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A Note on the Kinetics of Homogeneous Piles

Description: Abstract. In investigating stability of a homogeneous pile it has been customary to assume that the production of bubbles follows the production of power instantaneously. Here we investigate the implications of introduction of an intermediate dissolved gas stage under two hypotheses on the formation of bubbles from this dissolved gas. It is seen that this additional stage tends to make the pile unstable.
Date: June 26, 1945
Creator: Wilkins, J. Ernest, Jr., 1923-2011
open access

The Stopping Power of Metals

Description: Summary. The effect of the conduction electrons on the stopping power of metals has been considered from two essentially different points of view. No numerical calculations have been carried out, because we have found no completely satisfactory was of computing Z'e, the effective charge on the moving ion. A rather crude estimate made on the basis of the Thomas-Fermi atomic model indicates that Z'2/E is roughly constant. Using this relation one finds that the stopping power of the conduction eleā€¦ more
Date: July 2, 1945
Creator: Goldberger, Marvin L.
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The Hall Effect in Neutron Irradiated and Annealed Graphite

Description: Abstract. Irradiated Whiting graphite possesses a small negative or a positive Hall constant, depending upon the dosage. Annealing at 500 degrees C for 1 hour in helium results in a Hall constant which is large in magnitude and negative in sign. The properties of the annealed graphite are presumably close to those of the original unirradiated material. Unirradiated AGOT-K graphite has a large, negative Hall constant. A mechanism is suggested which accounts for the change in sign of the Hall conā€¦ more
Date: April 18, 1945
Creator: Maurer, Robert J. & Ruder, Richard C.
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Theory of Oscillating Absorber in a Chain Reacting Pile

Description: Abstract. the fluctuation in pile intensity caused by an oscillating point absorber is calculation. It is found that the nature of the response depends on the frequency of the impressed oscillation. If the frequency is high compared to the decay rate of the high harmonics, the response consists of a wave which is propagated away from the oscillator. If the frequency is low, the propagated wave character of the response disappears and the intensity of the whole pile tends to oscillate with the sā€¦ more
Date: April 6, 1945
Creator: Cahn, Albert S., Jr.; Monk, A. T. & Weinberg, Alvin Martin, 1915-2006
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The Effect of Thermal Cycling on the Thermal Transfer from a Sand Blasted Slug to an Unbonded Jacket

Description: Abstract. Measurements were made to determine the effect of thermal cycling on heat transfer from slug to jack using a slug with a sand blasted surface. The value of the transfer coefficient h decreased from initial values ranging from 10 to [formula], to values and [formula] after 1700 cycles, and to a range of 0.15 to 0.45 [formula] after 3200 cycles. Comparisons are made with the results found for slugs with different surfaces.
Date: April 2, 1945
Creator: Bentley, Robert R.
open access

Pile Heat Exchanger Calculations

Description: Abstract. Some idealized calculations (CP-807) relating to the design of heat exchangers for minimum holdup of pile liquid are presented in compact form to facilitate quick estimates. Their use is illustrated by application to a falling film type exchanger.
Date: February 14, 1945
Creator: Young, Gale Jay
open access

The Digging-in of a Warped Rod Into a Rib

Description: Abstract. Some rather idealized considerations are given regarding the depth a warped rod presses into the ribs at the places of contact. It appears that this distance may, under some conditions, be of the order of 70 times greater than for a straight rod resting uniformly on the ribs.
Date: January 22, 1945
Creator: Martin, A. V.
open access

Estimates of the Maximum Surface Temperature for a Slug Displaced from the Center of the Tube

Description: When a slug has been displaced from its normal position the thickness of the water film is decreased over part of the surface, and higher temperatures may be expected where the film is thin. The experimental data necessary for an exact calculation is incomplete, but some approximate estimates ae made here with special assumption concerning the heat transfer coefficient h as a function of the angle p from the point where the water film is thinnest. Variation in water bulk temperature around the ā€¦ more
Date: January 9, 1945
Creator: Murray, F. H.
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A Study of Thorium Peroxide Sulfate

Description: Abstract. Thorium peroxide was precipitated from thorium nitrate solutions containing varying amounts of sulfate ion and of hydrogen ion. The washed solids were analyzed both wet and dry. Analyses were made for thorium, peroxide oxygen, sulfate, nitrate, and water contents. X-ray powder photographs of the dried samples by W.H. Zachariasen showed the presence of only two phases. When precipitated from high sulfuric acid, the solid phase was isomorphous with Th(OO)SO4.3H20. More weakly acid ā€¦ more
Date: October 1, 1945
Creator: Hamaker, John W.
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Composition and Thermal Decomposition of Uranyl Peroxide

Description: Technical report on the studies that have been made on the composition and thermal decomposition of uranyl peroxide. The conditions of precipitation and drying have been found to have no appreciable effect on the composition of the compound, but do affect the physical appearance of the precipitate and the rate of thermal decomposition. The UO4 + 2H2O appears to be thermodynamically unstable with respect to UO3 at 25 degrees C and atmospheric pressure, although the rate of conversion is extremeā€¦ more
Date: June 30, 1945
Creator: Leininger, R. F.; Hunt, J. P. & Koshland, D. E., Jr.
open access

The Determination of Thorium in Uranium-Thorium Alloys, Using Cupferron

Description: Technical report describing that the use of controlled amounts of carbonate, acting both as complexing agent buffer led to a fairly satisfactory procedure for the determination of Th in Th-U alloys, using cupferron. The alloy, dissolved in NHO2, in the presence of HF, is treated with H2SO4 and the mixture is evaporated in SO2 fumes. The solution is diluted and (NH4)2CO2 is added. Th is precipitated from this solution with cupferron. The precipitate is weighed as ThO2 after ignition. An accuraā€¦ more
Date: November 23, 1945
Creator: Eckert, A. C. & Bane, R. W.
open access

Recovery of D2O and UO2F2 by Distillation

Description: Technical report describing the purification and separation by distillation of UO2F2 from D2O. In the experiment which is discussed 2,129.6 lbs of UO2F2 were dissolved in 6,605 lbs of D2O. The average isotopic purity of the D2O decreased during the distillation from 99.77% to 99.73%. The dissolved impurities were less than those present originally in the heavy water.
Date: October 10, 1945
Creator: Fischer, R. & Wattenberg, Albert, 1917-
open access

Analysis of TH( NO3 ) -Ca( NO3 )2 ā€“HNO3 Solutions

Description: Abstract. Methods of analysis for thorium, calcium, and nitric acid in solutions from thorium extraction purification columns are described and the results and errors are outlined. A brief description of methods of analysis that were not successful is included.
Date: December 20, 1945
Creator: Warf, James C.; Patterson, J. H. & Banks, Charles V.
open access

The Rapid Determination of Nitric Acid and Thorium in Thorium Nitrate Solutions

Description: Abstract. The physico-chemical methods of determining nitric acid and thorium nitrate in solutions containing these two materials were investigated. Conductimetric titration with sodium hydroxide can be used to determine nitric acid accurately. the titration of thorium nitrate requires a separate standardization of the base however, since a basic salt is precipitated rather the normal hydroxide. The titration of thorium is reproductible however, so and empirical standardization can be used.ā€¦ more
Date: November 27, 1945
Creator: Newton, A. S.; Powell, J. (James), 1932- & Figard, P
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The Effect of Neutron Bombardment on the Specific Heat of Graphite at Low Temperatures

Description: The work described in this technical report was undertaken as part of a larger program dealing with a systematic investigation of changes in the physical prosperities of artificial graphite due to neutron bombardment. Very pronounced among those changes is the increase in the elastic modulus. Since there is a general relationship between the elastic modulus of a given substance and its specific heat, it was expected that corresponding changes will occur in the specific heat. In conclusion, thā€¦ more
Date: September 5, 1945
Creator: Estermann, I. (Immanuel), 1900-1973 & Kirkland, G. I.
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Sweeping of Fission Gases from Solutions of U and Plutonium

Description: Technical report describing two experiments performed to compare the amounts of fission gases swept out of UNH solution with those amounts swept out of PU solution under idential condiditons. The charge wire technique was used. The essential date and the results are given in tables in the report.
Date: September 4, 1945
Creator: Adams, R. M. & Finkelstein, H.
open access

The Solubility of Helium in Tuballoy

Description: This technical report summarizes the work done in attempting to determine the solubility of helium in tuballoy. In general, the method used has been to allow the tuballoy to stand in contact with helium at one atmosphere presume at a fixed temperature for an extended period, then to pump off the excess helium to a low pressure in as short a time as possible (10-6 mm of Hg or less). The system was then closed off and the pressure increase was measured by a suitable gauge as a function of time.ā€¦ more
Date: June 26, 1945
Creator: Seltz , H. & Young, C. W.
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The Extraction of Uranium into Hexone as Uranyl Thiocyanate from Thorium Nitrate Solutions

Description: Technical report with six sections describing the process: (1) The reaction of HN)3 with HSCN; (2) The distribution of nitric acid between hexone and water; (3) The distribution of HSCN between hexone and water; (4) The solubility of thorium sulfate in various extraction solutions; (5) The distribution of protoactinium and fission elements between hexone and aqueous thiocyanate solutions; and (6) Separation of uranium from thorium by extraction into hexone as UO2(SCH)a.
Date: May 18, 1945
Creator: Reas, William H.
open access

Analysis of Heavy Water by Equilibration

Description: Technical report discussing that the deuterium concentration of heavy water can be determined by equilibrating the water with deuterium gas in the presence of a catalyst with subsequent analysis of the equilibrated gas on the mas spectrometer. The apparatus for equilibration analyses maybe be considered in three parts: 1) apparatus for introducing the ingredients into the reaction chambers; 2) the reaction chambers; 3) the mass spectrometer for analysis of the equilibrated gas. The isotopic coā€¦ more
Date: May 15, 1945
Creator: Fischer, R. B.; Potter, R. A. & Voskuyl, R. J.
open access

Precipitation of Thorium Oxalate from Nitric Acid Solutions

Description: Introduction. It has been known for a long time that thorium is precipitated by oxalic acid in acid solutions, but a survey of the literature showed no study of the limits of the acidity and oxalic acid excess which yield quantitative results. V. I. Spitzin reports on the solubility of thorium oxalate in varying concentrations of several acids, but the effect of an excess oxalic acid is not included. Since solutions are sometimes presented for analysis that contain more than the recommended ā€¦ more
Date: October 5, 1945
Creator: Ayers, A. S.
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