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The Waste Package Project. Final report, July 1, 1995--February 27, 1996: Volume 1, The structural performance of the shell and fuel rods of a high level nuclear waste container

Description: This dissertation proposal covers research work that started in the spring of 1992. The aim of the research has been to study the structural performance and stability of proposed nuclear waste containers and the enclosed fuel rods to be used in the long term storage of High Level Nuclear Waste (HLNW). This research is in two phases, computational and experimental. The computational phase deals with the linear and nonlinear Finite Element Analysis of the different containers due to various loading conditions during normal handling conditions and due to the effect of long term corrosion while the canister is stored in the drift of a backfilled geological repository. The elastoplastic stability of the nuclear fuel rods were studied under body forces resulting from acceleration vectors at varying angles, resulting from a sudden drop of the canister at an angle onto a hard surface.
Date: June 1, 1996
Creator: Ladkany, S.G. & Rajagopalan, R.

Thin films of metal oxides on metal single crystals: Structure and growth by scanning tunneling microscopy

Description: Detailed studies of the growth and structure of thin films of metal oxides grown on metal single crystal surfaces using Scanning Tunneling Microscopy (STM) are presented. The oxide overlayer systems studied are iron oxide and titanium oxide on the Pt(III) surface. The complexity of the metal oxides and large lattice mismatches often lead to surface structures with large unit cells. These are particularly suited to a local real space technique such as scanning tunneling microscopy. In particular, the symmetry that is directly observed with the STM elucidates the relationship of the oxide overlayers to the substrate as well as distinguishing, the structures of different oxides.
Date: December 1, 1995
Creator: Galloway, H.C.

Search for {Sigma}{sub c} {yields} {Lambda}{sub c}{pi} using {Lambda}{sub c} {yields} {Sigma}{sub s}{pi}{pi} in 250 GeV {pi}{sup {minus}}-nucleon interactions

Description: Combined cross section times branching fraction limits are given for {Sigma}{sub c}{sup +}{sup +} {r_arrow} {Lambda}{sub c}{sup +}{pi}{sup +} and {Sigma}{sub c}{sup 0} {r_arrow} {Lambda}{sub c}{sup +}{pi}{sup {minus}} where {Lambda}{sub c}{sup +} {r_arrow} {Sigma}{sub s}{sup {plus_minus}}{pi}{sup {plus_minus}}{pi}{sup +}. The {Lambda}{sub c}{sup +} is reconstructed with partial information on the {Sigma}{sub s}; the missing {Sigma}{sub s} momentum is established through momentum conservation imposed by a constrained fit. The data are of {pi}{sup {minus}} beam interactions at 250 GeV from Fermilab experiment E769.
Date: October 10, 1995
Creator: Passmore, D.A.

Studies of thin films and surfaces with optical harmonic generation and electron spectroscopy

Description: Optical second harmonic generation (SHG) and sum frequency generation (SFG) were used to study C{sup 60} thin solid films (low energy ED forbidden electronic excitations), and electron spectroscopy was used to study organic overlayers (xylenes) on Pt(111). Theory of SHG from a thin film is described in terms of surface and bulk contributions as well as local and nonlocal contributions to the optical nonlinearities. (1)In situ SHG data on C{sub 60} films during UHV film growth can be described in terms of only nonlocal contributions to both surface and bulk nonlinear susceptibilities. Microscopic origin of SHG response is discussed in terms of electric quadrupole and ED transitions of C{sub 60}. (2)Adsorption and thermal decomposition of ortho- and para-xylene on Pt(111) is studied using HREELS, LEED, AES, and thermal desorption spectroscopy. We have observed preferential decomposition of the methyl groups which leads to distinct decomposition pathways for ortho- and para-xylene on Pt(111).
Date: January 1, 1996
Creator: Wilk, D.E.

Inductively coupled plasma spectrometry: Noise characteristics of aerosols, application of generalized standard additions method, and Mach disk as an emission source

Description: This dissertation is focused on three problem areas in the performance of inductively coupled plasma (ICP) source. The noise characteristics of aerosols produced by ICP nebulizers are investigated. A laser beam is scattered by aerosol and detected by a photomultiplier tube and the noise amplitude spectrum of the scattered radiation is measured by a spectrum analyzer. Discrete frequency noise in the aerosol generated by a Meinhard nebulizer or a direct injection nebulizer is primarily caused by pulsation in the liquid flow from the pump. A Scott-type spray chamber suppresses white noise, while a conical, straight-pass spray chamber enhances white noise, relative to the noise seen from the primary aerosol. Simultaneous correction for both spectral interferences and matrix effects in ICP atomic emission spectrometry (AES) can be accomplished by using the generalized standard additions method (GSAM). Results obtained with the application of the GSAM to the Perkin-Elmer Optima 3000 ICP atomic emission spectrometer are presented. The echelle-based polychromator with segmented-array charge-coupled device detectors enables the direct, visual examination of the overlapping lines Cd (1) 228.802 nm and As (1) 228.812 nm. The slit translation capability allows a large number of data points to be sampled, therefore, the advantage of noise averaging is gained. An ICP is extracted into a small quartz vacuum chamber through a sampling orifice in a water-cooled copper plate. Optical emission from the Mach disk region is measured with a new type of echelle spectrometer equipped with two segmented-array charge-coupled-device detectors, with an effort to improve the detection limits for simultaneous multielement analysis by ICP-AES.
Date: October 6, 1995
Creator: Shen, Luan

High-resolution spectroscopy using synchrotron radiation for surface structure determination and the study of correlated electron systems

Description: The surface structure of three molecular adsorbate systems on transition metal surfaces, ({radical}3 x {radical}3)R30{degrees} and (1.5 x 1.5)R18{degrees} CO adsorbed on Cu(111), and c(2x2) N2/Ni(100), have been determined using Angle-Resolved Photoemission Extended Fine Structure (ARPEFS). The adsorption site and bond lengths are reported for the adsorbate-metal bond and the first two substrate layers. The ARPEFS diffraction pattern of the shake-up peak for c(2x2) N2/Ni(100) is also discussed. A unique method of experimentally determining the angular momentum and intrinsic/extrinsic origin of core-level satellites is presented. We show for the first time that satellite peaks not associated with chemically differentiated atomic species display an ARPEFS intensity oscillation. Specifically, we present data for the C 1s from ({radical}3x{radical}3)R30 CO/Cu(111) and p2mg(2x1)CO/Ni(110), N is from c(2x2) N2/Ni(100), and Ni 3p from clean nickel(111). The satellite peaks in all cases exhibit ARPEFS curves which indicate an angular momentum identical to the main peak and are of an intrinsic nature. A Fourier Transform Soft X-ray spectrometer (FF-SX) has been designed and is under construction for the Advanced Light Source (ALS) at Lawrence Berkeley National Laboratory. The spectrometer is designed for ultra-high resolution theoretical resolving power E/{Delta}E{approx}-10{sup 6} in the photon energy region of 60-120 eV. This instrument is expected to provide experimental results which sensitively test models of correlated electron processes in atomic and molecular physics. The design criteria and consequent technical challenges posed by the short wavelengths of x-rays and desired resolving power are discussed. The fundamental and practical aspects of soft x-ray interferometry are also explored.
Date: May 1, 1996
Creator: Moler, E.J. Jr.

Application of the Environmental Protection Agency`s data quality objective process to environmental monitoring quality control

Description: The United States Environmental Protection Agency`s (EPA) Data Quality Objectives (DQO) process was applied to two environmental monitoring networks for the purpose of optimizing field quality control sampling to give the highest quality monitoring data with minimal impact on resources. The DQO process, developed primarily to aid in cleanup and restoration activities, is a systematic approach to designing sampling, and analysis programs with improved efficiency, cost savings, and measureable and traceable data quality. The two monitoring- networks studied had not been subjected to the systematic review and analysis of the DQO process defined by the EPA. The two monitoring networks studied had relied upon field duplicates or replicates as the main source of field quality control data. Sometimes, both duplicate and routine sample were analyzed by the same analytical laboratory; at other times they were analyzed by different laboratories. This study identified some potential inconsistencies between analytical data and reporting limits from two different laboratories. Application of the EPA DQO process resulted in recommendations for changes in the field quality control sampling program, allowed new insight into the monitoring data, and raised several issues that should be the subject of further investigation.
Date: November 1, 1995
Creator: Garcia, L.M.

A numerical model of hydro-thermo-mechanical coupling in a fractured rock mass

Description: Coupled hydro-thermo-mechanical codes with the ability to model fractured materials are used for predicting groundwater flow behavior in fractured aquifers containing thermal sources. The potential applications of such a code include the analysis of groundwater behavior within a geothermal reservoir. The capability of modeling hydro-thermo systems with a dual porosity, fracture flow model has been previously developed in the finite element code, FEHM. FEHM has been modified to include stress coupling with the dual porosity feature. FEHM has been further developed to implicitly couple the dependence of fracture hydraulic conductivity on effective stress within two dimensional, saturated aquifers containing fracture systems. The cubic law for flow between parallel plates was used to model fracture permeability. The Bartin-Bandis relationship was used to determine the fracture aperture within the cubic law. The code used a Newton Raphson iteration to implicitly solve for six unknowns at each node. Results from a model of heat flow from a reservoir to the moving fluid in a single fracture compared well with analytic results. Results of a model showing the increase in fracture flow due to a single fracture opening under fluid pressure compared well with analytic results. A hot dry rock, geothermal reservoir was modeled with realistic time steps indicating that the modified FEHM code does successfully model coupled flow problems with no convergence problems.
Date: June 1, 1996
Creator: Bower, K.M.

Stability of eutectic interface during directional solidification

Description: Directional solidification of eutectic alloys shows different types of eutectic morphologies. These include lamellar, rod, oscillating and tilting modes. The growth of these morphologies occurs with a macroscopically planar interface. However, under certain conditions, the planar eutectic front becomes unstable and gives rise to a cellular or a dendritic structure. This instability leads to the cellular/dendritic structure of either a primary phase or a two-phase structure. The objective of this work is to develop a fundamental understanding of the instability of eutectic structure into cellular/dendritic structures of a single phase and of two-phases. Experimental studies have been carried out to examine the transition from a planar to two-phase cellular and dendritic structures in a ceramic system of Alumina-Zirconia (Al{sub 2}O{sub 3}-ZrO{sub 2}) and in a transparent organic system of carbon tetrabromide and hexachloroethane (CBr{sub 4}-C{sub 2}Cl{sub 6}). Several aspects of eutectic interface stability have been examined.
Date: April 23, 1996
Creator: Han, S.H.

Fully implicit kinetic modelling of collisional plasmas

Description: This dissertation describes a numerical technique, Matrix-Free Newton Krylov, for solving a simplified Vlasov-Fokker-Planck equation. This method is both deterministic and fully implicit, and may not have been a viable option before current developments in numerical methods. Results are presented that indicate the efficiency of the Matrix-Free Newton Krylov method for these fully-coupled, nonlinear integro-differential equations. The use and requirement for advanced differencing is also shown. To this end, implementations of Chang-Cooper differencing and flux limited Quadratic Upstream Interpolation for Convective Kinematics (QUICK) are presented. Results are given for a fully kinetic ion-electron problem with a self consistent electric field calculated from the ion and electron distribution functions. This numerical method, including advanced differencing, provides accurate solutions, which quickly converge on workstation class machines. It is demonstrated that efficient steady-state solutions can be achieved to the non-linear integro-differential equation, obtaining quadratic convergence, without incurring the large memory requirements of an integral operator. Model problems are presented which simulate plasma impinging on a plate with both high and low neutral particle recycling typical of a divertor in a Tokamak device. These model problems demonstrate the performance of the new solution method.
Date: May 1, 1996
Creator: Mousseau, V.A.

INDEEP Annual report (1995-1996)

Description: The International database on Energy Efficiency Programs (INDEEP) project is designed to make available information on electric and gas utility demand-side management (DSM) programs, as well as DSM programs carried out by government agencies and others. Efforts in the program for this time period are described.
Date: June 1996
Creator: Vine, E.

Estimation of hydrologic properties of heterogeneous geologic media with an inverse method based on iterated function systems

Description: The hydrologic properties of heterogeneous geologic media are estimated by simultaneously inverting multiple observations from well-test data. A set of pressure transients observed during one or more interference tests is compared to the corresponding values obtained by numerically simulating the tests using a mathematical model. The parameters of the mathematical model are varied and the simulation repeated until a satisfactory match to the observed pressure transients is obtained, at which point the model parameters are accepted as providing a possible representation of the hydrologic property distribution. Restricting the search to parameters that represent fractal hydrologic property distributions can improve the inversion process. Far fewer parameters are needed to describe heterogeneity with a fractal geometry, improving the efficiency and robustness of the inversion. Additionally, each parameter set produces a hydrologic property distribution with a hierarchical structure, which mimics the multiple scales of heterogeneity often seen in natural geological media. Application of the IFS inverse method to synthetic interference-test data shows that the method reproduces the synthetic heterogeneity successfully for idealized heterogeneities, for geologically-realistic heterogeneities, and when the pressure data includes noise.
Date: May 1, 1996
Creator: Doughty, C.A.

A new post-column reactor-laser induced fluorescence detector for capillary electrophoresis

Description: Capillary zone electrophoresis (CZE), a powerful separation method based on the differential migration of charged species under the influence of an electric field, has been widely used for separations covering from small ions to big biomolecules. Chapter 1 describes the method, then discusses detection of the separated analytes by laser induced fluorescence and by chemical derivatization, and the use of O-phthaldialdehyde (OPA) as a post-column reagent. Chapter 2 describes a post-column reactor which uses two narrow bore capillaries connected coaxially. This reactor differs from other coaxial reactors in terms of capillary dimensions, reagent flow control, ease of construction and most importantly, better limits of detection. The derivatization reagent is electroosmotically driven into the reaction capillary and the reagent flow rate is independently controlled by a high voltage power supply. Amino acids, amines and proteins, derivatized by OPA/2-mercaptoethanol using this post-column reactor coupled with LIF detection, show low attomole mass limits of detection, and for the first time, the authors demonstrate single cell capability with a post-column derivatization scheme. The single cell capability shows that this reactor could find applications in assaying non-fluorescent or electrochemically inactive components in individual biological cells in the future.
Date: January 2, 1996
Creator: Liling, Zhang

Determination of toxic material penetrations for wildland respirator filters

Description: Thousands of wildland firefighters are exposed to high levels of toxic materials every year. Carbon monoxide, formaldehyde and acrolein gases, along with high particulate concentrations, are the major toxics encountered. Currently, the only respiratory protection wildland firefighters use is a bandanna over the mouth and nose. In this study, a modem activated carbon cartridge with an electrostatic prefilter was compared to a typical bandanna for its ability to filter wildland smoke toxics such as formaldehyde and particulates. The results of the tests were disappointing; neither filter performed very well. The activated carbon cartridge and prefilter efficiently collected formaldehyde gas for up to 60 minutes; however, it only collected 85 percent of the challenge particulate. ]Me bandanna, as expected, was only partially effective at collecting smoke particulate and filtered no toxic gases.
Date: May 1, 1994
Creator: Foote, K.L.

Optimizing parallel reduction operations

Description: A parallel program consists of sets of concurrent and sequential tasks. Often, a reduction (such as array sum) sequentially combines values produced by a parallel computation. Because reductions occur so frequently in otherwise parallel programs, they are good candidates for optimization. Since reductions may introduce dependencies, most languages separate computation and reduction. The Sisal functional language is unique in that reduction is a natural consequence of loop expressions; the parallelism is implicit in the language. Unfortunately, the original language supports only seven reduction operations. To generalize these expressions, the Sisal 90 definition adds user-defined reductions at the language level. Applicable optimizations depend upon the mathematical properties of the reduction. Compilation and execution speed, synchronization overhead, memory use and maximum size influence the final implementation. This paper (1) Defines reduction syntax and compares with traditional concurrent methods; (2) Defines classes of reduction operations; (3) Develops analysis of classes for optimized concurrency; (4) Incorporates reductions into Sisal 1.2 and Sisal 90; (5) Evaluates performance and size of the implementations.
Date: June 1, 1995
Creator: Denton, S.M.

The multi-niche crowding genetic algorithm: Analysis and applications

Description: The ability of organisms to evolve and adapt to the environment has provided mother nature with a rich and diverse set of species. Only organisms well adapted to their environment can survive from one generation to the next, transferring on the traits, that made them successful, to their offspring. Competition for resources and the ever changing environment drives some species to extinction and at the same time others evolve to maintain the delicate balance in nature. In this disertation we present the multi-niche crowding genetic algorithm, a computational metaphor to the survival of species in ecological niches in the face of competition. The multi-niche crowding genetic algorithm maintains stable subpopulations of solutions in multiple niches in multimodal landscapes. The algorithm introduces the concept of crowding selection to promote mating among members with qirnilar traits while allowing many members of the population to participate in mating. The algorithm uses worst among most similar replacement policy to promote competition among members with similar traits while allowing competition among members of different niches as well. We present empirical and theoretical results for the success of the multiniche crowding genetic algorithm for multimodal function optimization. The properties of the algorithm using different parameters are examined. We test the performance of the algorithm on problems of DNA Mapping, Aquifer Management, and the File Design Problem. Applications that combine the use of heuristics and special operators to solve problems in the areas of combinatorial optimization, grouping, and multi-objective optimization. We conclude by presenting the advantages and disadvantages of the algorithm and describing avenues for future investigation to answer other questions raised by this study.
Date: September 1, 1995
Creator: Cedeno, W.

XRF and leaching characterization of waste glasses derived from wastewater treatment sludges

Description: Purpose of this study was to investigate use of XRF (x-ray fluorescence spectrometry) as a near real-time method to determine melter glass compositions. A range of glasses derived from wastewater treatment sludges associated with DOE sites was prepared. They were analyzed by XRF and wet chemistry digestion with atomic absorption/inductively coupled emission spectrometry. Results indicated good correlation between these two methods. A rapid sample preparation and analysis technique was developed and demonstrated by acquiring a sample from a pilot-scale simulated waste glass melter and analyzing it by XRF within one hour. From the results, XRF shows excellent potential as a process control tool for waste glass vitrification. Glasses prepared for this study were further analyzed for durability by toxicity characteristic leaching procedure and product consistency test and results are presented.
Date: December 1, 1994
Creator: Ragsdale, R.G., Jr

Simulations of longitudinal beam dynamics of space-charge dominated beams for heavy ion fusion

Description: The longitudinal instability has potentially disastrous effects on the ion beams used for heavy ion driven inertial confinement fusion. This instability is a {open_quotes}resistive wall{close_quotes} instability with the impedance coining from the induction modules in the accelerator used as a driver. This instability can greatly amplify perturbations launched from the beam head and can prevent focusing of the beam onto the small spot necessary for fusion. This instability has been studied using the WARPrz particle-in-cell code. WARPrz is a 2 1/2 dimensional electrostatic axisymmetric code. This code includes a model for the impedance of the induction modules. Simulations with resistances similar to that expected in a driver show moderate amounts of growth from the instability as a perturbation travels from beam head to tail as predicted by cold beam fluid theory. The perturbation reflects off the beam tail and decays as it travels toward the beam head. Nonlinear effects cause the perturbation to steepen during reflection. Including the capacitive component of the, module impedance. has a partially stabilizing effect on the longitudinal instability. This reduction in the growth rate is seen in both cold beam fluid theory and in simulations with WARPrz. Instability growth rates for warm beams measured from WARPrz are lower than cold beam fluid theory predicts. Longitudinal thermal spread cannot account for this decrease in the growth rate. A mechanism for coupling the transverse thermal spread to decay of the longitudinal waves is presented. The longitudinal instability is no longer a threat to the heavy ion fusion program. The simulations in this thesis have shown that the growth rate for this instability will not be as large as earlier calculations predicted.
Date: December 1, 1994
Creator: Miller, D.A.C.

Conformal field theory on affine Lie groups

Description: Working directly on affine Lie groups, we construct several new formulations of the WZW model, the gauged WZW model, and the generic affine-Virasoro action. In one formulation each of these conformal field theories (CFTs) is expressed as a one-dimensional mechanical system whose variables are coordinates on the affine Lie group. When written in terms of the affine group element, this formulation exhibits a two-dimensional WZW term. In another formulation each CFT is written as a two-dimensional field theory, with a three- dimensional WZW term, whose fields are coordinates on the affine group. On the basis of these equivalent formulations, we develop a translation dictionary in which the new formulations on the affine Lie group are understood as mode formulations of the conventional formulations on the Lie group. Using this dictionary, we also express each CFT as a three-dimensional field theory on the Lie group with a four-dimensional WZW term. 36 refs.
Date: April 1, 1996
Creator: Clubok, K.S.

Solid phase epitaxial regrowth of (100)GaAs

Description: This thesis showed that low temperature (250 C) SPE of stoichiometrically balanced ion implanted GaAs layers can yield good epitaxial recovery for doses near the amorphization threshold. For 250 C anneals, most of the regrowth occurred in the first 10 min. HRTEM revealed much lower stacking fault density in the co-implanted sample than in the As-only and Ga-only samples with comparable doses. After low temp annealing, the nonstoichiometric samples had a large number of residual defects. For higher dose implants, very high temperatures (700 C) were needed to remove residual defects for all samples. The stoichiometrically balanced layer did not regrow better than the Ga-only and As-only samples. The co-implanted sample exhibited a thinner amorphous layer and a room temperature (RT) annealing effect. The amorphous layer regrew about 5 nm, suggesting that stoichiometrically balanced amorphous layers can regrow even at RT. Mechanisms for solid phase crystallization in (100)GasAs is discussed: nucleation and growth of randomly oriented crystallites and SPE. These two mechanisms compete in compound semiconductors at much lower temperatures than in Si. For the low dose As-only and Ga-only samples with low-temp anneals, both mechanisms are active. For this amorphization threshold dose, crystallites remain in the amorphous layer for all as-implants. 250 C annealing showed recrystallization from the surface and bulk for these samples; for the co-implant, the mechanism is not evident.
Date: February 1, 1996
Creator: Almonte, M. I.

Computational modeling of neoclassical and resistive MHD tearing modes in tokamaks

Description: Numerical studies of the linear and nonlinear evolution of magnetic tearing type modes in three-dimensional toroidal geometry are presented. In addition to traditional resistive MHD effects, where the parameter {Delta}{prime} determines the stability properties, neoclassical effects have been included for the first time in such models. The inclusion of neoclassical physics introduces and additional free-energy source for the nonlinear formation of magnetic islands through the effects of a bootstrap current in Ohm`s law. The neoclassical tearing mode is demonstrated to be destabilized in plasmas which are otherwise {Delta}{prime} stable, albeit once an island width threshold is exceeded. The simulations are based on a set of neoclassical reduced magnetohydrodynamic (MHD) equations in three-dimensional toroidal geometry derived from the two-fluid equations in the limit of small inverse aspect ratio {epsilon} and low plasma pressure {beta} with neoclassical closures for the viscous force {del} {center_dot} {leftrightarrow}{pi}. The poloidal magnetic flux {psi}, the toroidal vorticity {omega}{sup {zeta}}, and the plasma pressure p are time advanced using the parallel projection of Ohm`s law, the toroidal projection of the curl of the momentum equation, and a pressure evolution equation with anisotropic pressure transport parallel to and across magnetic field lines. The equations are implemented in an initial value code which Fourier decomposes equilibrium and perturbation quantities in the poloidal and toroidal directions, and finite differences them radially based on a equilibrium straight magnetic field line representation. An implicit algorithm is used to advance the linear terms; the nonlinear terms are advanced explicitly. The simulations are benchmarked linearly and nonlinearly against single and multiple helicity {Delta}{prime} tearing modes in toroidal geometry in the absence of neo-classical effects.
Date: February 1, 1996
Creator: Gianakon, T.A.

Neutral particle dynamics in the Alcator C-Mod tokamak

Description: This thesis presents an experimental study of neutral particle dynamics in the Alcator C-Mod tokamak. The primary diagnostic used is a set of six neutral pressure gauges, including special-purpose gauges built for in situ tokamak operation. While a low main chamber neutral pressure coincides with high plasma confinement regimes, high divertor pressure is required for heat and particle flux dispersion in future devices such as ITER. Thus we examine conditions that optimize divertor compression, defined here as a divertor-to-midplane pressure ratio. We find both pressures depend primarily on the edge plasma regimes defined by the scrape-off-layer heat transport. While the maximum divertor pressure is achieved at high core plasma densities corresponding to the detached divertor state, the maximum compression is achieved in the high-recycling regime. Variations in the divertor geometry have a weaker effect on the neutral pressures. For otherwise similar plasmas the divertor pressure and compression are maximum when the strike point is at the bottom of the vertical target plate. We introduce a simple flux balance model, which allows us to explain the divertor neutral pressure across a wide range of plasma densities. In particular, high pressure sustained in the detached divertor (despite a considerable drop in the recycling source) can be explained by scattering of neutrals off the cold plasma plugging the divertor throat. Because neutrals are confined in the divertor through scattering and ionization processes (provided the mean-free-paths are much shorter than a typical escape distance) tight mechanical baffling is unnecessary. The analysis suggests that two simple structural modifications may increase the divertor compression in Alcator C-Mod by a factor of about 5. Widening the divertor throat would increase the divertor recycling source, while closing leaks in the divertor structure would eliminate a significant neutral loss mechanism. 146 refs., 82 figs., 14 tabs.
Date: August 1, 1995
Creator: Niemczewski, A.P.

Line narrowing spectroscopic studies of DNA-carcinogen adducts and DNA-dye complexes

Description: Laser-induced fluorescence line narrowing and non-line narrowing spectroscopic methods were applied to conformational studies of stable DNA adducts of the 7{beta}, 8{alpha}-dihydoxy-9{alpha}, l0{alpha}-epoxy-7,8,9, 10-tetrahydrobenzo[{alpha}]pyrene (anti-BPDE). Stereochemically distinct (+)-trans-, ({minus})-trans-, (+)-cis- and ({minus})-cis adducts of anti-BPDE bound to exocyclic amino group of the central guanine in an 11-mer oligonucleotide, exist in a mixture of conformations in frozen aqueous buffer matrices. The (+)-trans adduct adopts primarily an external conformation with a smaller fraction ( {approximately} 25 %) exists in a partially base-stacked conformation. Both cis adducts were found to be intercalated with significant {pi}-{pi} stacking interactions between the pyrenyl residues and the bases. Conformations of the trans-adduct of (+)-anti -BPDE in 11-mer oligonucleotides were studied as a function of flanking bases. In single stranded form the adduct at G{sub 2} or G{sub 3} (5 ft-flanking, base guanine) adopts a conformation with strong, interaction with the bases. In contrast, the adduct with a 5ft-flanking, thymine exists in a primarily helixexternal conformation. Similar differences were observed in the double stranded oligonucleotides. The nature of the 3ft-flanking base has little influence on the conformational equilibrium of the (+)-trans-anti BPDE-dG adduct. The formation and repair of BPDE-N{sup 2}-dG in DNA isolated from the skin of mice treated topically with benzo[{alpha}]pyrene (BP) was studied. Low-temperature fluorescence spectroscopy of the intact DNA identified the major adduct as (+)-trans-anti-BPDE-N-dG, and the minor adduct fraction consisted mainly of (+)-cis-anti-BPDE-N{sup 2}-dG.
Date: December 6, 1995
Creator: Suh, Myungkoo