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Terrestrial fate of coal-liquid constituents: behavior of alkyl anilines in soil

Description: The low molecular weight aromatic amines (anilines) are important water soluble constituents of coal liquids. The impact of anilines released to the terrestrial environment will largely depend on their mobility and persistence. Studies were conducted to investigate those processes governing the mobility and persistence of the alkylanilines, namely, soil sorption and chemical/microbial degradation. Soil sorption measurements were conducted on aniline and several methyl substituted anilines on A … more
Date: July 1, 1982
Creator: Felice, L. J.; Zachara, J. M. & Rogers, J. E.
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
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Pentamethylcyclopentadienyl and bis(trimethylsilyl)amido complexes of the di- and trivalent lanthanides

Description: The reaction of the divalent iodides YbI/sub 2/ and EuI/sub 2/ with NaN(SiMe/sub 3/)/sub 2/ has provided pentane-soluble, monomeric derivatives of the divalent lanthanides. These compounds are isolated as the solvated species Eu(N(SiMe/sub 3/)/sub 2/)/sub 2/L/sub 2/ (L = thf or 1,2-dme), Yb(N(SiMe/sub 3/)/sub 2/)/sub 2/(thf)/sub 1/ /sub 5/ and Yb(N(SiMe/sub 3/)/sub 2/)/sub 2/L/sub 2/ (L = 1,2-dme or OEt/sub 2/), or as the sodium salts NaM(N(SiMe/sub 3/)/sub 2/)/sub 3/ (M = Eu or Yb). The pentam… more
Date: March 1, 1982
Creator: Tilley, T. D.
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
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Physicochemical Studies of the Carbamate-CO/sub 2/-Solvent System

Description: The formation of carbamate from CO/sub 2/ and the various amine solutions has been investigated for the purpose of elucidating the structure of the species generated in the reaction. The amine solutions used were 1 and 2 molar solutions of di-n-butylamine (DNBA) in triethylamine (TEA), pure DNBA and pure TEA. It has been found that the nonaqueous solvent participates in the formation of carbamate in 1 and 2M-DNBA/TEA solutions as a proton acceptor in DNBA-carbamate formation. However, due to th… more
Date: August 1, 1977
Creator: Prencipe, M. & Ishida, T.
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
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Photodegradation of mutagens in solvent-refined coal liquids

Description: The purpose of this investigation was to evaluate any changes in the chemical composition and microbial mutagenicities of two representative solvent-refined coal (SRC) liquids as a function of exposure time to sunlight and air. This information was desired to assess potential health hazards arising from ground spills of these liquids during production, transport and use. Results of microbial mutagenicity assays using Salmonella typhimurium TA98, conducted after exposure, showed that the mutagen… more
Date: April 1, 1984
Creator: Kalkwarf, D. R.; Stewart, D. L.; Pelroy, R. A. & Weimer, W. C.
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
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Mechanisms for radiation damage in DNA. Progress report, January 1, 1982-December 31, 1982

Description: In this project several mechanisms are proposed for radiation damage to DNA constituents and DNA, and a series of experiments utilizing electron spin resonance spectrometry to test the proposed mechanisms have been detailed. In the past studies have concentrated chiefly on the direct effect of radiation on DNA. We are currently investigating irradiated systems of DNA constituents which may shed light on indirect effects. In addition, studies of radiation effects on lipids have been undertaken w… more
Date: May 1, 1982
Creator: Sevilla, M. D.
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
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Control of catalytic hydrotreating selectivity with ammonia. [Hydrodeoxygenation]

Description: The hydrogenation of naphthalene in the presence of 0, 24, or 48 kPa of ammonia derived from propyl amine was studied during the hydrodeoxygenation (HDO) of dibenzofuran (DBF). A new sample of sulfided NiMo/Al{sub 2}O{sub 3} catalyst at 360{degrees}C, 6.9 MPa total H{sub 2} pressure in a vapor phase tubular reactor was used. As a base-line the HDO of DBF was also studied in the absence of both naphthalene and ammonia. Ammonia inhibited both the HDO of dibenzofuran and the hydrogenation of napht… more
Date: January 1, 1992
Creator: Satterfield, C. N. & Lee, C. M.
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
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Interdisciplinary research and training program in the plant sciences

Description: This document is the compiled progress reports from the Interdisciplinary Research and Training Program in the Plant Sciences funded through the MSU-DOE Plant Research Laboratory. Fourteen reports are included, covering topics such as the molecular basis of plant/microbe symbiosis, cell wall proteins and assembly, gene expression, stress responses, growth regulator biosynthesis, interaction between nuclear and organelle genomes, sensory transduction and tropisms, intracellular sorting and membr… more
Date: January 1, 1991
Creator: Wolk, C.P.
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
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Nuclear medicine program progress report for quarter ending December 31, 1991

Description: This report presents information on (1) a new improved synthesis of carrier-free rhenium-188-labeled Re(V) dimercaptosuccinic acid (DMSA) complex as a potential therapeutic agent for treatment of thyroid medullary carcinoma; and (2) the synthesis and evaluation of a series of iodine-125-labeled analogues of altanserine for imaging of serotonin receptors.
Date: April 1, 1992
Creator: Knapp, F. F., Jr.; Ambrose, K. R.; Callahan, A. P.; McPherson, D. W.; Mirzadeh, S.; Srivastava, P. C. et al.
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
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Hydrogen-Transfer and Charge Transfer in Photochemical and High Energy Radiation Induced Reactions: Effects of Thiols. Final Report, February 1, 1960-January 31, 1979

Description: Absorption of ultraviolet or visible light, or high energy radiation, may lead to highly reactive free radicals. Thiols affect the reactions of these radicals in the following ways: (1) transfer of hydrogen from sulfur of the thiol to a substrate radical, converting the radical to a stable molecule, and the thiol to a reactive thiyl radical; and (2) transfer of hydrogen from a substrate radical or molecule to thiyl, regenerating thiol. The thiol is thus used repeatedly and a single molecule may… more
Date: March 1, 1980
Creator: Cohen, S. G.
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
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Studies of the surface structures of molecular crystals and of adsorbed molecular monolayers on the (111) crystal faces of platinum and silver by low-energy electron diffraction

Description: The structures of molecular crystal surfaces were investigated for the first time by the use of low-energy electron diffraction (LEED). The experimental results from a variety of molecular crystals were examined and compared as a first step towards understanding the properties of these surfaces on a microscopic level. The method of sample preparation employed, vapor deposition onto metal single-crystal substrates at low temperatures in ultrahigh vacuum, allowed concurrent study of the structure… more
Date: January 1, 1977
Creator: Firment, L.E.
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
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Particulate oil shale inhalation and pulmonary inflammatory response in rats

Description: This experiment detrimetal that long-term inhalation of shale dusts by rats elicits a limited inflammatory response in the lung less profound than that observed in animals exposed to equivalent levels of quartz alone. This observation suggests that organic and inorganic constituents of shale may provide a protective effect. The implications for fibrogenic disease are two-fold: (1) inhalation of oil shale dusts appeared to be less detriemtal than the inhalation of quartz along, and (2) there was… more
Date: January 1, 1983
Creator: Wilson, J. S.; Holland, L. M.; Halleck, M. S.; Martinez, E. & Saunders, G.
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
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Some nitrogen-14 NMR studies in solids

Description: The first order quadrupolar perturbation of the /sup 14/N NMR spectrum yields information regarding the static and dynamic properties of the surrounding electronic environment. Signal to noise problems caused by long /sup 14/N longitudinal relaxation times (T/sub 1/) and small equilibrium polarizations are reduced by rotating frame cross polarization (CP) experiments between /sup 14/N and /sup 1/H. Using quadrupolar echo and CP techniques, the /sup 14/N quadrupolar coupling constants (e/sup 2/q… more
Date: November 1, 1983
Creator: Pratum, T. K.
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
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Reverse phase ion-pairing chromatography at pressures up to 345 MPa

Description: The effects of pressure up to 345 MPa (50,000 psi) on a reverse phase ion-pairing system were studied in 50% methanol-water. Retention increased by a factor of 3.2 for methyl orange when the pressure was increased to 241 MPa (30,000 psi) and still larger (not measurable) at 345 MPa (50,000 psi). The retention of methyl red was increased by a factor of 2.2 by pressures of 241 MPa (30,000 psi) and by a factor of 2.5 by 345 MPa (50,000 psi). When the methanol concentration was increased to 75%, re… more
Date: May 1, 1977
Creator: Prukop, G. & Rogers, L. G.
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
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Health and environmental effects of complex chemical mixtures: proceedings

Description: The Office of Health and Environmental Research (OHER) of the Department of Energy supports a broad long-term research program on human health and environmental effects from potential exposure to energy-related complex chemical mixtures. The program seeks basic mechanistic data on the effects of complex mixtures at the cellular, molecular, and whole animal levels to aid in predicting human health effects and seeks ecological data on biological and physical transformations in the mixtures, conce… more
Date: January 1, 1985
Item Type: Refine your search to only Article
Partner: UNT Libraries Government Documents Department
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Recovery of anaerobic digestion after exposure to toxicants. Final report

Description: The concept that methane fermentation cannot tolerate chronic or slug doses of toxicants has almost totally precluded methane fermentation as a viable contender for the treatment of industrial wastewaters. This study assayed a wide variety of toxicants, heavy metals, inorganic salts, organic chemicals, solvents, and antibiotics which are used in industrial processes and, therefore, appear in the industrial wastewaters therefrom. Toxicity was related to the reduction in methane production of a c… more
Date: December 1, 1979
Creator: Yang, J.; Parkin, G. F. & Speece, R. E.
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
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Implementation of the GAUSSIAN 78 programs on the NYU VAX/11-780: a probe into basis set and correlation effects on the structure of molecular complexes. [Complexes of p- and m-hydroxylaniline with formamidinium cation]

Description: The program package is used in a theoretical study of molecular complexes that serve as models of drug receptor interactions. The complexes are of para-hydroxyaniline and meta-hydroxyaniline with formamidinium cation. Results indicate that the description of the nature of interaction obtained at the STO-3G SCF level does not change when the basis set is extended to the 4-31G level or when correlation effects are included to second order in a Moeller-Plesset formulation. 5 figures, 4 tables. (DL… more
Date: April 1, 1980
Creator: Topiol, S; Moskowitz, J W; Osman, R & Weinstein, H
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
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Chemistry of silica in Cerro Prieto brines

Description: The precipitation of amorphous silica from synthetic geothermal brines which resemble the flashed brine at Cerro Prieto has been studied. It was found that part of the dissolved silica quickly polymerizes to form suspended colloidal silica. The colloidal silica flocculates and settles slowly at unmodified brine pH values near 7.35. Raising the pH of the brine to about 7.8 by adding base and stirring for a few minutes causes rapid and complete flocculation and settling. These results have been c… more
Date: April 1, 1980
Creator: Weres, O.; Tsao, L. & Iglesias, E.
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
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Quantitative mammalian cell genetic toxicology: study of the cytotoxicity and mutagenicity of 70 individual environmental agents related to energy technologies and 3 subfractions of a crude synthetic oil in the CHO/HGPRT system. [Hamsters]

Description: Conditions necessary for quantifying mutation-induction to 6-thioguanine resistance, which selects for >98% mutants deficient in the activity of hypoxanthine-guanine phosphoribosyl transferase (HGPRT) in a near-diploid Chinese hamster ovary (CHO) cell line, referred to as CHO/HGPRT system, have been defined. Employing this mutation assay, we have determined the mutagenicity of diversified agents including 11 direct-acting alkylating agents, 16 nitrosamines, 10 heterocyclic nitrogen mustards,… more
Date: January 1, 1978
Creator: Hsie, A. W.; Neill, J. P. & San Sebastian, J. R.
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
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The thermodynamic properties of 2-methylaniline and trans-(R,S)- decahydroquinoline

Description: Measurements leading to the calculation of the ideal-gas thermodynamic properties for 2-methylaniline and trans-(R,S)-decahydroquinoline are reported. Experimental methods included combustion calorimetry, adiabatic heat-capacity calorimetry, comparative ebulliometry, inclined-piston gauge manometry, and differential-scanning calorimetry (dsc). Entropies, enthalpies, and Gibbs energies of formation were derived for the ideal gas at selected temperatures for both compounds. Critical properties we… more
Date: February 1, 1990
Creator: Steele, W. V.; Chirico, R. D.; Nguyen, A. & Knipmeyer, S. E.
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
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Tests of alternative reductants in the second uranium purification cycle

Description: Miniature mixer-settler tests of the second uranium purification cycle show that plutonium cannot be removed by hydroxylamine-hydrazine (NH/sub 2/OH-N/sub 2/H/sub 4/) because the acidity is too high, or by 2,5-di-t-pentylhydroquinone because HNO/sub 3/ oxidizes the hydroquinone. Plutonium can be removed satisfactorily when U(IV)-hydrazine is used as the reductant.
Date: May 1, 1980
Creator: Thompson, M.C.
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
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Chemical characterization and genotoxic potential related to boiling point for fractionally distilled SRC-I coal liquids

Description: This report summarizes selected research efforts oriented toward ameliorating the genotoxic potential of direct coal liquefaction materials through modification or optimization of process conditions. The studies described were conducted to evaluate the utility of optimized distillation for coal liquids from the SRC-I process. SRC-I process solvent was distilled into 50/sup 0/F-range boiling point (bp) cuts. Analysis of amino-PAH (APAH) showed that mutagenic APAHs containing 3 or more rings were… more
Date: July 1, 1982
Creator: Wilson, B. W.; Pelroy, R. A. & Mahlum, D. D.
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
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