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NOx Control Options and Integration for US Coal Fired Boilers Quarterly Progress Report: July-September 2000

Description: This report summarizes the research that has been performed by Reaction Engineering International (REI) during the last three months on demonstrating and evaluating low NOx control strategies and their possible impact on boiler performance for firing US coals. The focus of our efforts during the last six months have been on: (1) Field Tests for RRI at the Conectiv BL England Station Unit No.1, a 130 MW cyclone fired boiler; (2) Extending our Computational Fluid Dynamics (CFD) based NOx model to accommodate the chemistry for Rich Reagent Injection (RRI) in cyclone fired boilers; (3) Applying the NOx model to evaluate RRI systems integrated into a boiler with Over Fired Air (OFA) and Selective Non-Catalytic Reduction (SNCR); (4) Field Tests of the REI Corrosion Probe at the Conectiv BL England Station Unit No.1; (5) Commence engineering study of ammonia adsorption mechanisms for Fly Ash; (6) Presentation of current program accomplishments and plans for future work to DoE staff members at NETL-FE (Pittsburgh); and (7) Presentation of preliminary field test results for RRI to EPRI CNCIG.
Date: October 31, 2000
Creator: Bockelie, Michael J.

NOx Control Options and Integration for US Coal Fired Boilers Quarterly Progress Report: October-December 2000

Description: This is the second Quarterly Technical Report for DOE Cooperative Agreement No: DE-FC26-00NT40753. The goal of the project is to develop cost effective analysis tools and techniques for demonstrating and evaluating low NOx control strategies and their possible impact on boiler performance for firing US coals. The focus of our efforts during the last three months have been on: (1) Completion of a long term field test for Rich Reagent Injection (RRI) at the Conectiv BL England Station Unit No.1, a 130 MW Cyclone fired boiler; (2) Extending our Computational Fluid Dynamics (CFD) based NOx model to accommodate the chemistry for RRI in PC fired boilers; (3) Design improvements and calibration tests of the corrosion probe; and (4) Investigations on ammonia adsorption mechanisms and removal processes for Fly Ash.
Date: January 31, 2001
Creator: Bockelie, Mike; Cremer, Marc; Davis, Kevin; Hurt, Bob & Eddings, Eric

NOx Control Options and Integration for US Coal Fired Boilers Quarterly Progress Report: April-June 2001

Description: This is the third Quarterly Technical Report for DOE Cooperative Agreement No: DE-FC26-00NT40753. The goal of the project is to develop cost effective analysis tools and techniques for demonstrating and evaluating low NOx control strategies and their possible impact on boiler performance for firing US coals. The Electric Power Research Institute (EPRI) is providing cofunding for this program. This program contains multiple tasks and good progress is being made on all fronts. A Rich Reagent Injection (RRI) design has been developed for a cyclone fired utility boiler in which a field test of RRI will be performed later this year. Initial evaluations of RRI for PC fired boilers have been performed. Calibration tests have been developed for a corrosion probe to monitor waterwall wastage. Preliminary tests have been performed for a soot model within a boiler simulation program. Shakedown tests have been completed for test equipment and procedures that will be used to measure soot generation in a pilot scale test furnace. In addition, an initial set of controlled experiments for ammonia adsorption onto fly ash in the presence of sulfur have been performed that indicates the sulfur does enhance ammonia uptake.
Date: July 27, 2001
Creator: Bockelie, Mike; Cremer, Marc; Davis, Kevin; Hurt, Bob & Eddings, Eric

NOx Control Options and Integration for US Coal Fired Boilers Quarterly Progress Report: July-September 2001

Description: This is the fifth Quarterly Technical Report for DOE Cooperative Agreement No: DE-FC26-00NT40753. The goal of the project is to develop cost effective analysis tools and techniques for demonstrating and evaluating low NOx control strategies and their possible impact on boiler performance for firing US coals. The Electric Power Research Institute (EPRI) is providing cofunding for this program. This program contains multiple tasks and good progress is being made on all fronts. Field tests for NOx reduction in a cyclone fired utility boiler due to using Rich Reagent Injection (RRI) have been started. CFD modeling studies have been started to evaluate the use of RRI for NOx reduction in a corner fired utility boiler using pulverized coal. Field tests of a corrosion monitor to measure waterwall wastage in a utility boiler have been completed. Computational studies to evaluate a soot model within a boiler simulation program are continuing. Research to evaluate SCR catalyst performance has started. A literature survey was completed. Experiments have been outlined and two flow reactor systems have been designed and are under construction. Commercial catalyst vendors have been contacted about supplying catalyst samples. Several sets of new experiments have been performed to investigate ammonia removal processes and mechanisms for fly ash. Work has focused on a promising class of processes in which ammonia is destroyed by strong oxidizing agents at ambient temperature during semi-dry processing (the use of moisture amounts less than 5 wt-%). Both ozone and an ozone/peroxide combination have been used to treat both basic and acidic ammonia-laden ashes.
Date: October 10, 2001
Creator: Bockelie, Mike; Cremer, Marc; Davis, Kevin; Senior, Connie; Hurt, Bob; Eddings, Eric et al.

NOx Control Options and Integration for US Coal Fired Boilers Quarterly Progress Report: October-December 2001

Description: This is the sixth Quarterly Technical Report for DOE Cooperative Agreement No: DE-FC26-00NT40753. The goal of the project is to develop cost effective analysis tools and techniques for demonstrating and evaluating low NOx control strategies and their possible impact on boiler performance for firing US coals. The Electric Power Research Institute (EPRI) is providing co-funding for this program. This program contains multiple tasks and good progress is being made on all fronts. Preliminary results from laboratory and field tests of a corrosion probe to predict waterwall wastage indicate good agreement between the electrochemical noise corrosion rates predicted by the probe and corrosion rates measured by a surface profilometer. Four commercial manufacturers agreed to provide catalyst samples to the program. BYU has prepared two V/Ti oxide catalysts (custom, powder form) containing commercially relevant concentrations of V oxide and one containing a W oxide promoter. Two pieces of experimental apparatus being built at BYU to carry out laboratory-scale investigations of SCR catalyst deactivation are nearly completed. A decision was made to carry out the testing at full-scale power plants using a slipstream of gas instead of at the University of Utah pilot-scale coal combustor as originally planned. Design of the multi-catalyst slipstream reactor was completed during this quarter. One utility has expressed interest in hosting a long-term test at one of their plants that co-fire wood with coal. Tests to study ammonia adsorption onto fly ash have clearly established that the only routes that can play a role in binding significant amounts of ammonia to the ash surface, under practical ammonia slip conditions, are those that must involve co-adsorbates.
Date: January 31, 2002
Creator: Bockelie, Mike; Cremer, Marc; Davis, Kevin; Senior, Connie; Hurt, Bob; Suuberg, Eric et al.

NOx Control Options and Integration for US Coal Fired Boilers Quarterly Progress Report: January-March 2002

Description: This is the seventh Quarterly Technical Report for DOE Cooperative Agreement No: DE-FC26-00NT40753. The goal of the project is to develop cost effective analysis tools and techniques for demonstrating and evaluating low NOx control strategies and their possible impact on boiler performance for firing US coals. The Electric Power Research Institute (EPRI) is providing co-funding for this program. This program contains multiple tasks and good progress is being made on all fronts. A series of field tests for RRI at the Ameren Sioux Unit No.1 have demonstrated that RRI can provide up to 30% NOx reduction over the use of over fire air in large scale (480MW) cyclone fired utility boilers. The field tests and modeling results are in good agreement. Final data analysis has been completed for tests performed at Eastlake Power Station of a real-time waterwall corrosion monitoring system. The tests demonstrated that corrosion could be measured accurately in real-time in normal boiler operations, and an assessment of waterwall wastage could be made without impacting boiler availability. Detailed measurements of soot volume fraction have been performed for a coal burner in a pilot scale test furnace. The measured values are in good agreement with the expected trends for soot generation and destruction. Catalysts from four commercial manufacturers have been ordered and one of the samples was received this quarter. Several in situ analyses of vanadium-based SCR catalyst systems were completed at BYU. Results to date indicate that the system produces results that represent improvements compared to literature examples of similar experiments. Construction of the catalyst characterization system (CCS) reactor is nearly complete, with a few remaining details discussed in this report. A literature review originally commissioned from other parties is being updated and will be made available under separate cover as part of this investigation. Fabrication of the ...
Date: April 30, 2002
Creator: Bockelie, Mike; Cremer, Marc; Davis, Kevin; Senior, Connie; Hurt, Bob; Eddings, Eric et al.

NOx Control Options and Integration for US Coal Fired Boilers Quarterly Progress Report: April-June 2002

Description: This is the eighth Quarterly Technical Report for DOE Cooperative Agreement No: DE-FC26-00NT40753. The goal of the project is to develop cost effective analysis tools and techniques for demonstrating and evaluating low NOx control strategies and their possible impact on boiler performance for firing US coals. The Electric Power Research Institute (EPRI) is providing co-funding for this program. This program contains multiple tasks and good progress is being made on all fronts. CFD modeling studies of RRI in a full scale utility boiler have been performed that provide further insight into the NOx reduction process that occurs if the furnace is not adequately staged. In situ reactivity data indicate thus far that titania sulfates under SCR conditions but there is no indication of vanadia sulfation in agreement with some, but not most literature results. Additional analysis and advanced diagnostics are under way to confirm this result and determine its accuracy. Construction of a catalyst characterization reactor system is nearly complete, with a few remaining details discussed in this report. Shakedown testing of the SCR field reactor was completed at the University of Utah pilot-scale coal furnace. The CEM system has been ordered. Talks continued with American Electric Power about hosting a demonstration at their Rockport plant.
Date: July 28, 2002
Creator: Bockelie, Mike; Cremer, Marc; Davis, Kevin; Senior, Connie; Hurt, Bob; Eddings, Eric et al.

NOx Control Options and Integration for US Coal Fired Boilers Quarterly Progress Report: July-September 2002

Description: This is the ninth Quarterly Technical Report for DOE Cooperative Agreement No: DE-FC26-00NT40753. The goal of the project is to develop cost effective analysis tools and techniques for demonstrating and evaluating low NOx control strategies and their possible impact on boiler performance for firing US coals. The Electric Power Research Institute (EPRI) is providing cofunding for this program. This program contains multiple tasks and good progress is being made on all fronts. Various subsystems of BYU's Catalyst Characterization System (CCS) were upgraded this quarter. Work on the CCS hardware and software will continue in the coming quarter. A preliminary test matrix of poisoning experiments in the CCS has been drafted that will explore the effects of at least three poisons: sodium, potassium and calcium. During this quarter, we attempted to resolve discrepancies in previous in situ measurements of catalyst sulfation. Modifications were made to the XPS analysis procedure that allowed analyses of uncrushed samples. Although the XPS and FTIR results are now more consistent in that both indicate that the surface is sulfating (unlike the results reported last quarter), they disagree with respect to which species sulfates. The CEM system for the multi-catalyst slipstream reactor arrived this quarter. Minor modifications to the reactor and control system were completed. The reactor will be shipped to AEP Rockport plant next quarter for shakedown and installation. In a parallel effort, we have proposed to make mercury oxidation measurements across the catalysts at the start of the field test. Pending approval from DOE, we will begin the mercury measurements next quarter.
Date: October 24, 2002
Creator: Bockelie, Mike; Cremer, Marc; Davis, Kevin; Senior, Connie; Hurt, Bob; Eddings, Eric et al.

NOx Control Options and Integration for US Coal Fired Boilers Quarterly Progress Report: October-December 2002

Description: This is the tenth Quarterly Technical Report for DOE Cooperative Agreement No: DE-FC26-00NT40753. The goal of the project is to develop cost effective analysis tools and techniques for demonstrating and evaluating low NO{sub x} control strategies and their possible impact on boiler performance for firing US coals. The Electric Power Research Institute (EPRI) is providing cofunding for this program. This program contains multiple tasks and good progress is being made on all fronts. During this quarter, progress was made on the computational simulation of a full-scale boiler with the purpose of understanding the potential impacts of burner operating conditions on soot and NO{sub x} generation. Sulfation tests on both the titania support and vanadia/titania catalysts were completed using BYU's in situ spectroscopy reactor this quarter. These experiments focus on the extent to which vanadia and titania sulfate in an SO{sub 2}-laden, moist environment. Construction of the CCS reactor system is essentially complete and the control hardware and software are largely in place. A large batch of vanadia/titania catalyst in powder form has been prepared for use in poisoning tests. During this quarter, minor modifications were made to the multi-catalyst slipstream reactor and to the control system. The slipstream reactor was installed at AEP's Rockport plant at the end of November 2002. In this report, we describe the reactor system, particularly the control system, which was created by REI specifically for the reactor, as well as the installation at Rockport.
Date: January 30, 2003
Creator: Bockelie, Mike; Cremer, Marc; Davis, Kevin; Linjewile, Temi; Senior, Connie; Shim, Hong-Shig et al.

NOx Control Options and Integration for US Coal Fired Boilers Quarterly Progress Report: January-March 2003

Description: This is the eleventh Quarterly Technical Report for DOE Cooperative Agreement No: DE-FC26-00NT40753. The goal of the project is to develop cost effective analysis tools and techniques for demonstrating and evaluating low NO{sub x} control strategies and their possible impact on boiler performance for boilers firing US coals. The Electric Power Research Institute (EPRI) is providing co-funding for this program. This program contains multiple tasks and good progress is being made on all fronts. During this quarter, FTIR experiments for SCR catalyst sulfation were finished at BYU and indicated no vanadium/vanadyl sulfate formation at reactor conditions. Poisoned catalysts were prepared and tested in the CCS. Poisoning with sodium produced a noticeable drop in activity, which was larger at higher space velocity. A computer code was written at BYU to predict conversion along a cylindrical monolithic reactor. This code may be useful for monolith samples that will be tested in the laboratory. Shakedown of the slipstream reactor was completed at AEP's Rockport plant. Ammonia was connected to the reactor. The measurement of O{sub 2} and NO{sub x} made by the CEMs corresponded to values measured by the plant at the economizer outlet. Excellent NO{sub x} reduction was observed in preliminary tests of the reactor. Some operational problems were noted and these will be addressed next quarter.
Date: April 29, 2003
Creator: Bockelie, Mike; Linjewile, Temi; Senior, Connie; Eddings, Eric & Baxter, Larry

NOx Control Options and Integration for US Coal Fired Boilers Quarterly Progress Report: April-June 2003

Description: This is the twelfth Quarterly Technical Report for DOE Cooperative Agreement No: DE-FC26-00NT40753. The goal of the project is to develop cost effective analysis tools and techniques for demonstrating and evaluating low NOx control strategies and their possible impact on boiler performance for boilers firing US coals. The Electric Power Research Institute (EPRI) is providing co-funding for this program. This program contains multiple tasks and good progress is being made on all fronts. During this quarter, a new effort was begun on the development of a corrosion management system for minimizing the impacts of low NOx combustion systems on waterwalls; a kickoff meeting was held at the host site, AEP's Gavin Plant, and work commenced on fabrication of the probes. FTIR experiments for SCR catalyst sulfation were finished at BYU and indicated no vanadium/vanadyl sulfate formation at reactor conditions. Improvements on the mass-spectrometer system at BYU have been made and work on the steady state reactor system shakedown neared completion. The slipstream reactor continued to operate at AEP's Rockport plant; at the end of the quarter, the catalysts had been exposed to flue gas for about 1000 hours. Some operational problems were addressed that enable the reactor to run without excessive downtime by the end of the quarter.
Date: June 30, 2003
Creator: Bockelie, Mike; Davis, Kevin; Linjewile, Temi; Senior, Connie; Eddings, Eric; Whitty, Kevin et al.

NOx Control Options and Integration for US Coal Fired Boilers Quarterly Progress Report: July-September 2003

Description: This is the thirteenth Quarterly Technical Report for DOE Cooperative Agreement No: DEFC26-00NT40753. The goal of the project is to develop cost effective analysis tools and techniques for demonstrating and evaluating low NO{sub x} control strategies and their possible impact on boiler performance for boilers firing US coals. The Electric Power Research Institute (EPRI) is providing co-funding for this program. This program contains multiple tasks and good progress is being made on all fronts. The corrosion probe task is proceeding: Two plant visits were made to prepare for field testing and shakedown tests for the probes were conducted at the University of Utah''s L1500 furnace. Corrosion probes will be installed at the Gavin Plant site in the next quarter. Laboratory studies of SCR catalyst continued this quarter. FTIR studies of catalyst sulfation and of adsorption of NH3 and NO were continued at BYU. NO activities have been measured for a number of samples of BYU catalyst and insights have been gained from the results. Plans are being detailed to test monolith and plate catalysts exposed in the field. In this quarter, the catalysts in the slipstream reactor at AEP's Rockport plant were exposed to the dusty flue gas for 1695 hours. Thus the cumulative catalyst exposure to flue gas rose from 980 hours last quarter to 2677 hours in this quarter. Loss of catalyst activity was noted between April (when the catalysts were fresh) and August. Further analysis of activity data will be needed.
Date: September 30, 2003
Creator: Bockelie, Mike; Davis, Kevin; Linjewile, Temi; Senior, Connie; Eddings, Eric; Whitty, Kevin et al.

NOx Control Options and Integration for US Coal Fired Boilers Quarterly Progress Report: October-December 2003

Description: This is the fourteenth Quarterly Technical Report for DOE Cooperative Agreement No: DEFC26-00NT40753. The goal of the project is to develop cost effective analysis tools and techniques for demonstrating and evaluating low NOx control strategies and their possible impact on boiler performance for boilers firing US coals. The Electric Power Research Institute (EPRI) is providing co-funding for this program. Using the initial CFD baseline modeling of the Gavin Station and the plant corrosion maps, six boiler locations for the corrosion probes were identified and access ports have been installed. Preliminary corrosion data obtained appear consistent and believable. In situ, spectroscopic experiments at BYU reported in part last quarter were completed. New reactor tubes have been made for BYU's CCR that allow for testing smaller amounts of catalyst and thus increasing space velocity; monolith catalysts have been cut and a small reactor that can accommodate these pieces for testing is in its final stages of construction. A poisoning study on Ca-poisoned catalysts was begun this quarter. A possible site for a biomass co-firing test of the slipstream reactor was visited this quarter. The slipstream reactor at Rockport required repair and refurbishment, and will be re-started in the next quarter. This report describes the final results of an experimental project at Brown University on the fundamentals of ammonia / fly ash interactions with relevance to the operation of advanced NOx control technologies such as selective catalytic reduction. The Brown task focused on the measurement of ammonia adsorption isotherms on commercial fly ash samples subjected to a variety of treatments and on the chemistry of dry and semi-dry ammonia removal processes.
Date: December 31, 2003
Creator: Bockelie, Mike; Davis, Kevin; Linjewile, Temi; Senior, Connie; Eddings, Eric; Whitty, Kevin et al.

NOx Control Options and Integration for US Coal Fired Boilers Quarterly Progress Report: January-March 2004

Description: This is the fifteenth Quarterly Technical Report for DOE Cooperative Agreement No: DE-FC26-00NT40753. The goal of the project is to develop cost effective analysis tools and techniques for demonstrating and evaluating low NOx control strategies and their possible impact on boiler performance for boilers firing US coals. The Electric Power Research Institute (EPRI) is providing co-funding for this program. At AEP's Gavin Plant, data from the corrosion probes showed that corrosion rate increased as boiler load was increased. During an outage at the plant, the drop in boiler load, sensor temperature and corrosion rate could all be seen clearly. Restarting the boiler saw a resumption of corrosion activity. This behavior is consistent with previous observations made at a 600MWe utility boiler. More data are currently being examined for magnitudes of corrosion rates and changes in boiler operating conditions. Considerable progress was made this quarter in BYU's laboratory study of catalyst deactivation. Surface sulfation appears to partially suppress NO adsorption when the catalyst is not exposed to NH3; NH3 displaces surface-adsorbed NO on SCR catalysts and surface sulfation increases the amount of adsorbed NH3, as confirmed by both spectroscopy and TPD experiments. However, there is no indication of changes in catalyst activity despite changes in the amount of adsorbed NH3. A monolith test reactor (MTR), completed this quarter, provided the first comparative data for one of the fresh and field-exposed monolith SCR catalysts yet developed in this project. Measurements of activity on one of the field-exposed commercial monolith catalysts do not show significant changes in catalyst activity (within experimental error) as compared to the fresh catalyst. The exposed surface of the sample contains large amounts of Ca and Na, neither of which is present in the fresh sample, even after removal of visibly obvious fouling deposits. However, these fouling compounds do ...
Date: March 31, 2004
Creator: Bockelie, Mike; Davis, Kevin; Linjewile, Temi; Senior, Connie; Eddings, Eric; Whitty, Kevin et al.

NOx Control Options and Integration for US Coal Fired Boilers Quarterly Progress Report: April-June 2004

Description: This is the sixteenth Quarterly Technical Report for DOE Cooperative Agreement No: DEFC26-00NT40753. The goal of the project is to develop cost effective analysis tools and techniques for demonstrating and evaluating low NOx control strategies and their possible impact on boiler performance for boilers firing US coals. The Electric Power Research Institute (EPRI) is providing co-funding for this program. During an unplanned outage, damage occurred to the electrochemical noise corrosion probes installed at the AEP Gavin plant; testing is expected to resume in August. The KEMCOP corrosion coupons were not affected by the unplanned outage; the coupons were removed and sent for analysis. BYU conducted a series of tests before the ISSR lab was relocated. Ammonia adsorption experiments provided clear evidence of the types of acidic sites present on catalyst surfaces. Data collected this quarter indicate that surface sulfation decreases Lewis acid site concentrations for all catalysts thus far studied, confirming that catalytic activity under commercial coal-based SCR conditions occurs primarily on Br{o}nsted acid sites and would be susceptible to basic impurities such as alkali and alkaline earth oxides, chlorides, and sulfates. SCR activity tests based on MS analysis showed that increasing sulfation generally increases NO reduction activity for both 0% and 1% vanadia catalysts. During this quarter, the slipstream reactor at Rockport operated for 720 hours on flue gas. Catalyst exposure time reached 4500 hours since installation. The reactor is out of service at the Rockport plant and plans are being made to move it to the Gadsden Plant. At Gadsden, modifications have begun in preparation for installation of the slipstream reactor next quarter.
Date: June 30, 2004
Creator: Bockelie, Mike; Davis, Kevin; Linjewile, Temi; Senior, Connie; Eddings, Eric; Whitty, Kevin et al.

NOx Control Options and Integration for US Coal Fired Boilers Quarterly Progress Report: July-September 2004

Description: This is the seventeenth Quarterly Technical Report for DOE Cooperative Agreement No: DEFC26-00NT40753. The goal of the project is to develop cost effective analysis tools and techniques for demonstrating and evaluating low NOx control strategies and their possible impact on boiler performance for boilers firing US coals. The Electric Power Research Institute (EPRI) is providing co-funding for this program. The SCR slipstream reactor was assembled and installed at Plant Gadsden this quarter. Safety equipment for ammonia had not been installed at the end of the quarter, but will be installed at the beginning of next quarter. The reactor will be started up next quarter. Four ECN corrosion probes were reinstalled at Gavin and collected corrosion data for approximately one month. Two additional probes were installed and removed after about 30 hours for future profilometry analysis. Preliminary analysis of the ECN probes, the KEMA coupons and the CFD modeling results all agree with the ultrasonic tube test measurements gathered by AEP personnel.
Date: September 30, 2004
Creator: Bockelie, Mike; Davis, Kevin; Shino, Connie Senior Darren; Swenson, Dave; Baxter, Larry; Bartholomew, Calvin et al.

NOx Control Options and Integration for US Coal Fired Boilers Quarterly Progress Report: October-December 2004

Description: This is the eighteenth Quarterly Technical Report for DOE Cooperative Agreement No: DEFC26-00NT40753. The goal of the project is to develop cost effective analysis tools and techniques for demonstrating and evaluating low NOx control strategies and their possible impact on boiler performance for boilers firing US coals. The Electric Power Research Institute (EPRI) is providing co-funding for this program. Safety equipment for ammonia for the SCR slipstream reactor at Plant Gadsden was installed. The slipstream reactor was started and operated for about 1400 hours during the last performance period. Laboratory analysis of exposed catalyst and investigations of the sulfation of fresh catalyst continued at BYU. Thicker end-caps for the ECN probes were designed and fabricated to prevent the warpage and failure that occurred at Gavin with the previous design. A refurbished ECN probe was successfully tested at the University of Utah combustion laboratory. Improvements were implemented to the software that controls the flow of cooling air to the ECN probes.
Date: December 31, 2004
Creator: Bockelie, Mike; Davis, Kevin; Senior, Connie; Shino, Darren; Swenson, Dave; Baxter, Larry et al.

NOx Control Options and Integration for US Coal Fired Boilers Quarterly Progress Report: January-March 2005

Description: This is the nineteenth Quarterly Technical Report for DOE Cooperative Agreement No: DEFC26-00NT40753. The goal of the project is to develop cost effective analysis tools and techniques for demonstrating and evaluating low NO{sub x} control strategies and their possible impact on boiler performance for boilers firing US coals. The Electric Power Research Institute (EPRI) is providing co-funding for this program. Refurbished corrosion probes were installed at Plant Gavin and operated for approximately 1,300 hours. This quarterly report includes further results from the BYU catalyst characterization lab and the in-situ lab, and includes the first results from a model suitable for comprehensive simulation codes for describing catalyst performance. The SCR slipstream reactor at Plant Gadsden operated for approximately 100 hours during the quarter because of ash blockage in the inlet probe.
Date: March 31, 2005
Creator: Bockelie, Mike; Davis, Kevin; Senior, Connie; Shino, Darren; Swenson, Dave; Baxter, Larry et al.

NOx Control Options and Integration for US Coal Fired Boilers Quarterly Progress Report: April-June 2005

Description: This is the twentieth Quarterly Technical Report for DOE Cooperative Agreement No: DEFC26-00NT40753. The goal of the project is to develop cost-effective analysis tools and techniques for demonstrating and evaluating low-NO{sub x} control strategies and their possible impact on boiler performance for boilers firing US coals. The Electric Power Research Institute (EPRI) is providing co-funding for this program. At the beginning of this quarter, the corrosion probes were removed from Gavin Station. Data analysis and preparation of the final report continued this quarter. This quarterly report includes further results from the BYU catalyst characterization lab and the in-situ FTIR lab, and includes the first results from tests run on samples cut from the commercial plate catalysts. The SCR slipstream reactor at Plant Gadsden was removed from the plant, where the total exposure time on flue gas was 350 hours. A computational framework for SCR deactivation was added to the SCR model.
Date: June 30, 2005
Creator: Bockelie, Mike; Davis, Kevin; Denison, Martin; Senior, Connie; Shim, Hong-Shig; Shino, Darren et al.