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Carbonaceous Aerosol Particles From Common Vegetation in the Grand Canyon

Description: The problem of visibility reduction in the Grand Canyon due to fine organic aerosol particles in the atmosphere has become an area of increased environmental concern. Aerosol particles can be derived from many emission sources. In this report, we focus on identifying organic aerosols derived from common vegetation in the Grand Canyon. These aerosols are expected to be significant contributors to the total atmospheric organic aerosol content. Aerosol samples from living vegetation were collected by resuspension of surface wax and resin components liberated from the leaves of vegetation common to areas of the Grand Canyon. The samples were analyzed using high-resolution gas chromatography/mass spectrometry (GC/MS). Probable identification of compounds was made by comparison of sample spectra with National Institute of Standards and Technology (NIST) mass spectral references and positive identification of compounds was made when possible by comparison with authentic standards as well as NIST references. Using these references, we have been able to positively identify the presence of n-alkane and n-alkanoic acid homolog series in the surface waxes of the vegetation sampled. Several monoterpenes, sesquiterpenes, and diterpenes were identified also as possible biogenic aerosols which may contribute to the total organic aerosol abundance leading to visibility reduction in the Grand Canyon.
Date: May 1992
Creator: Hallock, K. A.; Mazurek, M. A. & Cass, G. R.
Location Info:

Mineral Resources of the Black Mountains North and Burns Spring Wilderness Study Areas, Mohave County, Arizona

Description: From abstract: At the request of the U.S. Bureau of Land Management, approximately 19,300 acres of the Black Mountains North Wilderness Study Area (AZ-020-009) and 23,310 acres of the Burns Spring Wilderness Study Area (AZ-020-010) were evaluated for mineral resources and mineral resource potential. In this report, the area studied is referred to, collectively or individually, as the 'wilderness study area' or simply 'the study area'; any reference to the Black Mountains North or Burns Spring Wilderness Study Areas refers only to that part of the wilderness study area for which a mineral survey was requested by the U.S. Bureau of Land Management. The study area is located in western Arizona, about 30 mi northwest of Kingman. There are no identified resources in the study area.
Date: 1990
Creator: Conrad, James E.; Hill, Randall H.; Jachens, Robert C. & Neubert, John T.

Mineral Resources of the Wabayuma Peak Wilderness Study Area, Mohave County, Arizona

Description: From abstract: The Wabayuma Peak Wilderness Study Area (AZ-020-037/043), for which a mineral survey was requested by the U.S. Bureau of Land Management, encompasses 40,118 acres in northwestern Arizona. Fieldwork was carried out in 1986-88 by the U.S. Bureau of Mines and the U.S. Geological Survey to appraise the identified (known) resources and assess the mineral resource potential (undiscovered) of the wilderness study area. Within the Wabayuma Peak Wilderness Study Area are 14 private parcels of land totaling 1,315 acres. The Wabayuma Peak Wilderness Study Area, including the 14 private parcels of land, is herein referred to as the "wilderness study area" or the "study area." The Boriana, Antler, and Copper World mines lie near the east boundary of the study area. The Boriana mine was a major tungsten-producing mine of the United States during World War II. The Antler and Copper World mines produced relatively small amounts of copper and zinc prior to 1970.
Date: 1990
Creator: Conway, Clay M.; Hassemer, Jerry R. & Knepper, Daniel H., Jr.

Mineral Resources of the Warm Springs Wilderness Study Area, Mohave County, Arizona

Description: From abstract: At the request of the U.S. Bureau of Land Management, approximately 113,500 acres of the Warm Springs Wilderness Study Area (AZ-020-028/029) were evaluated for mineral resources and mineral resource potential. In this report, the area studied is referred to as the "wilderness study area" or "study area"; any reference to the Warm Springs Wilderness Study Area refers only to that part of the wilderness study area for which a mineral survey was requested. This study area is located in west-central Arizona. The U.S. Geological Survey and the U.S. Bureau of Mines conducted geological, geochemical, and geophysical surveys to appraise the identified mineral resources (known) and assess the mineral resource potential (undiscovered) of the study area. Fieldwork for this report was carried out largely in 1986-1989.
Date: 1990
Creator: Gray, Floyd; Jachens, Robert C.; Miller, Robert J. & Knepper, Daniel H., Jr.

Petrographic and Geochemical Analyses of Leach Samples from Artillery Peak, Mohave County, Arizona

Description: Abstract: The first step in determining whether Mn can be recovered by in situ leaching is to develop and test a selective lixiviant. Two column leach tests and one core leach test were conducted by the U.S. Bureau of Mines on Mn oxide ore using aqueous sulfur dioxide (SO2) as the lixiviant. The column tests showed that aqueous SO2 could selectively dissolve available Mn oxides from calcite-rich ore in a heap leach system. However, the core test showed that calcite gangue side reactions can have pronounced negative effects on the likelihood of successful in situ leaching of a calcite-rich ore with aqueous SO2. Petrographic and geochemical analyses showed that both Mn (IV, II) oxides and calcite were dissolved. The abundance of dissolved Ca caused precipitation of gypsum. Acid consumption by calcite dissolution caused a rise in pH that caused the S02/S species to shift to SO32- (sulfite), which hindered reductive dissolution of Mn oxide. Gypsum precipitation did not affect complete leaching of the rock fragments in the column tests; however, it plugged the natural permeability in the core. Manganese recoveries were high for the column tests and low for the core test.
Date: 1995
Creator: Brink, Susan; Blake, Rolland & Marozas, Dianne