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Absorption Spectra of Aromatic Disulfides

Description: The effect of solvents and temperature on the optical absorption spectrum of a number of substituted aromatic disulfides is reported. The problems offered by the disulfide link and the exchange reactions between disulfides, and between disulfides and thiols, are receiving increasing attention. Recently the base-catalyzed exchange between various alkyl disulfides and the corresponding thiols was studied by means of a radioactive-tracer technique. Our initial purpose was to extend these investigations to a large number of compounds in a variety of experimental conditions using a spectrophotometric technique that, if applicable, would have been incomparably faster.
Date: October 31, 1956
Creator: Fava, Antonio & Calvin, Melvin

Absorption Spectra of Plutonium and Impurity Ions in Nitric Acid Solution

Description: The absorption spectra for Pu(III), (IV), (VI), and the red Pu(IV)- peroxy complex were determined in HNO/sub 3/ solution. Extinction coefficients for the above species of Pu were measured. Temperature has little effect on the spectra, but variation of acidity causes shifting of absorption peaks and some changes in the extinction coefficients. The absorption spectra and extinction coefficients in the region 390 to 1200 m mu were measured for chromic, nickelous, manganous, calcium, lanthanum, aluminum, ferrous. ferric, and permanganate ions in HNO/sub 3/ solutions. In addition, the effects of nitrite, oxalic acid, sulfamic acid, hydrogen peroxide, and various HNO/sub 3/ concentrations on the extinction coefficients of some of these ions were determined. The chromic, nickelous, ferrous, and permanganate ions, and ferric ion with oxalic acid, have sufficiently high extinction coefficients to cause inaccuracies in valence determinations of Pu in solutions containing high concentrations of these ions, unless corrections are made. (auth)
Date: July 31, 1956
Creator: Myers, M. N.

Acoustics of a nonhomogeneous moving medium.

Description: Report discussing theoretical basis of the acoustics of a moving nonhomogeneous medium. Experiments that illustrate or confirm some of the theoretical explanation or derivation of these acoustics are also included.
Date: February 1956
Creator: Blokhintsev, D I

ACTIVE PROCESS DEVELOPMENT ACTIVITIES FOR PROCESSING OF FEED MATERIALS

Description: The carbonate and organic leaching processes for the recovery of U from its ores are outlined. The Excer prccess (ion-exchange conversion and electrolytic reduction) and the Fluorox process (starch-- HF reaction) for the production of UF/sub 4/ from ore concentrate and depleted reactor fuels are described. The fluidized-bed process for UF/sub 4/ production from UO/sub 2/(NO/ sub 3/)/sub 2/ is also described. Methods for improving the reactivity of UO/sub 3/ and mechanical and thermal processes for increasing the density of UF/sub 4/ were investigated. Applications of fluoride volatility prccesses to feed materials are discussed. (C.W.H.)
Date: January 1, 1956

Adaptation of Combustion Principles to Aircraft Propulsion, Volume 2, Combustion in Air-Breathing Jet Engines

Description: This volume continues the NACA study of combustion principles for aircraft propulsion. The various aspects of combustion pertinent to jet engines are organized and interpreted with quite extensive information, particularly for basic or fundamental. subject matter. The report concerns only air-breathing engines and hydrocarbon fuels, and not rocket engines and high-energy fuels. Since the references have been selected to illustrate important points, the bibliographies, while thorough, are not complete. This volumes describes the observed performance and design problems of engine combustors of the principal types. These include combustor-inlet conditions; starting, acceleration, combustion limits, combustion efficiency, coke deposits, and smoke formation in turbojets; ram-jet performance; and afterburner performance and design.
Date: May 2, 1956

Aerodynamic and hydrodynamic characteristics of a deck-inlet multijet water-based-aircraft configuration designed for supersonic flight

Description: From Introduction: "In the present investigation, lift, drag, and pitching moment were determined over a Mach number range 0.6 to 1.42. Smooth-water takeoff and landing stability and resistance were investigated. A brief check of the rough-water spray and behavior was also made."
Date: December 5, 1956
Creator: Bielat, Ralph P; Coffee, Claude W , Jr & Petynia, William W

Aerodynamic characteristics and flying qualities of a tailless triangular-wing airplane configuration as obtained from flights of rocket-propelled models at transonic and supersonic speeds

Description: Report discussing a flight investigation of rocket-powered models of a tailless triangular-wing airplane configuration was made through the transonic and low supersonic speed range at the Langley Pilotless Aircraft Research Station at Wallops Island, Va. An analysis of the aerodynamic coefficients, stability derivatives, and flying qualities based on the results obtained from the successful flight tests of three models is presented.
Date: November 1956
Creator: Mitcham, Grady L; Stevens, Joseph E & Norris, Harry P

The Aerodynamic Characteristics in Pitch of a 1/15-Scale Model of the Grumman F11F-1 Airplane at Mach Numbers of 1.41, 1.61, and 2.01, TED No. NACA DE 390

Description: Tests have been made in the Langley 4- by 4-foot supersonic pressure tunnel at Mach numbers of 1.41, 1.61, and 2.01 to determine the static longitudinal stability and control characteristics of various arrangements of the Grumman F11F-1 airplane. Tests were made of the complete model and various combinations of its component parts and, in addition, the effects of various body modifications, a revised vertical tail, and wing fences on the longitudinal characteristics were determined. The results indicate that for a horizontal-tail incidence of -10 deg the trim lift coefficient varied from 0.29 at a Mach number of 1.61 to 0.23 at a Mach number of 2.01 with a corresponding decrease in lift-drag trim from 3.72 to 3.15. Stick-position instability was indicated in the low-supersonic-speed range. A photographic-type nose modification resulted in slightly higher values of minimum drag coefficient but did not significantly affect the static stability or lift-curve slope. The minimum drag coefficient for the complete model with the production nose remained essentially constant at 0.047 throughout the Mach number range investigated.
Date: May 23, 1956
Creator: Driver, Cornelius

Aerodynamic characteristics of a 0.04956-scale model of the Convair F-102B airplane at Mach numbers of 1.41, 1.61, and 2.01: COORD No. AF-231

Description: Report discussing testing of a scale model of the Convair F-102B to determine its aerodynamic characteristics at several Mach numbers. Four basic body modifications and two afterbody configurations were evaluated.The body modifications were all found to slightly reduce values of minimum drag, but did not cause a change in the static stability and lift-curve-slope values compared to the F-102A.
Date: February 7, 1956
Creator: Driver, Cornelius & Robinson, Ross B.

Aerodynamic control of supersonic inlets for optimum performance

Description: From Introduction: "The purpose of this paper is to discuss and evaluate some of the input signals or control parameters which have been experimentally employed to operate turbojet inlet-control systems. These include the normal-shock position, the oblique-shock position, and the diffuser-exit Mach number. The discussion is based on results obtained at the NACA Lewis laboratory during control investigations of ram-jet engines (ref. 1 to 5) and during a study on the control of a supersonic inlet for the J34 turbojet engine (refs 6 and 7)."
Date: February 20, 1956
Creator: Wilcox, Fred A. & Perchonok, Eugene