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FORTIO: a FORTRAN I/O Interface
A set of OS/370 Basic Assembly Language programs is described which provides a FORTRAN IV interface with OS/370 Macros.
Final Report on the Small-Scale Vapor-Explosion Experiments Using a Molten NaCl-H2O System
Vapor explosions were produced by injecting small quantities of water into a container filled with molten sodium chloride. Minimum explosion efficiencies, as evaluated from reaction-impulse measurements, were relatively large. Subsurface movies showed that the explosions resulted from a two-step sequence: an initial bulk-mixing phase in which the two liquids intermix on a large scale, but remain locally separated by an insulating gas-vapor layer; and a second step, immediately following breakdown of the gas layer, during which the two liquids locally fragment, intermix, and pressurize very rapidly. The experimental results were compared with various mechanistic models that had been proposed to explain vapor explosions. Early models seemed inconsistent with the results. More recent theories suggest that vapor explosions may be caused by a nucleation limit or by dynamic mixing combined with high surface-heat-transfer rates. Both types of models are consistent with the results.
High-Performance Batteries for Off-Peak Energy Storage and Electric-Vehicle Propulsion, Progress Report: July-December 1975
Progress report describing the research and management efforts of Argonne National Laboratory's program on high-performance lithium/metal sulfide batteries during the period July-December 1975. The batteries are being developed for two applications: off-peak energy storage in electric utility networks and electric-vehicle propulsion. The battery designs for the two applications differ, particularly in cell configuration and electrode design because of the differing performance requirements.
Simple Conduction Model with Phase Change for Fuel Pin
A simple conduction model with phase change has been developed for the transient analysis of a fuel pin based on average properties and lumped-parameter techniques. The transient behavior of fuel and cladding can be accurately described by simple analytical expressions that agree with conventional numerical approaches for under-cooling transient analysis. If it be assumed that the heat-transfer resistance between the fuel and cladding remains the same for both steady-state and transient periods, the phase-change problem for fuel and cladding melting can be significantly simplified. BY using the predetermined average overall heat-transfer coefficient across a fuel pin in the steady-state period, the average transient fuel and cladding temperatures can be formulated analytically. For loss of flow at constant power, the start of melting and complete melting for both the fuel and cladding can be estimated with considerable accuracy.
Risk-assessment methodology for fast breeder reactors
The methods applied or proposed for risk assessment of nuclear reactors are reviewed, particularly with respect to their applicability for risk assessment of future commercial fast breeder reactors. All methods are based on the calculation of accident consequences for relatively few accident scenarios. The role and general impact of uncertainties in fast-reactor accident analysis are discussed. The discussion shows the need for improvement of the methodology. A generalized and improved risk-assessment methodology is outlined and proposed (accident-spectra-progression approach). The generalization consists primarily of an explicit treatment of uncertainties throughout the accident progression. The results of this method are obtained in form of consequence distributions. The width and shape of the distributions depend in part on the superposition of the uncertainties. The first moment of the consequence distribution gives an improved prediction of the ''average'' consequence. The higher-consequence moments can be used for consideration of risk aversion. The assessment of the risk of one or a certain number of nuclear reactors can only provide an ''isolated'' risk assessment. The general problem of safety risk assessment and its relation to public acceptance of certain modes of power production is a much broader problem area, which is also discussed.
Measurement of the Hydrogen Yield in the Radiolysis of Water by Dissolved Fission Products
Hydrogen from the radiolysis of water by dissolved fission products is stripped from the solution and collected by bubbling carbon dioxide through the solution. Quantitative measurements of the G value for hydrogen show that the yield is essentially the same as would be obtained by external gamma radiolysis of nonradioactive solutions of the same chemical composition. The hydrogen yield can be enhanced by addition of a hydrogen-atom donor, such as formic acid, to the solution. The yield of hydrogen from fission-waste solutions is discussed with respect to the question of whether it represents a significant energy source.
Studies of Unprotected Loss-of-Flow Accidents for the Clinch River Breeder Reactor
Studies of unprotected loss-of-flow accidents in the CRBR for various rates of flow coast-down and with various options in the SAS 3A code did not lead to conditions for a violent disassembly. Maximum fuel temperatures using the SLUMPY module for disassembly were in the range 4000-4500 deg C. An approximate treatment of the LOF-driven TOP accident, not properly modeled by SAS 3A, indicates the possibility of some increase in accident severity. The effect of fission gas in dispersing fuel was not taken into account in these calculations. Parameter variations included the presence or absence of axial fuel expansion and of clad motion and use of the moving coolant film model versus the static film model. Study of severe pipe rupture accidents with scram indicated that pin power density and fuel-clad conductance were important parameters in determining what coolant flow rate was needed to prevent boiling after the rupture. It appears that for the CRBR when engineering hot channel factors are considered, this fraction would have to exceed 25 percent.
Environmental Research Division Annual Report: Part 2, Center for Human Radiobiology, July 1983 - June 1984
Current status of epidemiological studies of the late effects of internal radium in humans, and mechanistic investigations of those effects.
Nuclear Technology Programs Quarterly Progress Report: July-September 1984
Quarterly report on activities of Argonne National Laboratory's Nuclear Technical Programs, including results of studies to measure the degradation of backfill materials after their exposure to temperature and humidity expected in high-level nuclear waste repositories.
Advanced Thermoplastic Materials for District Heating Piping Systems
The work described in this report represents research conducted in the first year of a three-year program to assess, characterize, and design thermoplastic piping for use in elevated-temperature district heating (DH) systems. The present report describes the results of a program to assess the potential usefulness of advanced thermoplastics as piping materials for use in DH systems.
Chemical Technology Division Annual Technical Report 1985
Highlights of the Chemical Technology (CMT) Division's activities during 1985 are presented. In this period, CMT conducted research and development in areas that include advanced batteries--mainly lithium-alloy/metal sulfide and sodium/sulfur, advanced fuel cells with molten carbonate or solid oxide electrolytes, corrosion-protective coatings for high-strength steel, coal utilization, including the heat and seed recovery technology for coal-fired magnetohydrodynamics plants and the technology for fluidized-bed combustion, methodologies for recovery of energy from municipal waste nuclear technology related to waste management, the recovery processes for discharged fuel and the uranium blanket in a sodium-cooled fast reactor, and proof of breeding in a light water breeder reactor, and physical chemistry of selected materials in environments simulating those of fission and fusion energy systems.
Instability Characteristics of Fluidelastic Instability of Tube Rows in Crossflow
An experimental study is reported to investigate the jump phenomenon in critical flow velocities for tube rows with different pitch-to-diameter ratios and the excited and intrinsic instabilities for a tube row with a pitch-to-diameter ratio of 1.75. The experimental data provide additional insights into the instability phenomena of tube arrays in crossflow.
Site Surveillance and Maintenance Program for Palos Park : Report for 1985
Results of environmental monitoring program conducted at Palos Park.
Experimental Study on Impact/Fretting Wear in Heat Exchanger Tubes
A data bank of field experiences with heat exchanger tube vibration reveals numerous cases of tube failures at, or near, the baffle. The objective of this study is to provide qualitative impact/fretting wear information for heat exchanger tubes through the performance of a series of tests involving the pertinent parameters: impact force level, between the tube and its support; tube to support plate hole clearance; tube support plate thickness; and tube vibration frequency. The characteristics of impact/fretting wear relative to tube motion pattern, material combination and surrounding fluid were also investigated. The test apparatus consists of a cantilevered tube with a simulated tube support plate at the ''free end''. Tube vibration is induced by an electromagnetic exciter to simulate the flow-induced tube motion occurring in a real heat exchanger at the tube/tube support plate interface. Tests are conducted in air, water, and oil, all at room temperature. Wear rate increases significantly with the magnitude of the impact force between the tube and its support plate; the degree and trend of the wear rates are highly dependent on the mechanical and metallurgical properties of the tube/support material combination; the rate of impact/fretting wear decreases with increasing frequency. An empirical formula is proposed to correlate the experimental impact/fretting wear results.
Stability of Tubes Conveying Fluid
Tests and analysis are made for tubes conveying fluid for two types of support conditions. The objectives are to study the characteristics of different types of instability, the transition of one instability mechanism to another, and the control of instability.
The Automated Reasoning System ITP
This report describes a system designed to provide a portable environment for the study of automated reasoning. The system is built on the LMA automated reasoning subroutine package. This program is not part of LMA itself but illustrates the level of inference-based system that can be constructed from the LMA package of tools. It is a clause-based reasoning system supporting a wide variety of techniques which have proven valuable over the years in a long-running automated deduction research project. In addition, it is designed to present a convenient, interactive interface to its user.
A Design Philosophy for Reliable Systems, Including Control
This report develops a framework for a universe of discourse usable by such non-human experts. It is based on the idea that a design has many features of a contract and may be described as a contract between humans and a machine, defining what each must do to attain a goal. Several points are discussed: the use of techniques in analytical redundancy and their place as analogues in administrative control for conventional techniques in physical control; the use of redundant computer systems to protect against hardware faults; the necessity to prove properties of software used in redundant hardware, because software faults are common modes across redundant hardware; and some issues in choosing a programming language for provable control software. Because proof of correctness is costly, it should be used only where necessary. This report concludes that the degree of reliability needed by the plant model used in analytic redundancy protection need not be nearly as reliable as the mechanism to detect discrepancy between plant and model.
DIF3D: A Code to Solve One-, Two-, and Three-Dimensional Finite-Difference Diffusion Theory Problems
The mathematical development and numerical solution of the finite-difference equations are summarized. The report provides a guide for user application and details the programming structure of DIF3D. Guidelines are included for implementing the DIF3D export package on several large scale computers. Optimized iteration methods for the solution of large-scale fast-reactor finite-difference diffusion theory calculations are presented, along with their theoretical basis. The computational and data management considerations that went into their formulation are discussed. The methods utilized include a variant of the Chebyshev acceleration technique applied to the outer fission source iterations and an optimized block successive over-relaxation method for the within-group iterations. A nodal solution option intended for analysis of LMFBR designs in two- and three-dimensional hexagonal geometries is incorporated in the DIF3D package and is documented in a companion report, ANL-83-1.
Chemical Engineering Division Annual Technical Report 1981
Highlights of the Chemical Engineering (CEN) Division's activities during 1981 are presented. In this period, CEN conducted research and development in the following areas: rechargeable lithium-alloy/iron sulfide batteries for electric vehicles and other applications, aqueous batteries--improved lead-acid, nickel/zinc, and nickel/iron--for electric vehicles, as well as advanced lead-acid batteries for electric.-utility load leveling, energy-efficient industrial electrochemical processes, molten carbonate fuel cells for use by electric utilities, coal technology, mainly fluidized-bed combustion of coal in the presence of an SO2 sorbent of limestone, heat- and seed-recovery technology for open-cycle magnetohydrodynamic systems.
Advanced Fuel Cell Development Progress Report: October-December 1981
Quarterly report discussing fuel cell research and development work at Argonne National Laboratory (ANL). This report describes efforts directed toward (1) improving understanding of component behavior in molten carbonate fuel cells and (2) developing alternative materials and concepts for components. The principal focus was changed during this period from the development of cathodes fabricated from NiO and electrolyte supports of sintered y-LiA102 to an investigation of NiO cathode dissolution and deposition and a search for alternative cathode materials.
Proceedings of the NEANDC/NEACRP Specialists Meeting on Fast-Neutron Capture Cross Sections
This proceedings contains the summaries and contents of a number of papers presented at the 1982 NEANDC/NEACRP specialists meeting on fast-neutron capture cross sections. The table of contents has been summarized to provide a sketch of the topical matter.
Atmospheric Corrosion of batten and Enclosure Materials for Flat-Plate Solar Collectors
As part of the Solar Reliability and Materials Program at Argonne National Laboratory, the atmospheric corrosion of candidate batten and enclosure materials were tested on outdoor racks parallel to the tilted solar-collected panels at nine National Solar Data Network (NSDN) sites, located in mild marine, mild industrial, and rural environments. The candidate materials evaluated include galvanized steel (G-90), aluminized steel (Type 2), aluminum (6061), and white polyester painted steel. Data analyses predicted that all the first three materials will last more than 20 years in the nine sites tested. However, repainting of the painted steel is probably needed within five years in a mild marine environment and five to ten years in a mild industrial or rural environment.
Metal Corrosion Associated with Thermal Cycling of Inhibited and Uninhibited Propylene Glycol/Water Solution in Solar DHW Systems
As part of the Solar Reliability and Materials Program at Argonne National Laboratory, metal corrosion associated with thermal cycling at 82 C circulating and 176 C stagnating temperatures of propylene glycol and ASTM corrosive water mixture (50% v/o) was investigated. Preliminary data indicate that in a mixed metal system of copper, steel, and aluminum specimens stagnating together in a glycol solution, the copper randomly pits and the pitting stops when the pit depth extends to about 1-1/2 mil. The addition of 1% molybdate as an inhibitor to the glycol solution is slightly beneficial for steel, but the added expense of adding and maintaining the concentration of an inhibitor may not be warranted. Dissolved copper rapidly deposits on the aluminum surface and promotes severe galvanic corrosion.
TCLUST1: A Computer Program for Analysis of Intersubassembly Heat Transfer in an LMFBR
The TCLUST1 computer program was developed to study the transient thermal behavior of a subassembly of a liquid-metal fast breeder reactor (LMFBR) that is thermally coupled to its six neighboring subassemblies. Each of the seven subassemblies may be either a reflector subassembly, which contains a single solid hexagonal rod, or a pin-bundle subassembly. The TCLUST1 analytical model was developed based on conservation of energy, and the temperature distribution in the subassembly was obtained using the successive over-relaxation (SOR) technique. Measured temperatures obtained from a natural-convection flow test performed in EBR-II compare well with those predicted by TCLUST1. Appendixes describe the code input and go through a sample program.
Laboratory Testing of Glasses for Lockheed Idaho Technology Co. Fiscal Year 1994 Report
The purpose of this project is to measure the intermediate and long-term durability of vitrified waste forms developed by Lockheed Idaho Technology Co. (LITCO) for the immobilization of calcined radioactive wastes at Idaho National Engineering Laboratory. Two vitreous materials referred to as Formula 127 and Formula 532, have been subjected to accelerated durability tests to measure their long-term performance. Formula 127 consists of a glass matrix containing 5-10 vol % fluorite (CaF2) as a primary crystalline phase. It shows low releases of glass components to solution in 7-, 28-, 70-, and 140-day Product Consistency Tests performed at 2000 m⁻¹ at 90 C. In these tests, release rates for glass-forming components were similar to those found for durable waste glasses. The Ca and F released by the glass as it corrodes appear to re-precipitate as fluorite. Formula 532 consists of a glass matrix containing 5-10 vol % of an Al-Si-rich primary crystalline phase. The release rates for components other than aluminum are relatively low, but aluminum is released at a much higher rate than is typical for durable waste glasses. Secondary crystalline phases form relatively early during the corrosion of Formula 532 and appear to consist almost entirely of the Al-Si-rich primary phase (or a crystal with the same Al:Si ratio) and a sodium-bearing zeolite. Future test results are expected to highlight the relative importance of primary and secondary crystalline phases to the rate of corrosion of Formula 127 and Formula 532.
Some Software Implementations of the Functions Sine and Cosine
We present several software implementations of the elementary functions sin and cos designed to fit a large class of machines. Implementation details are provided. We also provide a detailed error analysis that bounds the errors of these implementations, over the full range of input arguments, from 0.721 to 0.912 units in the last place. Tests performed on these codes give results that are consistent with the error bounds.
Surveillance of Site A and Plot M : Report for 1989
The results of the environmental monitoring program conducted at Site A/Plot M in the Palos Park Forest Preserve area for CY 1989 are presented. The monitoring program is the ongoing remedial action that resulted from the 1976-1978 radiological characterization of the site. That study had determined that very low levels of hydrogen-3 (as tritiated water) migrated from the burial ground and was present in two nearby hand-pumped picnic wells. The current program consists of sample collection and analysis of air, surface and subsurface water, and bottom sediment.
Argonne National Laboratory-East Site Environmental Report for Calendar Year 1989
This report discusses the results of the environmental monitoring program at Argonne National Laboratory (ANL) for 1989. To evaluate the effects of ANL operations on the environment, samples of environmental media collected on the site, at the site boundary, and off the ANL site were analyzed and compared. A variety of radionuclides were measured in air, surface water, groundwater, soil, grass, bottom sediment, and milk samples.
Fluidized-Bed Regeneration of Sulfated Dolomite from a Coal-Fired FBC Process by Reductive Decomposition
A fluidized-bed, reductive decomposition process has been developed for regenerating calcium sulfate, a product of fluidized-bed combustion. The effect of process operating variables on the extent of regeneration and on the SO2 levels in the off-gas has been determined, and a process model has been proposed. A process for regenerating spent SO2 sorbents has been developed on a PDU scale. Tymochtee dolomite that had been sulfated during fluidized-bed combustion of coal is regenerated (reductive decomposition of calcium sulfate to calcium oxide and SO2) by the incomplete combustion of either methane or coal in a fluidized-bed reactor.
High-Performance Batteries for Off-Peak Energy Storage and Electric-Vehicle Propulsion, Progress Report: October-December 1976
Quarterly report on batteries being developed for electric-vehicle propulsion and for stationary energy storage applications.
Engineering Analysis of Thermal Phenomena for Lead-Acid Batteries During Recharge Processes
Transient thermal phenomena in Pb/PbO2 (lead-acid) batteries during charging processes were investigated. Mathematical models were formulated for the studies of heat transfer behavior across the electrode/electrolyte interface within a porous PbO2 electrode during charging, thermal behavior and temperature distribution over a lead-acid battery during different charging processes designed for electric-vehicle propulsion application, and cooling methods for lead-acid batteries during recharge cycles. Numerical solutions show that the heat transfer across the solid electrode and the electrolyte within the porous electrode is so fast that their temperatures may be regarded as the same. The results also show that, in a lead-acid battery designed for electric-vehicle propulsion, the heat generated in the cell during fast charging processes may cause a noticeable rise of temperature in the cell if the heat is not removed properly. The studies of heat-removal processes indicate that incorporation of cooling tubes within the cell cannot effectively remove the heat being released from the cell. However, the heat may be removed effectively by circulation of electrolyte through the battery. Numerical solutions are provided for the engineering evaluation of heat-removal design during battery cycling processes.
Proceedings of the Focused Research Program on Spectral Theory and Boundary Value Problems, Vol. 3: Linear Differential Equations and Systems
The third volume of a series of reports containing the proceedings of the Focused Research Program on "Spectral Theory and Boundary Value Problems."
Some Issues Concerning Fluidelastic Instability of a Group of Circular Cylinders in Crossflow
Since the early 1970s, extensive studies of fluid-elastic instability of circular cylinders in crossflow have been reported. A significant understanding of the phenomena involved now exists. However, some confusion, misunderstanding, and misinterpretation still remain. The objective of this report is to discuss, on the basis of the current state of the art, a series of the most asked questions. Emphasis is placed on the determination of the critical flow velocity, non-dimensional parameters, stability criteria, and instability mechanisms.
A Formal Model for Verification of Abstract Properties
This report is given a specification "s" that states the requirements of a problem in terms of data dependencies. There are also given some assumptions about the input domain and to define a formal model that can be used to verify that a program written according to the specification "s" does indeed have the data dependencies specified by "s."
GenoGraphics for OpenWindows
GenoGraphics is a generic utility for constructing and querying one-dimensional linear plots. The outgrowth of a request from Dr. Cassandra Smith for a tool to facilitate her genome mapping research. GenoGraphics development has benefited from a continued collaboration with her. Written in Sun Microsystem's OpenWindows environment and the BTOL toolkit developed at Argonne National Laboratory. GenoGraphics provides an interactive, intuitive, graphical interface. Its features include: viewing multiple maps simultaneously, zooming, and querying by mouse clicking. By expediting plot generation, GenoGraphics gives the scientist more time to analyze data and a novel means for deducing conclusions.
Dynamic Stability of Maglev Systems
Because dynamic instability is not acceptable for any commercial maglev systems, it is important to consider this phenomenon in the development of all maglev systems. This study considers the stability of maglev systems based on experimental data, scoping calculations, and simple mathematical models. Divergence and flutter are obtained for coupled vibration of a three-degree-of-freedom maglev vehicle on a guideway consisting of double L-shaped aluminum segments attached to a rotating wheel. The theory and analysis developed in this study identifies basic stability characteristics and future research needs of maglev systems.
Dynamic Stability Experiment of Maglev Systems
This report summarizes the research performed on Maglev vehicle dynamic stability at Argonne National Laboratory during the past few years. It also documents magnetic-force data obtained from both measurements and calculations. Because dynamic instability is not acceptable for any commercial Maglev system, it is important to consider this phenomenon in the development of all Maglev systems. This report presents dynamic stability experiments on Maglev systems and compares their numerical simulation with predictions calculated by a nonlinear dynamic computer code. Instabilities of an electrodynamic system (EDS)-type vehicle model were obtained from both experimental observations and computer simulations for a five-degree-of-freedom Maglev vehicle moving on a guideway consisting of double L-shaped aluminum segments attached to a rotating wheel. The experimental and theoretical analyses developed in this study identify basic stability characteristics and future research needs of Maglev systems.
Color Measurements on Marble and Limestone Briquettes Exposed to Outdoor Environment in the Eastern United States
In a long-term program that began in 1984, limestone and marble briquettes have been exposed to both anthropogenic acid deposition and natural weathering at four field sites in the eastern United States.
The Effect of Pressure on the Transient Swelling Rate of Oxide Fuel
An analysis of the transient swelling rate of oxide fuel, based on fission-gas bubble conditions calculated with the FRAS3 code, has been developed and implemented in the code. The need for this capability arises in the coupling of the FRAS3 fission-gas analysis code to the FPIN fuel-pin mechanics code. An efficient means of closely coupling the calculations of swelling strains and stresses between the modules is required. The present analysis provides parameters that allow the FPIN calculation to proceed through a fairly large time step, using estimated swelling rates, to calculate the stresses. These stress values can then be applied in the FRAS3 detailed calculation to refine the swelling calculation, and to provide new values for the parameters to estimate the swelling in the next time step. The swelling rates were calculated for two representative transients and used to estimate swelling over a short time period for various stress levels.
HYCSOS : A Chemical Heat Pump and Energy Conversion System Based on Metal Hydrides
The current status of the HYCSOS chemical heat pump and energy conversion system based on metal hydrides is described. Heat transfer fluid loops were insulated and modified for isothermal operation. Software development for HYCSOS manual mode operation was completed. Routines to handle data acquisition, logging, compression, correction and plotting, using a Tektronix Graphics system with flexible disk data storage, provide a rapid and versatile means of presenting HYCSOS data for analysis. Advanced concept heat exchangers to improve the heat transfer of the hydride bed with the heat transfer fluid are discussed. Preliminary tests made with a LaNi5 loaded aluminum foam test unit showed that heat transfer properties are very markedly improved. Thermodynamic expressions are applied to the selection of alloys for use in HYCSOS. The substitution of aluminum for nickel in AB5 type alloys is shown to reduce hysteresis and permits the use of potentially lower cost materials with added flexibility for the optimization of engineering design and performance characteristics of the hydride heat pump system. Transient thermal measurements on hydride beds of CaNi5 and LaNi5 show no deterioration with cycling. Relatively slow heat transfer between the hydride beds and heat transfer fluid in the coiled tube heat exchangers is indicated by temperature lag of the bed and heat transfer fluid. Improved heat transfer is anticipated with aluminum foam heat exchangers.
Waste Production and Management at EBR-II
This report surveys waste production rates and disposal practices at EBR-II, a small-scale liquid-metal fast breeder reactor, for the past decade. Normal airborne wastes have been reduced by switching to low-sulfur fuel oil in auxiliary boilers and converting to use of reactor steam for part of the plant space heating. Atmospheric releases of gaseous radioactive wastes initially increased during the implementation of program for testing reactor fuels to and beyond cladding breach; but the effluent rates have now been reduced to far below permissible limits by use of a cryogenic distillation column. EBR-II's small production of liquid radioactive waste is handled by evaporation, followed by disposal of the evaporator sludge as solid waste. Liquid-waste releases meet all applicable state and federal standards. Solid wastes are sent to two storage/disposal areas- one of which is reserved primarily for storage of materials containing sodium, pending development of a facility for disposal of the sodium.
Logic Machine Architecture Inference Mechanisms: Layer 2 User Reference Manual Release 2.0
Logic Machine Architecture (LMA) is a package of software tools for the construction of inference-based systems. This document is the reference manual for layer 2 of LMA. It contains the information necessary to write LMA-based systems at the level of layer 3. Such systems include theorem provers, reasoning components for expert systems, and customized deduction components for a variety of application systems.
The Utility Subroutine Package Used by Applied Physics Division Export Codes
This report describes the current state of the utility subroutine package used with codes being developed by the staff of the Applied Physics Division. The package provides a variety of useful functions for BCD input processing, dynamic core-storage allocation and management, binary I/O and data manipulation. The routines were written to conform to coding standards which facilitate the exchange of programs between different computers.
Analysis of an Internally Pressurized Prismatic Cell Can
This report contains an elastic stress and displacement analysis of a prismatic cell can subjected to internal pressure. A computer program was written to perform the analysis. The results show that, for the geometry chosen, the thicknesses of the cell-can walls and the magnitude of the internal pressure are the most important parameters that determine the stresses and deformations of the cell can. Recommendations for future studies are included.
Development of Advanced Batteries at Argonne National Laboratory : Summary Report for 1979
A summary for 1979 of Argonne National Laboratory's program on the development of advanced batteries is presented. These batteries are being developed for electric-vehicle propulsion and stationary energy-storage applications. The principal cells under investigation at present are of a vertically oriented, prismatic design with one or more inner positive electrodes of FeS or FeS2, facing negative electrodes of Li-Al alloy, and molten LiCl-KCl electrolyte; the cell operating temperature is 400 to 500 degrees C. A small effort on the development of a calcium/metal sulfide cell is also being conducted.
Flow Enhancement of Annulus Damping
Significant increases in flow damping were observed for a tube passing through a plate when a sharp-edge raised-diameter constriction was added to the hole in a plate subject to a constant pressure drop. A correlation of the data in the form of a concentrated viscous damper (dashpot) is given which will be useful in structural dynamic analysis.
An Assessment of the Performance of Heat Exchanger Materials in Fluidized-Bed Combustors
The work described in this report represents research conducted in the first year of a three-year program to assess, characterize, and design thermoplastic piping for use in elevated-temperature district heating (DH) systems. The present report describes the results of a program to assess the potential usefulness of advanced thermoplastics as piping materials for use in DH systems. This includes the review of design rules for thermoplastic materials used as pipes, a survey of candidate materials and available mechanical properties data, and mechanical properties testing to obtain baseline data on a candidate thermoplastic material extruded as pipe.
Investigation of Primary Li-Si/FeS2 Cells
The factors that limit the performance of thermally activated Li-Si/FeS2 batteries were defined through the use of electrochemical characterization tests and post-test examinations. For the characterization tests, 82 individual cells were instrumented with multiple voltage sensors and discharged under isothermal and isobaric conditions. The voltage data for the sensors were recorded to determine the ohmic and electrochemical impedances of each cell component at different levels of discharge. The data analysis completed to date has demonstrated that this approach can successfully differentiate the influence of various operating parameters (e.g., temperature, current density), electrode structures (e.g., FeS2 particle size), and additives on cell capacity, specific energy, and power capability. Thirty cells selected from these tests and additional tests at SNL were examined using optical and scanning electron microscopy, energy dispersive spectroscopy, and X-ray diffraction. These analyses documented microstructural and compositional changes in the active materials and electrolyte. In general, the electrochemical impedance of the FeS2 electrode limited cell performance. Several methods (including use of fine FeS2 particle size, graphite additions, and higher operating temperatures) produced measurable reductions in this impedance and yielded significant improvements in specific energy and power. Additions of KCl to the negative electrode extended the low-temperature capacity of this electrode by counterbalancing gradients in electrolyte composition that develop during discharge.
Site Surveillance and Maintenance Program for Palos Park : Report for 1986
The results of the environmental monitoring program conducted at Site A/Plot M in the Palos Park Forest Preserve area for CY 1986 are presented. The monitoring program is the ongoing remedial action that resulted from the original radiological characterization of the site. The program consists of sample collection and analysis of air, surface and subsurface water, and bottom sediment to determine the migration pathway of water from the burial ground (Plot M) to hand-operated picnic wells, establish if buried radionuclides other than hydrogen-3 have migrated, and generally characterize the radiological environment of the area.
TRUEX Hot Demonstration
In FY 1987, a program was initiated to demonstrate technology for recovering transuranic (TRU) elements from defense wastes. This hot demonstration was to be carried out with solution from the dissolution of irradiated fuels. This recovery would be accomplished with both PUREX and TRUEX solvent extraction processes. Work planned for this program included preparation of a shielded-cell facility for the receipt and storage of spent fuel from commercial power reactors, dissolution of this fuel, operation of a PUREX process to produce specific feeds for the TRUEX process, operation of a TRUEX process to remove residual actinide elements from PUREX process raffinates, and processing and disposal of waste and product streams. This report documents the work completed in planning and starting up this program. It is meant to serve as a guide for anyone planning similar demonstrations of TRUEX or other solvent extraction processing in a shielded-cell facility.
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