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ELECTROMOTIVE FORCE, EMF (CELLS)

Description: The voltage or electric potential difference across the terminals of a cell when no current is drawn from it. The emf of a cell is the sum of the electric potential differences (PDs) produced by a separation of charges (electrons or ions) that can occur at each phase boundary (or interface) in the cell. The magnitude of each PD depends on the chemical nature of the two contacting phases. Thus, at the interface between two different metals, some electrons will have moved from the metal with a higher free energy of electrons to the metal with a lower free energy of electrons. The resultant charge separation will produce a PD (just as charge separation produces a voltage across a capacitor) that, at equilibrium, exactly opposes further electron flow. Similarly, PDs can be produced when electrons partition across a metal/solution interface or metal/solid interface, and when ions partition across a solution/membrane/solution interface.
Date: September 16, 1998
Creator: Archer, M. D. & Feldberg, S. W.

Optical apparatus and method for sensing uranyl

Description: An optical sensing device for uranyl and other substances, a method for making an optical sensing device and a method for chemically binding uranyl and other indicators to glass, quartz, cellulose and similar substrates. The indicator, such as arsenazo III, is immobilized on the substrate using a chemical binding process. The immobilized arsenazo III causes uranyl from a fluid sample to bind irreversibly to the substrate at its active sites, thus causing absorption of a portion of light transmitted through the substrate. Determination of the amount of light absorbed, using conventional means, yields the concentration of uranyl present in the sample fluid. The binding of uranyl on the substrate can be reversed by subsequent exposure of the substrate to a solution of 2,6-pyridinedicarboxylic acid. The chemical binding process is suitable for similarly binding other indicators, such as bromocresol green.
Date: January 1, 1994
Creator: Baylor, L.C. & Buchanan, B.R.

Composition for detecting uranyl

Description: The present invention relates to an indicator composition for use in spectrophotometric detection of a substance in a solution, and a method for making the composition. Useful indicators are sensitive to the particular substance being measured, but are unaffected by the fluid and other chemical species that may be present in the fluid. Optical indicators are used to measure the uranium concentration of process solutions in facilities for extracting uranium from ores, production of nuclear fuels, and reprocessing of irradiated fuels. The composition comprises an organohalide covalently bonded to an indicator for the substance, in such a manner that the product is itself an indicator that provides increased spectral resolution for detecting the substance. The indicator is preferably arsenazo III and the organohalide is preferably cyanuric chloride. These form a composition that is ideally suited for detecting uranyl.
Date: January 1, 1994
Creator: Baylor, L.C. & Stephens, S.M.

Method for verification of constituents of a process stream

Description: This invention is comprised of a method for validating a process stream for the presence or absence of a substance of interest such as a chemical warfare agent; that is, for verifying that a chemical warfare agent is present in an input line for feeding the agent into a reaction vessel for destruction, or, in a facility for producing commercial chemical products, that a constituent of the chemical warfare agent has not been substituted for the proper chemical compound. The method includes the steps of transmitting light through a sensor positioned in the feed line just before the chemical constituent in the input line enters the reaction vessel, measuring an optical spectrum of the chemical constituent from the light beam transmitted through it, and comparing the measured spectrum to a reference spectrum of the chemical agent and preferable also reference spectra of surrogates. A signal is given if the chemical agent is not entering a reaction vessel for destruction, or if a constituent of a chemical agent is added to a feed line in substitution of the proper chemical compound.
Date: January 1, 1993
Creator: Baylor, L.C.; Buchanan, B.R. & O`Rourke, P.E.

Method for compression of data using single pass LZSS and run-length encoding

Description: A method used preferably with LZSS-based compression methods for compressing a stream of digital data. The method uses a run-length encoding scheme especially suited for data strings of identical data bytes having large run-lengths, such as data representing scanned images. The method reads an input data stream to determine the length of the data strings. Longer data strings are then encoded in one of two ways depending on the length of the string. For data strings having run-lengths less than 18 bytes, a cleared offset and the actual run-length are written to an output buffer and then a run byte is written to the output buffer. For data strings of 18 bytes or longer, a set offset and an encoded run-length are written to the output buffer and then a run byte is written to the output buffer. The encoded run-length is written in two parts obtained by dividing the run length by a factor of 255. The first of two parts of the encoded run-length is the quotient; the second part is the remainder. Data bytes that are not part of data strings of sufficient length are written directly to the output buffer.
Date: January 1, 1994
Creator: Berlin, G.J.

RPM-SIM (Renewable Energy Power System Modular Simulator) user's guide

Description: Using the VisSimTM visual environment, researchers developed a modular simulation system to facilitate an application-specific, low-cost study of the system dynamics for wind-diesel hybrid power systems. This manual presents the principal modules of the simulator and, using case studies of a hybrid system, demonstrates some of the benefits that can be gained from understanding the effects of the designer's modifications to these complex dynamic systems.
Date: November 15, 1999
Creator: Bialasiewicz, J.T.; Muljadi, E.; Nix, G.R. & Drouilhet, S.

Vitrification of organics-containing wastes

Description: A process for stabilizing organics-containing waste materials and recovery metals therefrom, and a waste glass product made according to the process are described. Vitrification of wastes such as organic ion exchange resins, electronic components and the like can be accomplished by mixing at least one transition metal oxide with the wastes, and, if needed, glass formers to compensate for a shortage of silicates or other glass formers in the wastes. The transition metal oxide increases the rate of oxidation of organic materials in the wastes to improve the composition of the glass-forming mixture: at low temperatures, the oxide catalyzes oxidation of a portion of the organics in the waste; at higher temperatures, the oxide dissolves and the resulting oxygen ions oxidize more of the organics; and at vitrification temperatures, the metal ions conduct oxygen into the melt to oxidize the remaining organics. In addition, the transition metal oxide buffers the redox potential of the glass melt so that metals such as Au, Pt, Ag, and Cu separate form the melt in the metallic state and can be recovered. After the metals are recovered, the remainder of the melt is allowed to cool and may subsequently be disposed of. The product has good leaching resistance and can be disposed of in an ordinary landfill, or, alternatively, used as a filler in materials such as concrete, asphalt, brick and tile.
Date: January 1, 1995
Creator: Bickford, D.F.

Purge water management system

Description: A purge water management system is described for effectively eliminating the production of purge water when obtaining a groundwater sample from a monitoring well. In its preferred embodiment, the purge water management system comprises an expandable container, a transportation system, and a return system. The purge water management system is connected to a wellhead sampling configuration, typically permanently installed at the well site. A pump, positioned with the monitoring well, pumps groundwater through the transportation system into the expandable container, which expands in direct proportion with volume of groundwater introduced, usually three or four well volumes, yet prevents the groundwater from coming into contact with the oxygen in the air. After this quantity of groundwater has been removed from the well, a sample is taken from a sampling port, after which the groundwater in the expandable container can be returned to the monitoring well through the return system. The purge water management system prevents the purge water from coming in contact with the outside environment, especially oxygen, which might cause the constituents of the groundwater to oxidize. Therefore, by introducing the purge water back into the monitoring well, the necessity of dealing with the purge water as a hazardous waste under the Resource Conservation and Recovery Act is eliminated.
Date: January 1995
Creator: Cardoso-Neto, J. E. & Williams, D. W.

Method for extracting metals from aqueous waste streams for long term storage

Description: A liquid-liquid extraction method for removing metals and hydrous metal colloids from waste streams is provided wherein said waste streams are contacted with a solvent system containing a water-in-oil microemulsion wherein the inverted micelles contain the extracted metal. A silicon alkoxide, either alone or in combination with other metal alkoxide compounds is added to the water-in-oil microemulsion, thereby allowing encapsulation of the extracted metal within a silicon oxide network. Lastly, the now-encapsulated metal is precipitated from the water-in-oil microemulsion phase to yield aggregates of metal-silicate particles having average. individual particle sizes of approximately 40 manometers.
Date: January 1, 1993
Creator: Chaiko, D.J.

Starting apparatus for internal combustion engines

Description: This report is a patent description for a system to start an internal combustion engine. Remote starting and starting by hearing impaired persons are addressed. The system monitors the amount of current being drawn by the starter motor to determine when the engine is started. When the engine is started the system automatically deactivates the starter motor. Five figures are included.
Date: January 1, 1995
Creator: Dyches, G.M. & Dudar, A.M.

Method of making multilayered titanium ceramic composites

Description: A method making a titanium ceramic composite involves forming a hot pressed powder body having a microstructure comprising at least one titanium metal or alloy layer and at least one ceramic particulate reinforced titanium metal or alloy layer and hot forging the hot pressed body follwed by hot rolling to substantially reduce a thickness dimension and substantially increase a lateral dimension thereof to form a composite plate or sheet that retains in the microstructure at least one titanium based layer and at least one ceramic reinforced titanium based layer in the thickness direction of the composite plate or sheet.
Date: August 25, 1998
Creator: Fisher, George T., II; Hansen; S., Jeffrey; Oden; L., Laurance; Turner et al.

Apparatus and method for two-stage oxidation of wastes

Description: An apparatus and method for oxidizing wastes in a two-stage process. The apparatus includes an oxidation device, a gas-liquid contacting column and an electrocell. In the first stage of the process, wastes are heated in the presence of air to partially oxidize the wastes. The heated wastes produce an off-gas stream containing oxidizable materials. In the second stage, the off-gas stream is cooled and flowed through the contacting column, where the off-gas stream is contacted with an aqueous acid stream containing an oxidizing agent having at least two positive valence states. At least a portion of the oxidizable materials are transferred to the acid stream and destroyed by the oxidizing agent. During oxidation, the valence of the oxidizing agent is decreased from its higher state to its lower state. The acid stream is flowed to the electrocell, where an electric current is applied to the stream to restore the oxidizing agent to its higher valence state. The regenerated acid stream is recycled to the contacting column.
Date: September 28, 1993
Creator: Fleischman, S. D.

Biocarrier composition for and method of degrading pollutants

Description: The present invention relates to biocarrier compositions that attract and bond pollutant-degrading antigens that will degrade the pollutants. Biocarriers are known generally as a variety of inert or semi-inert compounds or structures having the ability to sequester (attract), hold and biomagnify (enhance) specific microorganisms within their structure. Glass or polystyrene beads are the most well known biocarriers. The biocarrier, which is preferably in the form of glass microspheres, is coated with an antibody or group of antibodies that attract and react specifically with certain pollutant-degrading antigens. The antibody, once bonded to the biocarrier, is used by the composition to attract and bond those pollutant-degrading antigens. Each antibody is specific for an antigen that is specific for a given pollutant. The resulting composition is subsequently exposed to an environment contaminated with pollutants for degradation. In the preferred use, the degrading composition is formed and then injected directly into or near a plume or source of contamination.
Date: January 1, 1994
Creator: Fliermans, C.B.

Use of serospecific biocarrier compositions for enhanced biodegradation and bioremediation of groundwater

Description: A composition and method for using the composition for degrading pollutants in-situ is presented. The composition comprises a biocarrier coated with an antigen-specific antibody that attracts and binds pollution-degrading antigens. The biocarrier, which is preferably in the form of glass microspheres, is coated with one or more strains of antibody. The antibody may be placed into the ground in or near the source of pollutants where it may attract antigens present and bind them, or the antibodies may be first exposed to the antigens and then placed in the ground. Alternatively, the coated biocarriers may be used to degrade pollutants in ground water pumped to the surface and through a biofilter containing the biocarriers. The remediated groundwater can then be returned to the soil.
Date: January 1, 1995
Creator: Fliermans, C.B.

Fiber optic signal amplifier using thermoelectric power generation

Description: A remote fiber optic signal amplifier for use as a repeater/amplifier, such as in transoceanic communication, powered by a Pu{sub 238} or Sr{sub 90} thermoelectric generator. The amplifier comprises a unit with connections on the receiving and sending sides of the communications system, and an erbium-doped fiber amplifier connecting each sending fiber to each receiving fiber. The thermoelectric generator, preferably a Pu{sub 238} or Sr{sub 90} thermoelectric generator delivers power to the amplifiers through a regulator. The heat exchange surfaces of the thermoelectric generator are made of material resistant to corrosion and biological growth and are directly exposed to the outside, such as the ocean water in transoceanic communications.
Date: January 1, 1993
Creator: Hart, M.M.

Bioremediation of contaminated groundwater

Description: Disclosed is an apparatus and method for in situ remediation of contaminated subsurface soil or groundwater contaminated by chlorinated hydrocarbons. A nutrient fluid (NF) is selected to simulated the growth and reproduction of indigenous subsurface microorganisms capable of degrading the contaminants; an oxygenated fluid (OF) is selected to create an aerobic environment with anaerobic pockets. NF is injected periodically while OF is injected continuously and both are extracted so that both are drawn across the plume. NF stimulates microbial colony growth; withholding it periodically forces the larger, healthy colony of microbes to degrade the contaminants. Treatment is continued until the subsurface concentration of contaminants is acceptable. NF can be methane and OF be air, for stimulating production of methanotrophs to break down chlorohydrocarbons, especially TCE and tetrachloroethylene.
Date: January 1, 1994
Creator: Hazen, T.C. & Fliermans, C.B.

Immersible solar heater for fluids

Description: An immersible solar heater is described comprising a light-absorbing panel attached to a frame for absorbing heat energy from the light and transferring the absorbed heat energy directly to the fluid in which the heater is immersed. The heater can be used to heat a swimming pool, for example, and is held in position and at a preselected angle by a system of floats, weights and tethers so that the panel can operate efficiently. A skid can be used in one embodiment to prevent lateral movement of the heater along the bottom of the pool. Alternative embodiments include different arrangements of the weights, floats and tethers and methods for making the heater.
Date: January 1, 1994
Creator: Hazen, T.C. & Fliermans, C.B.

Hydraulic pump with in-ground filtration and monitoring capability

Description: A hydraulically operated pump is described for in-ground filtering and monitoring of wells or other fluid sources, including a hollow cylindrical pump housing with an inlet and an outlet, filtering devices positioned in the inlet and the outlet, a piston that fits slidably within the pump housing, and an optical cell in fluid communication with the pump housing. A conduit within the piston allows fluid communication between the exterior and one end of the piston. A pair of O-rings form a seal between the inside of the pump housing and the exterior of the piston. A flow valve positioned within the piston inside the conduit allows fluid to flow in a single direction. In operation, fluid enters the pump housing through the inlet, flows through the conduit and towards an end of the pump housing. The piston then makes a downward stroke closing the valve, thus forcing the fluid out from the pump housing into the optical cell, which then takes spectrophotometric measurements of the fluid. A spring helps return the piston back to its starting position, so that a new supply of fluid may enter the pump housing and the downward stroke can begin again. The pump may be used independently of the optical cell, as a sample pump to transport a sample fluid from a source to a container for later analysis.
Date: January 1, 1995
Creator: Hopkins, C.D.; Livingston, R.R. & Toole, W.R. Jr.

Relationship of Course Woody Debris to Red-Cockaded Woodpecker Prey Diversity and Abundance

Description: The abundance of diversity of prey commonly used by the red-cockaded woodpecker were monitored in experimental plots in which course woody debris was manipulated. In one treatment, all the woody debris over four inches was removed. In the second treatment, the natural amount of mortality remained intact. The overall diversity of prey was unaffected; however, wood roaches were significantly reduced by removal of woody debris. The latter suggests that intensive utilizations or harvesting practices may reduce foraging.
Date: September 3, 1999
Creator: Horn, G.S.

Process for the extraction of strontium from acidic solutions

Description: The invention is a process for selectively extracting strontium values from aqueous nitric acid waste solutions containing these and other fission product values. The extractant solution is a macrocyclic polyether in an aliphatic hydrocarbon diluent containing a phase modifier. The process will selectively extract strontium values from nitric acid solutions which are up to 6 molar in nitric acid.
Date: January 1, 1993
Creator: Horwitz, E.P. & Dietz, M.L.

A process for the separation and purification of yttrium-90 for medical applications

Description: An extraction chromatographic method for the preparation of {sup 90}Y of high chemical and radiochemical purity is disclosed. After an initial purification of a {sup 90}Sr stock solution and a suitable period of {sup 90}Y ingrowth, the solution is passed through a series of strontium-selective chromatographic columns, each of which lowers the {sup 90}Sr content of the mixture by a factor of about 10{sup 3}. The {sup 90}Y remaining is freed from any residual {sup 90}Sr, from its {sup 90}Zr daughter, and from any remaining impurities by passing the sample through a final column designed to selectively retain yttrium.
Date: January 1, 1993
Creator: Horwitz, P.E. & Dietz, M.L.

Process for treating alkaline wastes for vitrification

Description: According to its major aspects and broadly stated, the present invention is a process for treating alkaline waste materials, including high level radioactive wastes, for vitrification. The process involves adjusting the pH of the wastes with nitric acid, adding formic acid (or a process stream containing formic acid) to reduce mercury compounds to elemental mercury and MnO{sub 2} to the Mn(II) ion, and mixing with class formers to produce a melter feed. The process minimizes production of hydrogen due to noble metal-catalyzed formic acid decomposition during, treatment, while producing a redox-balanced feed for effective melter operation and a quality glass product. An important feature of the present invention is the use of different acidifying and reducing, agents to treat the wastes. The nitric acid acidifies the wastes to improve yield stress and supplies acid for various reactions; then the formic acid reduces mercury compounds to elemental mercury and MnO{sub 2}) to the Mn(II) ion. When the pH of the waste is lower, reduction of mercury compounds and MnO{sub 2}) is faster and less formic acid is needed, and the production of hydrogen caused by catalytically-active noble metals is decreased.
Date: January 1, 1994
Creator: Hsu, Chia-lin W.