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EFFECT OF COMPRESSION ON CONDUCTIVITY AND MORPHOLOGY OF PFSA MEMBRANES

Description: Polymer-Electrolyte-Fuel-Cells (PEFCs) are promising candidates for powering vehicles and portable devices using renewable-energy sources. The core of a PEFC is the solid electrolyte membrane that conducts protons from anode to cathode, where water is generated. The conductivity of the membrane, however, depends on the water content of the membrane, which is strongly related to the cell operating conditions. The membrane and other cell components are typically compressed to minimize various contact resistances. Moreover, the swelling of a somewhat constrained membrane in the cell due to the humidity changes generates additional compressive stresses in the membrane. These external stresses are balanced by the internal swelling pressure of the membrane and change the swelling equilibrium. It was shown using a fuel-cell setup that compression could reduce the water content of the membrane or alter the cell resistance. Nevertheless, the effect of compression on the membrane’s transport properties is yet to be understood, as well as its implications in the structure-functions relationships of the membrane. We previously studied, both experimentally and theoretically, how compression affects the water content of the membrane.6 However, more information is required the gain a fundamental understanding of the compression effects. In this talk, we present the results of our investigation on the in-situ conductivity of the membrane as a function of humidity and cell compression pressure. Moreover, to better understand the morphology of compressed membrane, small-angle X-ray-scattering (SAXS) experiments were performed. The conductivity data is then analyzed by investigating the size of the water domains of the compressed membrane determined from the SAXS measurements.
Date: July 20, 2011
Creator: Kusoglu, Ahmet; Weber, Adam; Jiang, Ruichin & Gittleman, Craig
Item Type: Article

The effect of compression on natural graphite anode performance and matrix conductivity

Description: Anodes for lithium-ion cells were constructed from three types of natural graphite, two coated spherical and one flaky. Anode samples were compressed from 0 to 300 kg/cm2 and studied in half-cells to study the relations between anode density, SEI formation and anode cyclability. The C/25 formation of the SEI layer was found to depend on the nature of the graphite and the anode density. Compression of the uncoated graphite lead to an increased conductivity, but only slight improvements in the efficiency of the formation process. Compression of the anodes made from the amorphous-carbon-coated graphites greatly improved both the reversible capacity and first-cycle efficiency. In addition, the fraction of the irreversible charge associated with the surface of the graphite increased with compression, from both an increase in the electrolyte contact as well as compression of the amorphous layer. The cyclability of all of the anodes tended to improve with compression. This suggests that it is the improvement in the conductivity of the anode plays more of a role in the improvement in the cyclability than the formation process.
Date: March 11, 2004
Creator: Striebel, K.A.; Sierra, A.; Shim, J.; Wang, C.-W. & Sastry, A.M.
Item Type: Article

The Effect of Compression Ratio on Knock Limits of High-Performance Fuels in a CFR Engine II : Blends of 2,2,3-Trimethylpentane with 28-R

Description: The knock-limited performance of blends of 0,50; and 100 percent by volume of 2,2,3-trimethylpentane in 28-R fuel determined with a modified F-4 engine at three sets of conditions varying from severe to mild at each of three compression ratios (6.0, 8.0, and 10.0). A comparison of the knock-limited performance of 2,2,3-trimethylpentane with that of triptane (2,2,3-trimethylbutane) is included. The knock-Limited performance of 2,2,3-trimethylpontane was usually more sensitive to either compression ratio or inlet-air temperature than 28-R fuel, but the ratio of the knock-limited indicated mean effective pressure of a given blend containing 2,2,3-trimethypentane and 28-R to the indicated mean effective pressure of 28-R alone was not greatly affected by compression ratio if the engine operating conditions were mild. Although 2,2,3-trimethylpentane in general had a lower knock-limited performance than triptane, the characteristics of the two fuels were somewhat similar.
Date: February 10, 1945
Creator: Tower, Leonard K
Item Type: Report

Effect of Compression Ratio, Pressure, Temperature, and Humidity on Power

Description: Among other factors which affect the horsepower of an airplane engine are the atmospheric pressure, and consequently the altitude at which the engine is working, and the compression ratio, or cylinder volume divided by clearance volume. The tests upon which this report is based were selected from a large number of runs made during the intercomparison of various gasolines to determine the variation of horsepower with altitude at three different compression ratios. The test results and conclusions are presented in this report.
Date: January 1, 1919
Creator: Dickinson, H C; James, W S; Anderson, G V & Brinkerhoff, V W
Item Type: Report

Effect of compressor-outlet bleedoff on turbojet-engine performance

Description: An investigation was conducted in the NACA Lewis altitude wind tunnel to determine the effect of compressor-outlet bleedoff on the performance of an axial-flow turbojet engine equipped with a variable-area exhaust nozzle. Results presented indicate the effect of compressor-outlet bleedoff on performance at altitudes of 25,000 and 40,000 feet and a flight Mach number of 0.53. Variation of performance with bleedoff flow is indicated for operation with fixed- and variable-area exhaust nozzles. Temperature and pressure losses through the bleedoff ducting system are also discussed.
Date: August 7, 1950
Creator: Fleming, William A; Wallner, Lewis E & Wintler, John T
Item Type: Report

Effect of Concrete Waste Form Properties on Radionuclide Migration

Description: Assessing long-term performance of Category 3 waste cement grouts for radionuclide encasement requires knowledge of the radionuclide-cement interactions and mechanisms of retention (i.e., sorption or precipitation) the mechanism of contaminant release, the significance of contaminant release pathways, how waste form performance is affected by the full range of environmental conditions within the disposal facility, the process of waste form aging under conditions that are representative of processes occurring in response to changing environmental conditions within the disposal facility, the effect of waste form aging on chemical, physical, and radiological properties and the associated impact on contaminant release. This knowledge will enable accurate prediction of radionuclide fate when the waste forms come in contact with groundwater. Numerous sets of tests were initiated in fiscal years (FY) 2006-2009 to evaluate (1) diffusion of iodine (I) and technetium (Tc) from concrete into uncontaminated soil after 1 and 2 years, (2) I and rhenium (Re) diffusion from contaminated soil into fractured concrete, (3) I and Re (set 1) and Tc (set 2) diffusion from fractured concrete into uncontaminated soil, (4) evaluate the moisture distribution profile within the sediment half-cell, (5) the reactivity and speciation of uranium (VI) (U(VI)) compounds in concrete porewaters, (6) the rate of dissolution of concrete monoliths, and (7) the diffusion of simulated tank waste into concrete.
Date: September 30, 2009
Creator: Mattigod, Shas V.; Bovaird, Chase C.; Wellman, Dawn M.; Skinner, De'Chauna J.; Cordova, Elsa A. & Wood, Marcus I.
Item Type: Report

Effect of Concrete Wasteform Properties on Radionuclide Migration

Description: The objective of this investigation was to initiate numerous sets of concrete-soil half-cell tests to quantify 1) diffusion of I and Tc from concrete into uncontaminated soil after 1 and 2 years, 2) I and Re (set 1) and Tc (set 2) diffusion from fractured concrete into uncontaminated soil, and 3) evaluate the moisture distribution profile within the sediment half-cell. These half-cells will be section in FY2009 and FY2010. Additionally, 1) concrete-soil half-cells initiated during FY2007 using fractured prepared with and without metallic iron, half of which were carbonated using carbonated, were sectioned to evaluate the diffusion of I and Re in the concrete part of the half-cell under unsaturated conditions (4%, 7%, and 15% by wt moisture content), 2) concrete-soil half cells containing Tc were sectioned to measure the diffusion profile in the soil half-cell unsaturated conditions (4%, 7%, and 15% by wt moisture content), and 3) solubility measurements of uranium solid phases were completed under concrete porewater conditions. The results of these tests are presented.
Date: September 30, 2008
Creator: Wellman, Dawn M.; Bovaird, Chase C.; Mattigod, Shas V.; Parker, Kent E.; Ermi, Ruby M. & Wood, Marcus I.
Item Type: Report

Effect of conductive additives in LiFePO4 cathode for lithium-ion batteries

Description: The electrochemical properties of LiFePO4 cathodes with different carbon contents were studied to find out the role of carbon as conductive additive. LiFePO4 cathodes containing from 0 percent to 12 percent of conductive additive (carbon black or mixture of carbon black and graphite) were cycled at different C rates. The capacity of LiFePO4 cathode increased, as conductive additive content increased. Carbon increased the utilization of active material and the electrical conductivity of electrode, but decreased volumetric capacity of electrode.
Date: November 25, 2003
Creator: Shim, J.; Guerfi, A.; Zaghib, K. & Striebel, K.A.
Item Type: Article

Effect of conductivity between fasteners and aluminum skin on eddy current specimens

Description: The Federal Aviation Administration Airworthiness Assurance Nondestructive Inspection Validation Center (FAA-AANC) and Boeing Commercial Airplane Group are currently developing a study pertaining to the detection of cracks in multi-layered aluminum sheets. The specimen panels model pertinent aspects of the lap splice joints for Boeing 737 aircraft, Line Numbers 292 - 2565. Upon initial characterization of the specimen panels, it became clear that signals produced from a sliding probe at fastener sites were not representative of an in-service lap splice, and therefore, could not be used in a probability of detection experiment. This paper discusses specimen characterization and steps taken to make the specimens useful for nondestructive technology assessment.
Date: April 1, 1997
Creator: Moore, D.G. & Hutchinson, M.C.
Item Type: Article

The effect of connecting-passage diameter on the performance of a compression-ignition engine with a precombustion chamber

Description: Results of motoring tests are presented showing the effect of passage diameter on chamber and cylinder compression pressures, maximum pressure differences, and f.m.e.p. over a speed range from 300 to 1,750 r.p.m. Results of engine performance tests are presented which show the effect of passage diameter on m.e.p., explosion pressures, specific fuel consumption, and rates of pressure rise for a range of engine speeds from 500 to 1,500 r.p.m. The cylinder compression pressure, the maximum pressure difference, and the f.m.e.p. decreased rapidly as the passage diameter increased to 29/64 inch, whereas further increase in passage diameter effected only a slight change. The most suitable passage diameter for good engine performance and operating characteristics was 29/64 inch. Passage diameter became less critical with a decrease in engine speed. Therefore, the design should be based on maximum operating speed. Optimum performance and satisfactory combustion control could not be obtained by means of any single diameter of the connecting passage.
Date: November 1, 1932
Creator: Moore, C S & Collins, J H
Item Type: Report

The effect of continuous weathering on light metal alloys used in aircraft

Description: An investigation of the corrosion of light metal alloys used in aircraft was begun at the National Bureau of Standards in 1925 and has for its purpose causes of corrosion in aluminum-rich and magnesium-rich alloys together with the development of methods for its prevention. The results, obtained in an extensive series of laboratory and weather-exposure tests, reveal the relative durability of a number of commercially available materials and the extent to which the application of various surface coatings of oxide alone and with paint coatings afforded additional protection. The paper may be considered as a supplement to NACA report 490.
Date: January 1, 1939
Creator: Mutchler, Willard
Item Type: Report