIT SAMPLES

Description: This report summarizes the results from the characterization of deposits from the inlets of the primary off-gas Quencher and Steam Atomized Scrubber (SAS) in the Defense Waste Processing Facility (DWPF), as requested by a technical assistance request. DWPF requested elemental analysis and compound identification to help determine the potential causes for the substance formation. This information will be fed into Savannah River National Laboratory modeling programs to determine if there is a way… more
Date: June 6, 2007
Creator: Zeigler, K & Ned Bibler, N
Partner: UNT Libraries Government Documents Department
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Electrostatically Enhanced Barrier Filter Collection: Final Report

Description: This work was performed through the University of North Dakota (UND) Chemical Engineering Department with assistance from UND's Energy & Environmental Research Center. This research was undertaken in response to the U.S. Department of Energy Federal Technology Center Program Solicitation No. DE-PS26-99FT40479, Support of Advanced Coal Research at U.S. Universities and Colleges. Specifically, this research was in support of the UCR Core Program and addressees Topic 1, Improved Hot-Gas Contaminan… more
Date: June 1, 2003
Creator: Erjavec, John; Mann, Michael D.; Knutson, Ryan Z.; Swanson, Michael L. & Collings, Michael E.
Partner: UNT Libraries Government Documents Department
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Development of mercury control techniques for utility boilers

Description: This paper gives an overview of research being conducted at Argonne National Laboratory on the capture of mercury in flue gas by both dry sorbents and wet scrubbers. The emphasis in the research is on development of a better understanding of the key factors that control the capture of mercury. Future work is expected to utilize that information for the development of new or modified process concepts featuring enhanced mercury capture capabilities.
Date: June 1, 1995
Creator: Livengood, C. D.; Mendelsohn, M. H.; Huang, H. S. & Wu, J. M.
Partner: UNT Libraries Government Documents Department
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Chloride removal from vitrification offgas

Description: This study identified and investigated techniques of selectively purging chlorides from the low-level waste (LLW) vitrification process with the purge stream acceptable for burial on the Hanford Site. Chlorides will be present in high concentration in several individual feeds to the LLW Vitrification Plant. The chlorides are highly volatile in combustion type melters and are readily absorbed by wet scrubbing of the melter offgas. The Tank Waste Remediation System (TWRS) process flow sheets show… more
Date: June 1, 1995
Creator: Slaathaug, E.J.
Partner: UNT Libraries Government Documents Department
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Commercial Demonstration of the Manufactured Aggregate Processing Technology Utilizing Spray Dryer Ash

Description: This quarterly report covers the period from January 1st, 2003 through March 31st, 2003. It covers; technical development, permitting status, engineering status, construction status, operations summary and marketing support activities for this period.
Date: June 1, 2003
Creator: Scandrol, Roy
Partner: UNT Libraries Government Documents Department
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Survey of industrial coal conversion equipment capabilities: high-temperature, high-pressure gas purification

Description: In order to ensure optimum operating efficiencies for combined-cycle electric generating systems, it is necessary to provide gas treatment equipment capable of operating at high temperatures (>1000/sup 0/F) and high pressure (>10 atmospheres absolute). This equipment, when assembled in a process train, will be required to condition the inlet stream to a gas turbine to suitable levels of gas purity (removal of particulate matter, sulfur, nitrogen, and alkali metal compounds) so that it wil… more
Date: June 1, 1978
Creator: Meyer, J. P. & Edwards, M. S.
Partner: UNT Libraries Government Documents Department
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Development of a remote laboratory-scale waste treatment facility

Description: A waste treatment facility, designed on the basis of a feedrate of 1 l/hr of concentrated waste to a spray calciner, has been installed in a radiochemical hot cell at Pacific Northwest Laboratory. The facility includes three modules: feed preparation (storage tanks, evaporator, condenser), waste solidification (a spray calciner and in-can melter), and effluent control (venturi scrubber, cyclone separator, fission product adsorbers, nitrogen oxides destructor, iodine adsorber, HEPA filter, and p… more
Date: June 1, 1980
Creator: Knox, C.A. & Hanson, M.S.
Partner: UNT Libraries Government Documents Department
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GLYCOLIC-FORMIC ACID FLOWSHEET SLUDGE MATRIX STUDY

Description: Testing was completed to demonstrate the viability of the newly developed glycolic acid/formic acid flowsheet on processing in the Defense Waste Processing Facility's (DWPF) Chemical Process Cell (CPC). The Savannah River National Laboratory (SRNL) initiated a sludge matrix study to evaluate the impact of changing insoluble solid composition on the processing characteristics of slurries in DWPF. Four sludge simulants were prepared to cover two compositional ranges in the waste. The first was hi… more
Date: June 30, 2011
Creator: Lambert, D. & Koopman, D.
Partner: UNT Libraries Government Documents Department
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Commercial Demonstration of the Manufactured Aggregate Processing Technology Utilizing Spray Dryer Ash

Description: This quarterly report covers the period from November 14th, 2002 through December 31st, 2002. It covers; mix design development, permitting status, engineering status, construction status, and marketing support activities for this period.
Date: June 1, 2003
Creator: Scandrol, Roy
Partner: UNT Libraries Government Documents Department
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Albany Interim Landfill gas extraction and mobile power system: Using landfill gas to produce electricity. Final report

Description: The Albany Interim Landfill Gas Extraction and Mobile Power System project served three research objectives: (1) determination of the general efficiency and radius of influence of horizontally placed landfill gas extraction conduits; (2) determination of cost and effectiveness of a hydrogen sulfide gas scrubber utilizing Enviro-Scrub{trademark} liquid reagent; and (3) construction and evaluation of a dual-fuel (landfill gas/diesel) 100 kW mobile power station. The horizontal gas extraction syst… more
Date: June 1, 1997
Partner: UNT Libraries Government Documents Department
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Separation of flue-gas scrubber sludge into marketable products. Quarterly technical progress report, March 1, 1996--May 31, 1996

Description: To reduce their sulfur emissions, many coal-fired electric power plants use wet flue-gas scrubbers. These scrubbers convert sulfur oxides into solid sulfate and sulfite sludge, which must then be disposed of. This sludge is a result of reacting limestone with sulfur dioxide to precipitate calcium sulfite and calcium sulfate. It consists of calcium sulfite, gypsum, and unreacted limestone or lime, with miscellaneous objectionable impurities such as iron oxides, silicates, and magnesium, sodium, … more
Date: June 1, 1996
Creator: Kawatra, S. K. & Eisele, T. C.
Partner: UNT Libraries Government Documents Department
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Advanced emissions control development project. Phase I final report appendices, November 1, 1993--February 29, 1996

Description: Appendices are presented on the Advanced Emissions Control Development Project on the following: wet scrubber sampling and analysis; DBA/lime chemical analysis; limestone forced oxidation chemical analysis; benchmarking on baghouse conditions, electrostatic precipitators, and wet scrubber conditions.
Date: June 1, 1996
Creator: Farthing, G.A.
Partner: UNT Libraries Government Documents Department
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Advanced separation technology for flue gas cleanup. Final report, February 1998

Description: The objective of this work by SRI International was to develop a novel system for regenerable SO{sub 2} and NO{sub x} scrubbing of flue gas that focuses on (1) a novel method for regenerating spent SO{sub 2} scrubbing liquor and (2) novel chemistry for reversible absorption of NO{sub x}. High efficiency, hollow fiber contactors (HFCs) were proposed as the devices for scrubbing the SO{sub 2} and NO{sub x} from the flue gas. The system would be designed to remove more than 95% of the SO{sub 2} an… more
Date: June 1, 1998
Creator: Bhown, A. S.; Alvarado, D.; Pakala, N.; Tagg, T.; Riggs, T.; Ventura, S. et al.
Partner: UNT Libraries Government Documents Department
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