1,2-HOIQO--A highly versatile 1,2-HOPO analog
Description:
A cyclic, bidentate hydroxamic acid binding unit based on an isoquinoline scaffold has been utilized for the synthesis of a hexadentate tripodal ligand based on the TREN backbone. This prototype for a new class of multidentate chelators forms mononuclear iron(III) complexes and one-dimensional coordination polymers with lanthanide(III) cations. The latter has been determined by single crystal X-ray analysis of the cerium species. The solid state structure in the monoclinic space group P2{sub 1}…
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Date:
August 7, 2006
Creator:
Seitz, Michael; Pluth, Michael D. & Raymond, Kenneth N.
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