Pulse Radiolysis Studies of the Reactivity of the Solvated Electron in Ethanol and Methanol
Description:
Abstract. By means of the pulse radiolysis technique a short-lived transient species has been observed in irradiated de-aerated ethanol and methanol, exhibiting an optical absorption throughout the visible and near infra-red. This transient is suggested to be the solvated electron on the basis of the nature of the spectrum, the reactivity with hydrogen ion and with various organic electron acceptors, and the formation of mononegative ions of some of these acceptors. The absolute rate constants …
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Date:
June 10, 1963
Creator:
Taub, Irwin A.; Sauer, Myran, C., Jr. & Dorfman, Leon M.
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