Investigation of Sodium Distribution in Phosphate Glasses Using Spin-Echo {sup 23}Na NMR
Description:
The spatial arrangement of sodium cations for a series of sodium phosphate glasses, xNa{sub 2}O(100-x)P{sub 2}O{sub 5} (x<55), were investigated using {sup 23}Na spin-echo NMR spectroscopy. The spin-echo decay rate is a function of the Na-Na homonuclear dipolar coupling and is related to the spatial proximity of neighboring Na nuclei. The spin-echo decay rate in these sodium phosphate glasses increases non-linearly with higher sodium number density, and thus provides a measure of the Na-Na e…
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Date:
September 16, 1999
Creator:
ALAM, TODD M.; BOYLE, TIMOTHY J.; BROW, RICHARD K.; CLICK, CAROL C.; CONZONE, SAM; McLAUGHLIN, JAY et al.
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