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(2,2-Bipyridyl)bis(eta5-1,2,3,4,5-pentamethylcyclopentadienyl)Strontium(II)

Description: In the title compound, the Sr-N distances are 2.624 (3) and 2.676 (3) Angstroms. The Sr-centroid distances are 2.571 and 2.561 Angstroms. The N-C-C-N torsion angle in the bipyridine ligand is 2.2 (4){sup o}. Interestingly, the bipyridine ligand is tilted. The angle between the plane defined by Sr1, N1 and N2 and the plane defined by the 12 atoms of the bipyridine ligand is 10.7{sup o}.
Date: July 3, 2008
Creator: Kazhdan, Daniel; Kazhdan, Daniel; Hu, Yung-Jin; Kokai, Akos; Levi, Zerubba & Rozenel, Sergio

3,2-HOPO Complexes of Near-Infra-Red (NIR) Emitting Lanthanides: Sensitization of Ho(III) and Pr(III) in Aqueous Solution

Description: There is a growing interest in Near Infra-Red (NIR) emission originating from organic complexes of Ln{sup III} cations. As a major impetus, biological tissues are considerably more transparent at these low energy wavelengths when compared to visible radiation, which facilitates deeper penetration of incident and emitted light. Furthermore, the long luminescence lifetimes of Ln{sup III} complexes (eg. Yb{sup III}, {tau}{sub rad} {approx} 1 ms) when compared to typical organic molecules can be utilized to vastly improve signal to noise ratios by employing time-gating techniques. While the improved quantum yield of Yb{sub III} complexes when compared to other NIR emitters favors their use for bioimaging applications, there has also been significant interest in the sensitized emission from other 4f metals such as Ln = Nd, Ho, Pr and Er which have well recognized applications as solid state laser materials (eg. Nd {approx} 1.06 {micro}m, Ho {approx} 2.09 {micro}m), and in telecommunications (eg. Er {approx} 1.54 {micro}m) where they can be used for amplification of optical signals. As a result of their weak (Laporte forbidden) f-f absorptions, the direct excitation of Ln{sup III} cations is inefficient, and sensitization of the metal emission is more effectively achieved using the so-called antenna effect. We have previously examined the properties of several Eu{sup III} complexes which feature 1-hydroxypyridin-2-one (Fig. 1) as the light harvesting chromophore. While the 1,2-HOPO isomer was found to strongly sensitize Eu{sup III}, we noted the analogous Me-3,2-HOPO isomer does not, which prompted further investigation of the properties of this chromophore with other metals.
Date: May 19, 2008
Creator: Moore, Evan G.; Szigethy, Geza; Xu, Jide; Palsson, Lars-Olof; Beeby, Andrew & Raymond, Kenneth N.

3-D Microprobe Metrology

Description: This report documents the results of a project undertaken to develop an ultra-high-accuracy measurement capability, which is necessary to address a rising trend toward miniaturized mechanical products exhibiting dramatically reduced product tolerances. A significant improvement in measurement capability is therefore required to insure that a 4:1 ratio can be maintained between product tolerances and measurement uncertainty.
Date: October 14, 2008
Creator: Swallow, Kevin

3-D Model of Broadband Emission from Supernova Remnants Undergoing Non-linear Diffusive Shock Acceleration

Description: We present a 3-dimensional model of supernova remnants (SNRs) where the hydrodynamical evolution of the remnant is modeled consistently with nonlinear diffusive shock acceleration occurring at the outer blast wave. The model includes particle escape and diffusion outside of the forward shock, and particle interactions with arbitrary distributions of external ambient material, such as molecular clouds. We include synchrotron emission and cooling, bremsstrahlung radiation, neutral pion production, inverse-Compton (IC), and Coulomb energy-loss. Boardband spectra have been calculated for typical parameters including dense regions of gas external to a 1000 year old SNR. In this paper, we describe the details of our model but do not attempt a detailed fit to any specific remnant. We also do not include magnetic field amplification (MFA), even though this effect may be important in some young remnants. In this first presentation of the model we don't attempt a detailed fit to any specific remnant. Our aim is to develop a flexible platform, which can be generalized to include effects such as MFA, and which can be easily adapted to various SNR environments, including Type Ia SNRs, which explode in a constant density medium, and Type II SNRs, which explode in a pre-supernova wind. When applied to a specific SNR, our model will predict cosmic-ray spectra and multi-wavelength morphology in projected images for instruments with varying spatial and spectral resolutions. We show examples of these spectra and images and emphasize the importance of measurements in the hard X-ray, GeV, and TeV gamma-ray bands for investigating key ingredients in the acceleration mechanism, and for deducing whether or not TeV emission is produced by IC from electrons or pion-decay from protons.
Date: July 2, 2008
Creator: Lee, Shiu-Hang; Kamae, Tuneyoshi & Ellison, Donald C.

A 3-D model of superfluid helium suitable for numerical analysis

Description: The two-fluid description is a very successful phenomenological representation of the properties of Helium II. A 3-D model suitable for numerical analysis based on the Landau-Khalatnikov description of Helium II is proposed. In this paper we introduce a system of partial differential equations that is both complete and consistent as well as practical, to be used for a 3-D solution of the flow of Helium II. The development of a 3-D numerical model for Helium II is motivated by the need to validate experimental results obtained by observing the normal component velocity distribution in a Helium II thermal counter-flow using the Particle Image Velocimetry (PIV) technique.
Date: January 1, 2008
Creator: Darve, C.; U., /Fermilab /Northwestern; Patankar, N.A.; U., /Northwestern; Van Sciver, S.W. & Lab., /Natl. High Mag. Field

12.6 keV Kr K-alpha X-ray Source For High Energy Density Physics Experiments

Description: A high contrast 12.6 keV Kr K{alpha} source has been demonstrated on the petawatt-class Titan laser facility. The contrast ratio (K{alpha} to continuum) is 65, with a competitive ultra short pulse laser to x-ray conversion efficiency of 10{sup -5}. Filtered shadowgraphy indicates that the Kr K{alpha} and K{beta} x-rays are emitted from a roughly 1 x 2 mm emission volume, making this source suitable for area backlighting and scattering. Spectral calculations indicate a typical bulk electron temperature of 50-70 eV (i.e. mean ionization state 13-16), based on the observed ratio of K{alpha} to K{beta}. Kr gas jets provide a debris-free high energy K{alpha} source for time-resolved diagnosis of dense matter.
Date: April 22, 2008
Creator: Kugland, N; Constantin, C G; Niemann, C; Neumayer, P; Chung, H; Doppner, T et al.

14-MeV Neutron Generator Used as a Thermal Neutron Source

Description: One of the most important applications of the general purpose Monte Carlo N-Particle (MCNPS and MCNPX) codes is neutron shielding design. We employed this method to simulate the shield of a 14-MeV neutron generator used as a thermal neutron source providing an external thermal neutron beam for testing large area neutron detectors developed for diffraction studies in biology and also useful for national security applications. Nuclear reactors have been the main sources of neutrons used for scientific applications. In the past decade, however, a large number of reactors have been shut down, and the importance of other, smaller devices capable of providing neutrons for research has increased. At Brookhaven National Laboratory a moderated Am-Be neutron source with shielding is used for neutron detector testing. This source is relatively weak, but provides a constant flux of neutrons, even when not in use. The use of a 14 MeV energized neutron generator, with an order of magnitude higher neutron flux has been considered to replace the Am-Be source, but the higher fast neutron yield requires a more careful design of moderator and shielding. In the present paper we describe a proposed shielding configuration based on Monte Carlo calculations, and provide calculated neutron flux and dose distributions. We simulated the neutron flux distribution of our existing Am-Be source surrounded by a paraffin thermalizer cylinder (radius of 17.8 cm), 0.8 mm cadmium, and borated polyethylene as biological shield. The thermal neutrons are available through a large opening through the polyethylene and cadmium. The geometrical model for the MCNPS and MCNPX2 simulations is shown in Fig. 1. We simulated the Am-Be source neutron energy distribution as a point source having an energy distribution of four discrete lines at 3.0 (37%), 5.0 (35%), 8.0 (20%) and 11.0 (8%) MeV energies. The estimated source strength based on ...
Date: August 10, 2008
Creator: Dioszegi,I.

A 15-T Pulsed Solenoid for a High-Power Target Experiment

Description: The MERIT experiment, which ran at CERN in 2007, is a proof-of-principle test for a target system that converts a 4-MW proton beam into a high-intensity muon beam for either a neutrino factory complex or a muon collider. The target system is based on a free mercury jet that intercepts an intense proton beam inside a 15-T solenoidal magnetic field. Here, we describe the design and performance of the 15-T, liquid-nitrogen-precooled, copper solenoid magnet.
Date: June 23, 2008
Creator: Kirk,H.G.; Efthymiopoulos, I.; Fabich, A.; Haug, F.; Pereira, H.; Titus, P. et al.

20% Wind Energy - Diversifying Our Energy Portfolio and Addressing Climate Change (Brochure)

Description: This brochure describes the R&D efforts needed for wind energy to meet 20% of the U.S. electrical demand by 2030. In May 2008, DOE published its report, 20% Wind Energy by 2030, which presents an in-depth analysis of the potential for wind energy in the United States and outlines a potential scenario to boost wind electric generation from its current production of 16.8 gigawatts (GW) to 304 GW by 2030. According to the report, achieving 20% wind energy by 2030 could help address climate change by reducing electric sector carbon dioxide (CO2) emissions by 825 million metric tons (20% of the electric utility sector CO2 emissions if no new wind is installed by 2030), and it will enhance our nation's energy security by diversifying our electricity portfolio as wind energy is an indigenous energy source with stable prices not subject to fuel volatility. According to the report, increasing our nation's wind generation could also boost local rural economies and contribute to significant growth in manufacturing and the industry supply chain. Rural economies will benefit from a substantial increase in land use payments, tax benefits and the number of well-paying jobs created by the wind energy manufacturing, construction, and maintenance industries. Although the initial capital costs of implementing the 20% wind scenario would be higher than other generation sources, according to the report, wind energy offers lower ongoing energy costs than conventional generation power plants for operations, maintenance, and fuel. The 20% scenario could require an incremental investment of as little as $43 billion (net present value) more than a base-case no new wind scenario. This would represent less than 0.06 cent (6 one-hundredths of 1 cent) per kilowatt-hour of total generation by 2030, or roughly 50 cents per month per household. The report concludes that while achieving the 20% wind ...
Date: May 1, 2008

A 30 MW, 200 MHz Inductive Output Tube for RF Accelerators

Description: This program investigated development of a multiple beam inductive output tube (IOT) to produce 30 MW pulses at 200 MHz. The program was successful in demonstrating feasibility of developing the source to achieve the desired power in microsecond pulses with 70% efficiency. The predicted gain of the device is 24 dB. Consequently, a 200 kW driver would be required for the RF input. Estimated cost of this driver is approximately $1.25 M. Given the estimated development cost of the IOT of approximately $750K and the requirements for a test set that would significantly increase the cost, it was determined that development could not be achieved within the funding constraints of a Phase II program.
Date: June 19, 2008
Creator: Ives, R. Lawrence & Read, Michael

41. DISCOVERY, SEARCH, AND COMMUNICATION OF TEXTUAL KNOWLEDGE RESOURCES IN DISTRIBUTED SYSTEMS a. Discovering and Utilizing Knowledge Sources for Metasearch Knowledge Systems

Description: Advanced Natural Language Processing Tools for Web Information Retrieval, Content Analysis, and Synthesis. The goal of this SBIR was to implement and evaluate several advanced Natural Language Processing (NLP) tools and techniques to enhance the precision and relevance of search results by analyzing and augmenting search queries and by helping to organize the search output obtained from heterogeneous databases and web pages containing textual information of interest to DOE and the scientific-technical user communities in general. The SBIR investigated 1) the incorporation of spelling checkers in search applications, 2) identification of significant phrases and concepts using a combination of linguistic and statistical techniques, and 3) enhancement of the query interface and search retrieval results through the use of semantic resources, such as thesauri. A search program with a flexible query interface was developed to search reference databases with the objective of enhancing search results from web queries or queries of specialized search systems such as DOE's Information Bridge. The DOE ETDE/INIS Joint Thesaurus was processed to create a searchable database. Term frequencies and term co-occurrences were used to enhance the web information retrieval by providing algorithmically-derived objective criteria to organize relevant documents into clusters containing significant terms. A thesaurus provides an authoritative overview and classification of a field of knowledge. By organizing the results of a search using the thesaurus terminology, the output is more meaningful than when the results are just organized based on the terms that co-occur in the retrieved documents, some of which may not be significant. An attempt was made to take advantage of the hierarchy provided by broader and narrower terms, as well as other field-specific information in the thesauri. The search program uses linguistic morphological routines to find relevant entries regardless of whether terms are stored in singular or plural form. Implementation of additional ...
Date: March 18, 2008
Creator: Zamora, Antonio

S-102 Transfer Pump Restriction Modeling Results

Description: It was determined that a radioactive waste leak in the Hanford S Farm in the vicinity of the S-102 retrieval pump discharge occurred because of over-pressurization and failure of the S-102 dilution water supply hose while operating the retrieval pump in reverse with an obstructed suction cavity and an unobstructed flow path to the dilution water supply hose. This report describes efforts to identify plausible scenarios for the waste leak to occur.
Date: March 27, 2008
Creator: Wells, Beric E.; Johnson, Kenneth I.; Rector, David R. & Trent, Donald S.

200-BP-1 Prototype Hanford Barrier Annual Monitoring Report for Fiscal Years 2005 Through 2007

Description: A prototype Hanford barrier was deployed over the 216-B-57 Crib at the Hanford Site in 1994 to prevent percolation through the underlying waste and to minimize spreading of buried contaminants. This barrier is being monitored to evaluate physical and hydrologic performance at the field scale. This report summarizes data collected during the period FY 2005 through FY 2007. In FY 2007, monitoring of the prototype Hanford barrier focused on barrier stability, vegetative cover, evidence of plant and animal intrusion, and the main components of the water balance, including precipitation, runoff, storage, drainage, and deep percolation. Owing to a hiatus in funding in FY 2005 through 2006, data collected were limited to automated measurements of the water-balance components. For the reporting period (October 2004 through September 2007) precipitation amount and distribution were close to normal. The cumulative amount of water received from October 1994 through September 2007 was 3043.45 mm on the northern half of the barrier, which is the formerly irrigated treatment, and 2370.58 mm on the southern, non-irrigated treatments. Water storage continued to show a cyclic pattern, increasing in the winter and declining in the spring and summer to a lower limit of around 100 mm in response to evapotranspiration. The 600-mm design storage has never been exceeded. For the reporting period, the total drainage from the soil-covered plots ranged from near zero amounts under the soil-covered plots to almost 20 mm under the side slopes. Over the 13-yr monitoring period, side slope drainage accounted for about 20 percent of total precipitation while the soil-covered plots account for only 0.12 mm total. Above-asphalt and below-asphalt moisture measurements show no evidence of deep percolation of water. Topographic surveys show the barrier and protective side slopes to be stable. Plant surveys show a relatively high coverage of native plants still persists ...
Date: February 1, 2008
Creator: Ward, Andy L.; Link, Steven O.; Strickland, Christopher E.; Draper, Kathryn E. & Clayton, Ray E.

219-S CORROSION STUDY

Description: A minor leak was detected in a drain line for Hood 2B located in the 222-S Laboratory. The line transfers radioactive waste, spent analytical standards, and chemicals used in various analytical procedures. Details are in the report provided by David Comstock, 2B NDE June 2008, work package LAB-WO-07-2012. Including the noted leak, the 222-S Laboratory has experienced two drain line leaks in approximately the last two years of operation. As a consequence, CH2M HILL Hanford Group, Inc. (CH2M HILL) requested the support of ChemMet, Ltd., PC (ChemMet) at the Hanford Site 222-S Laboratory. The corrosion expertise from ChemMet was required prior to preparation of a compatibility assessment for the 222-S Laboratory waste transfer system to assure the expected life of the piping system is extended as much as practicable. The system includes piping within the 222-S Laboratory and the 219-S Waste Storage and Transfer Facility and Operations Process. The ChemMet support was required for an assessment by 222-S staff to analyze what improvements to operational activities may be implemented to extend the tank/piping system life. This assessment will include a summary of the various material types, age, and locations throughout the facility. The assessment will also include a discussion of materials that are safe for drain line disposal on a regular basis, materials that are safe for disposal on a case-by-case basis including specific additional requirements such as flushing, neutralization to a specific pH, and materials prohibited from disposal. The assessment shall include adequate information for 222-S Laboratory personnel to make informed decisions in the future disposal of specific material types by discussing types of compatibility of system materials and potential wastes. The assessment is expected to contain some listing of acceptable waste materials but is not anticipated to be a complete or comprehensive list. Finally the assessment will encompass ...
Date: December 1, 2008
Creator: Divine, James R. & Parsons, G. L.

242-16H 2H EVAPORATOR POT SAMPLING FINAL REPORT

Description: Due to the materials that are processed through 2H Evaporator, scale is constantly being deposited on the surfaces of the evaporator pot. In order to meet the requirements of the Nuclear Criticality Safety Analysis/Evaluation (NCSA/NCSE) for 2H Evaporator, inspections of the pot are performed to determine the extent of scaling. Once the volume of scale reaches a certain threshold, the pot must be chemically cleaned to remove the scale. Prior to cleaning the pot, samples of the scale are obtained to determine the concentration of uranium and plutonium and also to provide information to assist with pot cleaning. Savannah River National Laboratory (SRNL) was requested by Liquid Waste Organization (LWO) Engineering to obtain these samples from two locations within the evaporator. Past experience has proven the difficulty of successfully obtaining solids samples from the 2H Evaporator pot. To mitigate this risk, a total of four samplers were designed and fabricated to ensure that two samples could be obtained. Samples had previously been obtained from the cone surface directly below the vertical access riser using a custom scraping tool. This tool was fabricated and deployed successfully. A second scraper was designed to obtain sample from the nearby vertical thermowell and a third scraper was designed to obtain sample from the vertical pot wall. The newly developed scrapers both employed a pneumatically actuated elbow. The scrapers were designed to be easily attached/removed from the elbow assembly. These tools were fabricated and deployed successfully. A fourth tool was designed to obtain sample from the opposite side of the pot under the tube bundle. This tool was fabricated and tested, but the additional modifications required to make the tool field-ready could not be complete in time to meet the aggressive deployment schedule. Two samples were obtained near the pot entry location, one from the ...
Date: June 11, 2008
Creator: Krementz, D & William Cheng, W

275 C Downhole Microcomputer System

Description: An HC11 controller IC and along with serial SRAM and ROM support ICs chip set were developed to support a data acquisition and control for extreme temperature/harsh environment conditions greater than 275 C. The 68HC11 microprocessor is widely used in well logging tools for control, data acquisition, and signal processing applications and was the logical choice for a downhole controller. This extreme temperature version of the 68HC11 enables new high temperature designs and additionally allows 68HC11-based well logging tools and MWD tools to be upgraded for high temperature operation in deep gas reservoirs, The microcomputer chip consists of the microprocessor ALU, a small boot ROM, 4 kbyte data RAM, counter/timer unit, serial peripheral interface (SPI), asynchronous serial interface (SCI), and the A, B, C, and D parallel ports. The chip is code compatible with the single chip mode commercial 68HC11 except for the absence of the analog to digital converter system. To avoid mask programmed internal ROM, a boot program is used to load the microcomputer program from an external mask SPI ROM. A SPI RAM IC completes the chip set and allows data RAM to be added in 4 kbyte increments. The HC11 controller IC chip set is implemented in the Peregrine Semiconductor 0.5 micron Silicon-on-Sapphire (SOS) process using a custom high temperature cell library developed at Oklahoma State University. Yield data is presented for all, the HC11, SPI-RAM and ROM. The lessons learned in this project were extended to the successful development of two high temperature versions of the LEON3 and a companion 8 Kbyte SRAM, a 200 C version for the Navy and a 275 C version for the gas industry.
Date: August 31, 2008
Creator: Hutchens, Chris & Soo, Hooi Miin

275 C Downhole Switched-Mode Power Supply

Description: A vee-square (V2) control based controller IC is developed for a switch mode power supply capable of operating at extreme temperature/harsh environment conditions. A buck type regulator with silicon carbide power junction field effect transistors (JFET) as power devices is used to analyze the performance of controller. Special emphases are made on the analog sub-blocks--voltage reference, operational transconductance amplifier and comparator as individual building blocks. Transformer coupled gate drives and high temperature operable magnetic cores and capacitors are identified and tested for use in the design. Conventional ceramic chip packaging of ICs combined with lead carrier type mounting of passive filter components is introduced for hybrid packaging of the complete product. The developed SMPS is anticipated to support the operation of down-hole microcontrollers and other electronics devices that require low/medium power filtered dc inputs over an operating temperature of 275 C.
Date: August 31, 2008
Creator: Hutchens, Chris & Madhuravasal, Vijay

300 Area Integrated Field-Scale Subsurface Research Challenge (IFRC) Field Site Management Plan

Description: Pacific Northwest National Laboratory (PNNL) has established the 300 Area Integrated Field-Scale Subsurface Research Challenge (300 Area IFRC) on the Hanford Site in southeastern Washington State for the U.S. Department of Energy’s (DOE) Office of Biological and Environmental Research (BER) within the Office of Science. The project is funded by the Environmental Remediation Sciences Division (ERSD). The purpose of the project is to conduct research at the 300 IFRC to investigate multi-scale mass transfer processes associated with a subsurface uranium plume impacting both the vadose zone and groundwater. The management approach for the 300 Area IFRC requires that a Field Site Management Plan be developed. This is an update of the plan to reflect the installation of the well network and other changes.
Date: December 31, 2008
Creator: Freshley, Mark D.

300 Area Treatability Test: Laboratory Development of Polyphosphate Remediation Technology for In Situ Treatment of Uranium Contamination in the Vadose Zone and Capillary Fringe

Description: This report presents results from bench-scale treatability studies conducted under site-specific conditions to optimize the polyphosphate amendment for implementation of a field-scale technology demonstration to stabilize uranium within the 300 Area vadose and smear zones of the Hanford Site. The general treatability testing approach consisted of conducting studies with site sediment and under site conditions, to develop an effective chemical formulation and infiltration approach for the polyphosphate amendment under site conditions. Laboratory-scale dynamic column tests were used to 1) quantify the retardation of polyphosphate and its degradation products as a function of water content, 2) determine the rate of polyphosphate degradation under unsaturated conditions, 3) develop an understanding of the mechanism of autunite formation via the reaction of solid phase calcite-bound uranium and aqueous polyphosphate remediation technology, 4) develop an understanding of the transformation mechanism, the identity of secondary phases, and the kinetics of the reaction between uranyl-carbonate and -silicate minerals with the polyphosphate remedy under solubility-limiting conditions, and 5) quantify the extent and rate of uranium released and immobilized based on the infiltration rate of the polyphosphate remedy and the effect of and periodic wet-dry cycling on the efficacy of polyphosphate remediation for uranium in the vadose zone and smear zone.
Date: September 30, 2008
Creator: Wellman, Dawn M.; Pierce, Eric M.; Bacon, Diana H.; Oostrom, Martinus; Gunderson, Katie M.; Webb, Samuel M. et al.

300 Area VOC Program Slug Test Characterization Results for Selected Test/Depth Intervals for Wells 399-2-5, 399-3-22, and 399-4-14

Description: Multiple, stress-level slug tests were performed at selected test/depth intervals within wells 399-2-5, 399-3-22, and 399-4-14 as part of the 300 Area volatile organic compound characterization program at the Hanford Site in Washington State. The temporary test screen lengths were characterized as the boreholes were advanced to their final drill depths and before their completion as monitor-well facilities. Following well completion, slug tests were performed in the final, completed well-screen sections. The objectives of the slug tests were to provide the vertical distribution of hydraulic conductivity with depth at these locations and to support selection of the final well screen-depth interval for each of these monitor-well facilities.
Date: March 1, 2008
Creator: Newcomer, Darrell R.

L-325 Sagebrush Habitat Mitigation Project: FY2008 Compensation Area Monitoring Report

Description: This document provides a review and status of activities conducted in support of the Fluor Daniel Hanford Company (Fluor) Mitigation Action Plan (MAP) for Project L-325, Electrical Utility Upgrades. It includes time-zero monitoring results for planting activities conducted in January 2008, annual survival monitoring for all planting years (2007 and 2008), and recommendations for the successful completion of DOE habitat mitigation commitments for this project.
Date: September 30, 2008
Creator: Durham, Robin E. & Sackschewsky, Michael R.