IRRADIATION OF 3- SUBSTITUTED-2-PHENYLOXAZIRIDINES
Description:
It was noted previously that 3-(p-dimethylamino)-2-phenyloxaziridine (I) and 3-(p-dimethylamino)-2-(m-nitrophenyl)oxaziridine were photosensitive. Further study on the irradiation (in a variety of solvents under nitrogen) of (I), 2,3-diphenyloxaziridine (II), and 3-(p-nitrophenyl)-2-phenyloxaziridine (III) indicates the major photoreaction to be cleavage to the aldehyde and an intermediate which forms aniline and azobenzene. There is also formed in the photolysis varying amounts of the correspo…
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Date:
August 30, 1967
Creator:
Splitter, Janet S. & Calvin, Melvin.
Item Type:
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UNT Libraries Government Documents Department