1. Mono(annulene)Uranium(4) half-sandwich complexes, 2. Novel syntheses of symmetrically substituted cyclooctatetetraenes
Description: A reproducible, high-yield synthesis of mono(annulene)uranium(4)dichloride (1) is reported, along with the X-ray crystal structural of the bis(pyridine) adduct. Metathesis reactions of the half-sandwich complex 1 with a variety of simple alkyl and alkoxy reagents failed to generate any isolable mono-ring complexes. Reactions of 1 with polydentate, delocalized anions did produce stable derivatives, including mono(annulene)uranium(4)bis(acetylacetonate) (4). An X-ray crystal structure of 4 is reported.
Date: October 1, 1991
Creator: Boussie, T. R.