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Studies on the Determination of Carbon by the Low Pressure Combustion Method

Description: Technical report: The apparatus for the low pressure combustion method of determining carbon in iron and steel has be redesigned to increase the speed of manipulation. It has been tested by running several thousand determinations and found to yield results in good agreement with Wooten's form of the apparatus. A detailed description of the equipment and its manipulation is given together with an account of experimental studies on the method. Results are also shown for the carbon content of c… more
Date: October 20, 1943
Creator: Murray, W M., Jr. & Ashley, S E. Q.
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Metallurgical Laboratory, Chemical Research - Analytical, Graphite Purity Research Program

Description: Abstract. Chemical analytical studies of graphite raw materials have revealed new sources of petroleum cokes and pitches of greater purity than those previously used in the manufacture of project graphite. The use of these raw materials of exceptional purity has resulted in an improvement in k of the order of one per cent as compared with the AGOT-AGNT graphite typical of the previous production. A study of the graphitizing process has shown that no dangerous impurities are introduced in the… more
Date: December 22, 1943
Creator: Boyd, G. E.; Curtis, R. E. & Johnston, W. H.
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Chemical Research -- U233 Production and Extraction; Report for the Month Ending June 21, 1943

Description: Abstract. The precipitation of Pa233 with MnO2 from a solution of thorium nitrate has been studied in some detail and seems quite satisfactory up to 36 gm Th(HO3)4 4H2O per 100 cc solution. The concentration of Pa233 with respect to the manganese dioxide carrier and the thorium precipitated with the carrier appears to be accomplished quite well by either a series of MnO2 cycles or thorium iodate cycles. Volatility methods for both the separation of Pa233 from the original thorium and for its … more
Date: June 21, 1943
Creator: Franck, J.
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Metallurgical Laboratory, Chemical Research - Radiation Chemistry, Report for the Month Ending May 15, 1943

Description: Technical report that information has bee obtained on the effect of beta and gamma radiation on the electrical resistance of insulating materials The results are summarized. The recovery to original resistance values has been measured. In general, the initial rate is rapid for the first few hours; the rate then decreases sharply. Certain samples show evidence of complete recovery. Effects on mechanical properties of several plastics has also been studied. Data on gas evolution from severa… more
Date: May 15, 1943
Creator: Franck, J.
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Viscosities and Densities of Fluorolube Oils

Description: Abstract: Since the viscosity-temperature relationships of fluorocarbons are somewhat unusual, when compared to hydrocarbons, for example, it was decided to measure the viscosities, at several temperatures, of various fluorolube oils. The calculation of the viscosity of a blend of oils is at best an uncertain operation, varying considerably with the method used. A comparison of various methods was indicated, in order that reasonably accurate values might be assumed for theoretical composites.… more
Date: April 28, 1943
Creator: Haendler, H. M.; Burger, L. L.; Sheldon, Z. D. & Barber, E. J.
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Capture Cross Section of Pb208 for C Neutrons

Description: From abstract: "Using the method of induced radioactivity, the capture cross section of Pb[^]208 for C neutrons is found to be .00045 ± .00015 x 10[^]-24 cm[^]2. This is definitely lower than the value of .001 x 10[^]-24 reported by Maurer and Ramm."
Date: November 5, 1943
Creator: Levinger, Joseph S., 1921-; Compton, A. H.; Allison, Samuel King, 1900-1965; Watson, W. W. & Snell, A. H.
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Physical Properties of Uranyl Sulfate Solutions

Description: Abstract: Measurements are reported of the solubility of uranyl sulfate in water at several temperatures, of the density of uranyl sulfate solutions as a function of concentration, of the variation of density of uranyl sulfate solutions of three different concentrations over a temperature range from 0[degree]C. to about 93[degree]C., and of the pH of uranyl sulfate solutions as a function of concentration as well as of temperature. The pH measurements were taken on uranyl sulfate samples prepar… more
Date: December 15, 1943
Creator: Helmholz, Lindsay. & Friedlander, G.
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A Colorimetric Method

Description: From abstract: "This paper gives a method for determining Uranium using sodium cresotate as a colorimetric reagent. A precision is obtained of better than 2%. In carrying out analyses for Uranium in corrosion products by existing methods such as ignition to the oxide, silver reductor, or titration with ceric sulfate, it became apparent that a rapid, fairly accurate method for determining uranyl ion would be of great value. Such a method is described in this paper. The most logical color to use … more
Date: June 30, 1943
Creator: Priest, H. F. & Priest, G. I.
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Polarographic Determination of Uranium in Dust Samples

Description: Abstract: "Samples of dust are collected from the atmosphere with a Mine Safety Appliance Co. electrostatic precipitator and analyzed for uranium by means of a dropping mercury electrode apparatus. Two to three micrograms of uranium can be detected in a cell solution volume of 1 ml. Iron, nickel and chromium present in shop dusts do not interfere. Copper may interfere if present in excess but may be removed by a sulfide precipitation. Directions for preparation of cell solution and operation of… more
Date: August 30, 1943
Creator: Smith, Stanton B.
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Studies on the Electrolytic Reduction of Nitric Acid

Description: Report discussing the reduction of nitric acid that results from its use at the cathode for the electrolysis of uranyl nitrate. From introduction: "It is the purpose of this report to give the results of studies on the reduction of nitric acid of different concentrations, at different types of electrodes, and for various current densities in order to ascertain the effects of such changes."
Date: March 27, 1943
Creator: Hamer, Walter J.
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The Vapor Phase Hydrolysis of the Trichlorides of Lanthanum, Praseodymium, Samarium, and Americium

Description: The following report studies the reactions of vapor phase hydrolysis of the trichlorides of lanthanum, praseodymium, samarium, and americium with gas mixtures of HCl and H2O passing over the solid materials mounted on a cantilever-type quartz fiber microbalance. This report calculates the values of the heats and entropies of the reactions, as well as the heat formation of LaCl3, 1254.9 kcal mol-(-1) that was obtained by determining the heat of the solution of La metal in 1.5M HCl.
Date: 1943
Creator: Broido, Abraham
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The Diffusion Length and the Utilization of Thermal Neutrons in a Heterogeneous Pile

Description: Abstract: "An accurate calculation is given for the quantity which corresponds to the diffusion length in the theory of the pile. The procedure is to establish a relationship between the diffusion length and the change in thermal utilization from a pile with infinite sides to one with sides of a finite length. The calculation of this change in the thermal utilization is then carried through. Approximation to the answer and numerically exact calculations are given in the report. The results show… more
Date: October 6, 1943
Creator: Plass, Gilbert N.
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